ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
3rd Edition
ISBN: 9781119781448
Author: Klein
Publisher: WILEY
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Question
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Chapter 19, Problem 64PP

(a)

Interpretation Introduction

Interpretation:

Major product of the given reaction has to be predicted.

Concept introduction:

An imine is a compound having C=N bond that is formed by the reaction of a ketone or aldehyde and primary amine under mild acidic conditions with the elimination of water molecule.

The part of the molecule that is attached to the carbon atom in the C=N bond is from the ketone and the part attached to the nitrogen atom is for the primary amine.

(b)

Interpretation Introduction

Interpretation:

Major product of the given reaction has to be predicted.

Concept introduction:

Grignard Reaction: This is an organometallic reaction where an alkyl or aryl-magnesium halides is introduced to the carbonyl group present in an aldehyde and ketone. Here, aldehyde and ketone gets converted to alcohols.

  ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 19, Problem 64PP , additional homework tip  1

(c)

Interpretation Introduction

Interpretation:

Major product of the given reaction has to be predicted.

Concept introduction:

Baeyer Villiger oxidation is an oxidation reaction in which the ketone gets converted into ester by the introduction of one oxygen atom and cyclic ketone gets converted into lactone. The reagents used in the reaction are peroxy acid or peroxide.

  ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 19, Problem 64PP , additional homework tip  2

The rate of migration can be given as:

  H>3o>2o>Ph>1o>methyl

Oxidation: If electrons are moved from a species or oxygen atoms are added to a species or hydrogen atom gets removed from a species during a chemical reaction is known as reduction.

(d)

Interpretation Introduction

Interpretation:

Major product of the given reaction has to be predicted.

Concept introduction:

Baeyer Villiger oxidation is an oxidation reaction in which the ketone gets converted into ester by the introduction of one oxygen atom and cyclic ketone gets converted into lactone. The reagents used in the reaction are peroxy acid or peroxide.

  ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<, Chapter 19, Problem 64PP , additional homework tip  3

The rate of migration can be given as:

  H>3o>2o>Ph>1o>methyl

Oxidation: If electrons are moved from a species or oxygen atoms are added to a species or hydrogen atom gets removed from a species during a chemical reaction is known as reduction.

(e)

Interpretation Introduction

Interpretation:

Major product of the given reaction has to be predicted.

Concept introduction:

An imine is a compound having C=N bond that is formed by the reaction of a ketone or aldehyde and primary amine under mild acidic conditions with the elimination of water molecule.

The part of the molecule that is attached to the carbon atom in the C=N bond is from the ketone and the part attached to the nitrogen atom is for the primary amine.

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Chapter 19 Solutions

ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<

Ch. 19.5 - Prob. 9ATSCh. 19.5 - Prob. 10CCCh. 19.5 - Prob. 11CCCh. 19.5 - Prob. 12CCCh. 19.5 - Prob. 13CCCh. 19.6 - Prob. 3LTSCh. 19.6 - Prob. 14PTSCh. 19.6 - Prob. 15PTSCh. 19.6 - Prob. 16ATSCh. 19.6 - Prob. 17CCCh. 19.6 - Prob. 18CCCh. 19.6 - Prob. 20PTSCh. 19.6 - Prob. 21ATSCh. 19.6 - Prob. 22CCCh. 19.7 - Prob. 5LTSCh. 19.7 - Prob. 23PTSCh. 19.7 - Prob. 24ATSCh. 19.7 - Prob. 25CCCh. 19.8 - Prob. 26CCCh. 19.8 - Prob. 27CCCh. 19.9 - Prob. 28CCCh. 19.9 - Prob. 29CCCh. 19.10 - Prob. 30CCCh. 19.10 - Prob. 31CCCh. 19.10 - Prob. 32CCCh. 19.10 - Prob. 33CCCh. 19.10 - Prob. 6LTSCh. 19.10 - Prob. 34PTSCh. 19.10 - Prob. 35PTSCh. 19.10 - Prob. 36ATSCh. 19.10 - Prob. 37ATSCh. 19.10 - Prob. 38CCCh. 19.11 - Prob. 39CCCh. 19.12 - Prob. 7LTSCh. 19.12 - Prob. 40PTSCh. 19.12 - Prob. 41ATSCh. 19.13 - Prob. 42CCCh. 19 - Prob. 43PPCh. 19 - Prob. 44PPCh. 19 - Prob. 45PPCh. 19 - Prob. 46PPCh. 19 - Prob. 47PPCh. 19 - Prob. 48PPCh. 19 - Prob. 49PPCh. 19 - Prob. 50PPCh. 19 - Prob. 51PPCh. 19 - Prob. 52PPCh. 19 - Prob. 53PPCh. 19 - Prob. 54PPCh. 19 - Prob. 55PPCh. 19 - Prob. 56PPCh. 19 - Prob. 57PPCh. 19 - Prob. 58PPCh. 19 - Prob. 59PPCh. 19 - Prob. 60PPCh. 19 - Predict the major product(s) obtained when each of...Ch. 19 - Prob. 62PPCh. 19 - Prob. 63PPCh. 19 - Prob. 64PPCh. 19 - Prob. 65PPCh. 19 - Prob. 66PPCh. 19 - Prob. 67PPCh. 19 - Prob. 68PPCh. 19 - Prob. 69PPCh. 19 - Prob. 70PPCh. 19 - Prob. 71PPCh. 19 - Prob. 72PPCh. 19 - Prob. 73PPCh. 19 - Prob. 74IPCh. 19 - Prob. 75IPCh. 19 - Prob. 76IPCh. 19 - Prob. 77IPCh. 19 - Prob. 78IPCh. 19 - Prob. 79IPCh. 19 - Prob. 80IPCh. 19 - Prob. 81IPCh. 19 - Prob. 83IPCh. 19 - Prob. 84IPCh. 19 - Prob. 85IPCh. 19 - Prob. 86IPCh. 19 - Prob. 87IPCh. 19 - Prob. 88IPCh. 19 - Prob. 89IPCh. 19 - Prob. 90IPCh. 19 - Prob. 91IPCh. 19 - Prob. 92IPCh. 19 - Prob. 93IPCh. 19 - Prob. 94CPCh. 19 - Prob. 95CPCh. 19 - Treatment of the following ketone with LiAIHa...
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