Concept explainers
(a)
Interpretation:
The complex ion, the counter ions, the electronic configuration of the
Concept introduction:
The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.
(b)
Interpretation:
The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.
Concept introduction:
The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.
(c)
Interpretation:
The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.
Concept introduction:
The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.
Want to see the full answer?
Check out a sample textbook solutionChapter 21 Solutions
EBK CHEMISTRY
- An aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forwardFor each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forward
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning