Whether the researchers in Denver need to recalibrate the thermometer.

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1. A three-liter tank contains two gram-moles of nitrogen at − 150.8o C. Estimate the tank pressure using the ideal gas equation of state and then using the Virialequation of state truncated after the second term. Taking the second estimate to be correct, calculate the percentage error that results from the use of the ideal gas equation at the system conditions. Data for nitrogen: Tc = 126.2 K, pc = 33.5 atm, and ω = 0.04012. 2. One mole of propane gas is to be expanded from 0.001 m3 to 0.040 m3 while incontact with a heating bath at 100o C. The expansion is not reversible. The heatextract from the bath is 600 J. Determine the work for the expansion using theVan der Waals equation of state.

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Chapter 19, Problem 47PQ

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1. A three-liter tank contains two gram-moles of nitrogen at − 150.8o C. Estimate the tank pressure using the ideal gas equation of state and then using the Virialequation of state truncated after the second term. Taking the second estimate to be correct, calculate the percentage error that results from the use of the ideal gas equation at the system conditions. Data for nitrogen: Tc = 126.2 K, pc = 33.5 atm, and ω = 0.04012. 2. One mole of propane gas is to be expanded from 0.001 m3 to 0.040 m3 while incontact with a heating bath at 100o C. The expansion is not reversible. The heatextract from the bath is 600 J. Determine the work for the expansion using theVan der Waals equation of state.

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