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Refer to Table 19.1 to calculate
- +30.9 kJ
- −30.9 kJ
- −185 kJ
- +185 kJ
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Chapter 20 Solutions
Chemistry: Structure and Properties
- An aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forwardUnder standard conditions, what reaction occurs, if any, when each of the following operations is performed? a. Crystals of I2 are added to a solution of NaCl. b. Cl2 gas is bubbled into a solution of NaI. c. A silver wire is placed in a solution of CuCl2 d. An acidic solution of FeSO4 is exposed to air. For the reactions that occur, write a balanced equation and calculate ,G, and K at 25C.arrow_forwardAn aqueous solution of an unknown salt of vanadium is electrolyzed by a current of 2.50 amps for 1.90 hours. The electroplating is carried out with an efficiency of 95.0%, resulting in a deposit of 2.850 g of vanadium. a How many faradays are required to deposit the vanadium? b What is the charge on the vanadium ions (based on your calculations)?arrow_forward
- Three reactions very important to the semiconductor industry are The reduction of silicon dioxide to crude silicon, SiO2(s) + 2 C(s) → Si(s) + 2 CO(g) ΔrH° = 689.9 kJ/mol The formation of silicon tetrachloride from crude silicon, Si(s) + 2 Cl2(g) → SiCl4(g) ΔrH° = −657.01 kJ/mol The reduction of silicon tetrachloride to pure silicon with magnesium, SiCl4(g) + 2 Mg(s) → 2 MgCl2(s) + Si(s) ΔrH° = −625.6 kJ/mol Calculate the overall enthalpy change when 1.00 mol sand, SiO2, changes into very pure silicon by this series of reactions.arrow_forwardOrder the following oxidizing agents by increasing strength under standard-state conditions: Mg2+(aq), Hg2+(aq), Pb2+(aq).arrow_forwardConsider the following cell reaction at 25C. 2Cr(s)+3Fe2+(aq)2Cr3+(aq)+3Fe(s) Calculate the standard cell potential of this cell from the standard electrode potentials, and from this obtain G for the cell reaction. Use data in Appendix C to calculate H; note that Cr(H2O)63+(aq) equals Cr3+(aq). Use these values of H and G to obtain S for the cell reaction.arrow_forward
- One of the few industrial-scale processes that produce organic compounds electrochemically is used by the Monsanto Company to produce1,4-dicyanobutane. The reduction reaction is 2CH2CHCH+2H++2eNC(CH2)4CN The NC(CH2)4CN is then chemically reduced using hydrogen gas to H2N(CH2)6NH2, which is used in the production of nylon. What current must be used to produce 150.kg NC(CH2)4CN per hour?arrow_forwardCalcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forward
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