Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 19.5, Problem 6P
The oxidation of glyceraldehyde-3-phosphate to 1,3-bisphosphoglycerate is an endergonic reaction, but the flow through this point in glycolysis proceeds smoothly. How is the unfavorable equilibrium constant overcome?
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The oxidation of glyceraldehyde-3-phosphate to 1,3-bisphosphoglycerate is an endergonic reaction, but the flow through this point in glycolysis proceeds smoothly. How is the unfavorable equilibrium constant overcome?
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Chapter 19 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 19.4 - Prob. 1PCh. 19.4 - How many molecules of NADH are formed from the...Ch. 19.4 - Why does the OH group add to the -carbon rather...Ch. 19.5 - Prob. 4PCh. 19.5 - Prob. 5PCh. 19.5 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 19.5 - Prob. 7PCh. 19.6 - Prob. 8PCh. 19.6 - Prob. 9PCh. 19.6 - Propose a mechanism for the reduction of...
Ch. 19.7 - Prob. 11PCh. 19.8 - Acid-catalyzed dehydration reactions are normally...Ch. 19.8 - Prob. 13PCh. 19.8 - Prob. 14PCh. 19.8 - Prob. 15PCh. 19.9 - Prob. 16PCh. 19.10 - a. What is the name of the enzyme that converts...Ch. 19.13 - Prob. 18PCh. 19 - Prob. 19PCh. 19 - Prob. 20PCh. 19 - Prob. 21PCh. 19 - Prob. 22PCh. 19 - Prob. 23PCh. 19 - Prob. 24PCh. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Prob. 27PCh. 19 - Prob. 28PCh. 19 - Prob. 29PCh. 19 - Prob. 30PCh. 19 - Prob. 31PCh. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Prob. 35PCh. 19 - Prob. 36PCh. 19 - Prob. 37PCh. 19 - Prob. 38PCh. 19 - Prob. 39PCh. 19 - Prob. 40PCh. 19 - Prob. 41PCh. 19 - Prob. 42PCh. 19 - Prob. 43PCh. 19 - Prob. 44PCh. 19 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 19 - A student is trying to determine the mechanism for...Ch. 19 - What would be the results of the experiment in...
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- Show, by Lewis electron-dot structures of theappropriate portions of the molecule, where electrons are lost inthe following conversions:(a) Pyruvate to acetyl-CoA(b) Isocitrate to -ketoglutarate(c) -Ketoglutarate to succinyl-CoA(d) Succinate to fumarate(e) Malate to oxaloacetatearrow_forwardGiven the following information on reduction potentials, calculate the standard free energy in kJ/mol based on your understanding of electron transfer through the pyruvate dehydrogenase complex. Round to nearest whole number. Lipoamide + 2H+ + 2e- → dihydrolipoamide ∆εο = -0.29 FAD + 2H+ + 2e- → FADH2 ∆εο = −0.01arrow_forwardWhich of the reactions are spontaneous (favorable)? 1)DHAP↽−−⇀glyceraldehyde-3-phosphateΔ?=3.8 kJ/mol 2)L-malate+NAD+⟶oxaloacetate+NADH+H+Δ?=29.7 kJ/mol- 3) glutamate+NAD++H2O⟶NH+4+α-ketoglutarate+NADH+H+Δ?=3.7 kcal/ 4) C6H13O9P+ATP⟶C6H14O12P2+ADPΔ?=−14.2KJ/mol 5) −Rh(I)C2H6Δ?=−150.97 kJ/molC2H4+H2→Rh(I)C2H6ΔG=−150.97 kJ/mol 6) C4H4O5⟶C4H2O4+H2OΔ?=3.1 kJ/molarrow_forward
- Calculate the ΔG0’ for the reduction of pyruvate by NADH.arrow_forwardWhat is the standard free energy (∆G0’) for the reduction of coenzyme Q by NADH as carried out by Complex I (NADH-CoQ Reductase) of the electron transport pathway if E0’(NAD+/NADH) =-0.10 V and E0’ (CoQ/CoQH2) = +0.095 V. Answer Choicesarrow_forwardWhat factors influence the metabolic rate of citrate in the mitochondria? What is the fate of cytosolic pyruvate when it is reduced by cytosolic NADH? Could leptin be used to treat obesity?arrow_forward
- Why are two equivalents of NADPH required to reduce ydroxymethylglutaryl-CoA to mevalonic acid?arrow_forwardTriose phosphate isomerase catalyzes the conversion of dihydroxyacetone phosphate (DHAP) into glyceraldehyde-3-phosphate (G3P). Which of the following illustrates this chemical reaction? a) A b) B c) C d) Darrow_forwardWhich compound in each of the following pairs of phosphate-containing compounds releases more free energy upon hydrolysis? a. ATP and Phosphoenolpyruvate b. Creatine phosphate and ADP c. Glucose 1-phosphate and 1,3-biphosphoglycerate d. AMP and glycerol 3-phosphatearrow_forward
- All are metabolic pathways for glucose catabolism (metabolism) EXCEPT: Question 70 options: A) Embden-Myerhof pathway B) Glycogenesis C) Glyconeogenesis D) Hexose monophosphate shuntarrow_forwardList the following in order of increasing tendency to accept electrons: (a) α-ketoglutarate + CO2 (yielding isocitrate); (b) oxaloacetate; (c) O2; (d) NADP+.arrow_forwarddraw the chemical structures of the reactant and product of the following reactions: a.) addition of a phosphate group to (ex: phosphorylation of) glycose b.) addition of a phosphate group to (ex: phosphorylation of) fructose-6-phosphate c.) addition of a phosphate group to (ex: phosphorylation of) phosphoenolpyruvatearrow_forward
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