ORGANIC CHEMISTRY
4th Edition
ISBN: 9781119745105
Author: Klein
Publisher: WILEY
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Chapter 2, Problem 67ASP
Interpretation Introduction
Interpretation: The bond-line drawing of
Concept Introduction: A method used to represent molecular structures of compounds is said to be bond line notation. In this notation, a line depicts a bond between two atoms and are drawn in a zigzag format.
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3.
a. E,R
is?
b. E,S
c. S,Z
4. What is the л-energy diagram of the compound in question 3?
d. R,Z
e. not a.-d.
a.
b.
C.
d.
e. not a.-d.
Which resonance structure below holds the negative charge better.
A
B
C
H3C
H₂C
H₂C
Select one:
a. A
b. B
C. C
CH3
CH 3
CH 3
REPRESENTATIONS OF ORGANIC MOLECULES
Identifying isomers and resonance structures
Determine the relationship between Structure A and Structure B in each row of the table.
Structure A
Structure B
Relationship
H.
o isomers
H.
H
H
-H
H-C- C-O
-H-
O resonance structures
H
H.
H
H
Н—С—Н
o neither
H
o isomers
H :0:
:0-H
H.
H
H-
C-C
C-H
H-C=C
C=C-H
O resonance structures
H.
H.
H
o neither
o isomers
:o:
H
H.
H-
O resonance structures
H
H
H.
H
o neither
72°F
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II
Chapter 2 Solutions
ORGANIC CHEMISTRY
Ch. 2.1 - Prob. 1LTSCh. 2.1 - Prob. 3ATSCh. 2.2 - Prob. 2LTSCh. 2.2 - Prob. 4PTSCh. 2.2 - Prob. 6ATSCh. 2.4 - Prob. 3LTSCh. 2.4 - Prob. 9ATSCh. 2.5 - Prob. 4LTSCh. 2.5 - Prob. 11PTSCh. 2.9 - Prob. 6LTS
Ch. 2.9 - Prob. 15PTSCh. 2.9 - Prob. 16PTSCh. 2.10 - Prob. 18CCCh. 2.10 - Prob. 19CCCh. 2.10 - Prob. 20CCCh. 2.10 - Prob. 21CCCh. 2.10 - Prob. 22CCCh. 2.10 - Prob. 23CCCh. 2.10 - Prob. 24CCCh. 2.10 - Prob. 25CCCh. 2 - Prob. 34PPCh. 2 - Prob. 35PPCh. 2 - Prob. 36PPCh. 2 - Prob. 37PPCh. 2 - Prob. 38PPCh. 2 - Prob. 40PPCh. 2 - Prob. 42PPCh. 2 - Prob. 43PPCh. 2 - Prob. 44PPCh. 2 - Prob. 45PPCh. 2 - Prob. 46PPCh. 2 - Prob. 47PPCh. 2 - Prob. 48PPCh. 2 - Prob. 49PPCh. 2 - Prob. 50PPCh. 2 - Prob. 67ASP
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- Exothermic 1. Fill in the following table for endothermic and exothermic reactions: Endothermic n no so Absorb or release heat Positive or negative AH Products or reactants have higher energy Products or reactant more stable Favorable or unfavorable Bonds stronger in reactants or products 2. Circle the compound in each pair that has the higher bond dissociation energy/stronger bond: a. NH3 or PH3 b. H2Se or H2S с. CH4 or SIH4 Use AH and the balanced equation below to answer question 3 C,H12O6→ 2 C;H,O + 2 CO2 AH = -16.0 kcal 3. How many kcal would be released from: a. 6.00 mols of C,H12O6 reacting b. 2.13 mols of C¿HO being produced c. 20.0g grams C,H12O6 (180.1559 g/mol) reacting 4. Considering the reaction: O3 + NO → 02 + NO2, circle the impact on reaction rate of the following: a. Increasing concentration of O3: increase / decrease rate b. Decreased concentration of NO: increase / decrease rate c. Increased temperature: increase / decrease ratearrow_forwardStalevo is the trade name for a medication used for Parkinson's disease, which contains L-dopa, carbidopa, and entacapone. a. Draw a Lewis structure for entacapone. b. Which C–C bond in entacapone is the longest? c. Which C–C single bond is the shortest? d. Which C–N bond is the longest? e Which C–N bond is the shortest? f. Use curved arrows to draw a resonance structure that is an equal contributor to the resonance hybrid. g. Use curved arrows to draw a resonance structure that is a minor contributor to the resonance hybrid.arrow_forward4. Identify which of the structures below correspond to a. b. C. d. CH,CH,CH,CH(CH3)2 f. (CH3)2(CH2)2CH(CH3)2 (CH3)2CH₂CH₂CH(CH3)2 CH3(CH2)2CH(CH3)2 e. g. h. H H H H—C—C—C—C | H H H с H H H I C-H CIHarrow_forward
- H₂C a. How many polar bond(s) is (are) present in this molecule? b. What is the most electronegative atom present in this molecule? c. What is the least electronegative atom present in this molecule? N * For the C-0 bond, what is the direction of the dipole moment (from 3+ to 2-)? Use either 'up' or 'down' for your answer inaný 0=6 $ -0 to de % CH3 A hparrow_forward3. Resonance forms of the acetate ion are below. :0: :0: :0: H3C H3C H3C А C a. Provide arrows that show electron movement from A to B and B to C. b. Two of these resonance forms are identical. Which two are actually the same? C. Which is the "least contributing" resonance form (A, B, or C)? Briefly explain your choice. d. Draw the resonance hybrid for the acetate ion (use "delta" &+ or- to show partial charges).arrow_forwardConsider a molecule of methanimine (CH3N) compared to a molecule of methylamine (CH5N). The C-N bond in methanimine is than the C-N bond in methylamine. A. longer and stronger B. longer and weaker C. shorter and stronger D. shorter and weaker E. the same strength and length asarrow_forward
- 8. CH3CCH (propyne or methylacetylene) Projection Drawing: Perspective Drawing: lives a. Predict the angel HCC (the first carbon) CCC. b. Predict the molecular geometry around each carbon atomarrow_forwardWhat is the approximate H−C−O bond angle in formaldehyde, H2C=O? a. 90° b. 109° c. 120° d. 180° Group of answer choices a b c darrow_forward3. How many valence electron does carbon have? А. 1 В. 2 С. 4 D. 6 4. Which of the following is INCORRECT about the number of bonds one C atom can form? A. 2 double bonds B. 1 triple bond, 3 single bonds C. 2 single bonds, 1 double bond D. 3 single bonds, 1 double bondarrow_forward
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