(a)
Interpretation:
Product of the given tertiary
Concept Introduction:
Cope elimination:
When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.
The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an
(b)
Interpretation:
Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.
Concept Introduction:
Cope elimination:
When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.
The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.
(c)
Interpretation:
Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.
Concept Introduction:
Cope elimination:
When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.
The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.
(d)
Interpretation:
Product of the given tertiary amine reacts with hydrogen peroxide followed by heat has to be given.
Concept Introduction:
Cope elimination:
When tertiary amine reacts with hydrogen peroxide, it forms tertiary amine oxides which then undergo a reaction similar to Hoffmann elimination reaction is called Cope elimination.
The nitrogen atom in the tertiary amine acts as a nucleophile and attacks an oxygen atom of peroxide that results in the formation of hydroxyl ammonium ion along with hydroxide ion, this ion under goes an elimination reaction to gives an alkene with tertiary amine.
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- Give the products expected when the following tertiary amines are treated with a peroxyacid and heated.cyclohexyldimethylaminearrow_forwardIndicate whether the following statement is true or false. Aliphatic amines are more basic than ammonia, whereas aromatic amines are less basic than ammonia. When amines are reacted with bases, they form ammonium salts. Benzenesulfonyl chloride or p-toluenesulfonylchloride give N-substituted sulfonamides with primary and secondary amines. Derivative of primary amines is insoluble in dilute NaOHarrow_forwardGive the products expected when the following tertiary amines are treated with a peroxyacid and heated.N,N-diethylhexan-2-aminearrow_forward
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning