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Mass spectrometry is one of the most versatile and powerful tools chemical analysis because of its capacity to discriminate between atoms of different masses. When a sample containing a mixture of isotopes is introduced into a mass spectrometer, the ratio of the peaks observed reflects the ratio of the percent
An analysis was done on a rock sample to determine its rubidium content. The rubidium content of a portion of rock weighing 0.350 g was extracted, and to the extracted sample was added an additional 29.45 μg of
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EBK GENERAL CHEMISTRY
- An element X bas five major isotopes, which are listed below along with their abundances. What is the element? Isotope Percent Natural Abundance Mass (u) 46x 8.00% 45.95232 47x 7.30% 46.951764 48x 73.80% 47.947947 49x 5.50% 48.947841 50x 5.40% 49.944792arrow_forwardPolystyrene can be prepared by heating styrene with tribromobenzoyl peroxide in the absence of air. A sample prepared by this method has the empirical formula Br3C6cH3(C8H8)n, where the value of n can vary from sample to sample. If one sample has 0.105% Br, what is the value of n?arrow_forwardBoron consists of two isotopes, 10B and 11B. Chlorine also has two isotopes, 35Cl and 37Cl. Consider the mass spectrum of BC13. How many peaks would be present, and what approximate mass would each peak correspond to in the BCl3 mass spectrum?arrow_forward
- The element bromine is Br2, so the mass of a Br2 molecule is the sum of the mass of its two atoms. Bromine has two isotopes. The mass spectrum of Br2 produces three peaks with relative masses of 157.836, 159.834, and 161.832, and relative heights of 6.337, 12.499. and 6.164, respectively. (a) What isotopes of bromine are present in each of the three peaks? (b) What is the mass of each bromine isotope? (c) What is the average atomic mass of bromine? (d) What is the abundance of each of the two bromine isotopes?arrow_forwardTwo basic laws of chemistry are the law of conservation of mass and the law of constant composition. Which of these laws (if any) do the following statements illustrate? (a) Lavoisier found that when mercury(ll) oxide, HgO, decomposes, the total mass of mercury (Hg) and oxygen formed equals the mass of mercury(ll) oxide decomposed. (b) Analysis of the calcium carbonate found in the marble mined in Carrara, Italy, and in the stalactites of the Carlsbad Caverns in New Mexico gives the same value for the percentage of calcium in calcium carbonate. (c) Hydrogen occurs as a mixture of two isotopes, one of which is twice as heavy as the other.arrow_forwardReference Section 5-2 to find the atomic masses of 12C and 13C, the relative abundance of 12C and 13C in natural carbon, and the average mass (in u) of a carbon atom. If you had a sample of natural carbon containing exactly 10,000 atoms, determine the number of 12C and 13C atoms present. What would be the average mass (in u) and the total mass (in u) of the carbon atoms in this 10,000-atom sample? If you had a sample of natural carbon containing 6.0221 1023 atoms, determine the number of 12C and 13C atoms present What would be the average mass (in u) and the total mass (in u) of this 6.0221 1023 atom sample? Given that 1 g = 6.0221 1023 u, what is the total mass of I mole of natural carbon in units of grams?arrow_forward
- The element europium exists in nature as two isotopes: 151Eu has a mass of 150.9196 u and 153Eu has a mass of 152.9209 u. The average atomic mass of europium is 151.96 u. Calculate the relative abundance of the two europium isotopes.arrow_forwardThe age of the universe is unknown, but some conclude from measuring Hubbles constant that the age is about 18 billion years old, which is about four times the age of Earth. If so, calculate the age of the universe in seconds. If you had a sample of carbon with the same number of carbon atoms as there have been seconds since the universe began, determine whether you could measure this sample on a laboratory balance that can detect masses as small as 0.1 mg.arrow_forwardGallium arsenide, GaAs, has gained widespread use in semiconductor devices that convert light and electrical signals in fiber-optic communications systems. Gallium consists of 60.% 69Ga and 40.% 71Ga. Arsenic has only one naturally occurring isotope, 75As. Gallium arsenide is a polymeric material, but its mass spectrum shows fragments with the formulas GaAs and Ga2As2. What would the distribution of peaks look like for these two fragments?arrow_forward
- The density of a mixture of gases may be calculated by summing the products of the density of each gas and the fractional volume of space occupied by that gas. (Note the similarity to the calculation of the molar mass of an element from the isotopic masses and fractional abundances.) Assume dry air with CO2 removed is 20.96% (by volume) oxygen. 78.11% nitrogen, and 0.930% argon. Determine the density of argon.arrow_forwardA compound associated with the odor of garlic on a persons breath has the chemical formula CyH8S and a formula mass of 88.19 amu. What number does y stand for in the chemical formula of the compound?arrow_forward
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