Chemistry: The Central Science (14th Edition)
Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 19, Problem 87AE

(a)

Interpretation Introduction

To determine: The authenticity of the given statement, “The feasibility of manufacturing NH3 from N2 and H2 depends entirely on the value of ΔH for the process”.

Solution: The given statement is true.

Explanation:

The balanced chemical equation for the given reaction is,

    N2(g)+3H2(g)2NH3(g)

The feasibility of the reaction is determined by the value of free energy change of the reaction. If the value of free energy change is negative then the given reaction is feasible and vice versa.

The reaction of manufacturing of ammonia involves the formation of two gaseous products from four gaseous reactants which results in the decrease in randomness of the system and also the entropy change. Therefore, the feasibility of the reaction entirely depends upon the value of enthalpy change according to the given formula,

    ΔG0=ΔH0TΔS0

Where,

  • ΔG0 is the standard free energy change of the reaction.
  • ΔH0 is the standard enthalpy change of the reaction.
  • T is the temperature of the reaction.
  • ΔS0 is the standard entropy change of the reaction.

Conclusion:

The given statement is true.

(b)

Interpretation Introduction

To determine: The authenticity of the given statement, “The reaction of Na(s) with Cl2(g) to form NaCl(s) is a spontaneous process”.

(c)

Interpretation Introduction

To determine: The authenticity of the given statement, “A spontaneous process can in principle be conducted reversibly”.

(d)

Interpretation Introduction

To determine: The authenticity of the given statement, “Spontaneous processes in general require that work be done to force them to proceed”.

(e)

Interpretation Introduction

To determine: The authenticity of the given statement, “Spontaneous processes are those that are exothermic and that lead to high degree of order in the system”.

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Chapter 19 Solutions

Chemistry: The Central Science (14th Edition)

Ch. 19.5 - Which of these statements is true? All spontaneous...Ch. 19.5 - Prob. 19.6.2PECh. 19.5 - Prob. 19.7.1PECh. 19.5 - Prob. 19.7.2PECh. 19.5 - Prob. 19.8.1PECh. 19.5 - Prob. 19.8.2PECh. 19.6 - What is the temperature above which the Haber...Ch. 19.6 - Prob. 19.9.2PECh. 19.7 - Prob. 19.10.1PECh. 19.7 - Prob. 19.10.2PECh. 19.7 - Prob. 19.11.1PECh. 19.7 - Prob. 19.11.2PECh. 19.7 - Prob. 19.12.1PECh. 19.7 - Prob. 19.12.2PECh. 19 - Prob. 1DECh. 19 - Prob. 1ECh. 19 - As shown here, one type of computer keyboard...Ch. 19 - 19.3 a. What are the signs of ΔS and ΔH for the...Ch. 19 - Predict the signs of H and S for this reaction....Ch. 19 - The accompanying diagram shows how entropy varies...Ch. 19 - Prob. 6ECh. 19 - The accompanying diagram shows how H (red line)...Ch. 19 - Prob. 8ECh. 19 - Prob. 9ECh. 19 - Prob. 10ECh. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Can endothermic chemical reaction be spontaneous?...Ch. 19 - Prob. 15ECh. 19 - Prob. 16ECh. 19 - Prob. 17ECh. 19 - Prob. 18ECh. 19 - Prob. 19ECh. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 25ECh. 19 - Prob. 26ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Using the heat of vaporization in Appendix B,...Ch. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - Prob. 38ECh. 19 - For each of the following pairs, predict which...Ch. 19 - For each of the following pairs, predict which...Ch. 19 - Predict the sign of the entropy change of the...Ch. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - 19.44 Propanol (C3H7OH) melts at – 126.5 o C and...Ch. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Using So values from Appendix C, calculate So...Ch. 19 - Calculate So values for the following reactions by...Ch. 19 - Prob. 53ECh. 19 - Prob. 54ECh. 19 - For a certain chemical reaction, Ho = -35.4 kJ and...Ch. 19 - A certain reaction has Ho = +23.7.kJ and So = +...Ch. 19 - Using data in Appendix C, calculate Ho, So, and Go...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - Prob. 62ECh. 19 - Prob. 63ECh. 19 - Prob. 64ECh. 19 - Prob. 65ECh. 19 - Prob. 66ECh. 19 - Prob. 67ECh. 19 - Prob. 68ECh. 19 - Prob. 69ECh. 19 - Prob. 70ECh. 19 - a. Use data in Appendix c to estimate the boiling...Ch. 19 - Prob. 72ECh. 19 - Prob. 73ECh. 19 - Prob. 74ECh. 19 - Prob. 75ECh. 19 - Prob. 76ECh. 19 - Prob. 77ECh. 19 - 19.78 Consider the reaction 3CH4(g) C3H8(g) ...Ch. 19 - Use data from Appendix C to calculate the...Ch. 19 - Prob. 80ECh. 19 - Prob. 81ECh. 19 - Prob. 82ECh. 19 - Prob. 83ECh. 19 - Prob. 84ECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 88AECh. 19 - Prob. 89AECh. 19 - Prob. 90AECh. 19 - Prob. 91AECh. 19 - Prob. 92AECh. 19 - Prob. 93AECh. 19 - Prob. 94AECh. 19 - Prob. 95AECh. 19 - Prob. 96AECh. 19 - Prob. 97AECh. 19 - Prob. 98AECh. 19 - Prob. 99AECh. 19 - Prob. 100AECh. 19 - Prob. 101AECh. 19 - Prob. 102AECh. 19 - Most liquids follow Trouton’s rule (see Exercise...Ch. 19 - In chemical kinetics, the entropy of activation is...Ch. 19 - Prob. 105IECh. 19 - Prob. 106IECh. 19 - Prob. 107IECh. 19 - Prob. 108IECh. 19 - The following data compare the standard enthalpies...Ch. 19 - Prob. 110IECh. 19 - Prob. 111IECh. 19 - Prob. 112IE
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