Physics for Scientists and Engineers, Technology Update, Hybrid Edition (with Enhanced WebAssign Multi-Term LOE Printed Access Card for Physics)
9th Edition
ISBN: 9781305116429
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
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Question
Chapter 21, Problem 21.25P
(a)
To determine
The total heat capacity of the sample at constant volume.
(b)
To determine
The total heat capacity of the sample at constant pressure.
(c)
To determine
The total heat capacity of the sample at constant volume and pressure when the molecule both rotates and vibrate.
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A certain molecule has f degrees of freedom. Show that an ideal gas consisting of such molecules has the following properties: (a) its total internal energy is fnRT/2, (b) its molar specific heat at constant volume is fR/2, (c) its molar specific heat at constant pressure is (f + 2)R/2, and (d) its specific heat ratio is γ = CP/CV = (f + 2)/f.
Railroad tracks are made from segments L = 65 m long at T = 20° C. When the tracks are laid, the engineers leave gaps of width l between adjacent segments to allow for thermal expansion. The coefficient of linear expansion is α = 12 × 10-6 °C-1 and engineers design the tracks to withstand temperatures of Tc = 39.5 degrees.
A) Enter an expression, in terms of given variables, for the minimum gap distance l the engineers must leave for a track rated at temperature Tc.
l=
B)What is the minimum gap distance in meters?
C)
Suppose the engineers forgot to add the gaps at the beginning of 15 segments. How much longer, in meters, would the track be at Tc?
Only answer letters (d) and (e)
a) Using the Maxwell-Boltzmann function, calculate the fraction of argon gas molecules with a speed of 305 m/s at 500 K. (ans: 0.0014)
b) If the system in (a) has 0.46 moles of argon gas, how many molecules have the speed of 305 m/s? (ans: 6.44 x 10-4)
c) Calculate the values of vmp, vavg, and vrms for xenon gas at 298 K. (ans: Vmp=194.2 m/s , Vavg=219.2 m/s , Vrms=237.8 m/s)
d) From the values calculated in (c), label the Boltzmann distribution plot with the approximate locations of vmp, v avg, and vrms
e) What will have a larger speed distribution, helium at 500 K or argon at 300 K? Helium at 300 K or argon at 500 K? Argon at 400 K or argon at 1000 K?
Chapter 21 Solutions
Physics for Scientists and Engineers, Technology Update, Hybrid Edition (with Enhanced WebAssign Multi-Term LOE Printed Access Card for Physics)
Ch. 21 - Two containers hold an ideal gas at the same...Ch. 21 - (i) How does the internal energy of an ideal gas...Ch. 21 - Prob. 21.3QQCh. 21 - Prob. 21.4QQCh. 21 - Cylinder A contains oxygen (O2) gas, and cylinder...Ch. 21 - An ideal gas is maintained at constant pressure....Ch. 21 - Prob. 21.3OQCh. 21 - A helium-filled latex balloon initially at room...Ch. 21 - Prob. 21.5OQCh. 21 - Prob. 21.6OQ
Ch. 21 - A sample of gas with a thermometer immersed in the...Ch. 21 - Prob. 21.8OQCh. 21 - Which of the assumptions below is not made in the...Ch. 21 - Hot air rises, so why does it generally become...Ch. 21 - Prob. 21.2CQCh. 21 - When alcohol is rubbed on your body, it lowers...Ch. 21 - What happens to a helium-filled latex balloon...Ch. 21 - Which is denser, dry air or air saturated with...Ch. 21 - One container is filled with helium gas and...Ch. 21 - Daltons law of partial pressures states that the...Ch. 21 - (a) How many atoms of helium gas fill a spherical...Ch. 21 - A cylinder contains a mixture of helium and argon...Ch. 21 - Prob. 21.3PCh. 21 - In an ultrahigh vacuum system (with typical...Ch. 21 - A spherical balloon of volume 4.00 103 cm3...Ch. 21 - A spherical balloon of volume V contains helium at...Ch. 21 - A 2.00-mol sample of oxygen gas is confined to a...Ch. 21 - Oxygen, modeled as an ideal gas, is in a container...Ch. 21 - Prob. 21.9PCh. 21 - The rms speed of an oxygen molecule (O2) in a...Ch. 21 - A 5.00-L vessel contains nitrogen gas at 27.0C and...Ch. 21 - A 7.00-L vessel contains 3.50 moles of gas at a...Ch. 21 - In a period of 1.00 s, 5.00 1023 nitrogen...Ch. 21 - In a constant-volume process, 209 J of energy is...Ch. 21 - A sample of a diatomic ideal gas has pressure P...Ch. 21 - Review. A house has well-insulated walls. It...Ch. 21 - A 1.00-mol sample of hydrogen gas is healed at...Ch. 21 - A vertical cylinder with a heavy piston contains...Ch. 21 - Calculate the change in internal energy of 3.00...Ch. 21 - A 1.00-L insulated bottle is full of tea at 90.0C....Ch. 21 - Review. This problem is a continuation of Problem...Ch. 21 - A certain molecule has f degrees of freedom. Show...Ch. 21 - In a crude model (Fig. P21.23) of a rotating...Ch. 21 - Why is the following situation impossible? A team...Ch. 21 - Prob. 21.25PCh. 21 - A 2.00-mol sample of a diatomic ideal gas expands...Ch. 21 - During the compression stroke of a certain...Ch. 21 - How much work is required to compress 5.00 mol of...Ch. 21 - Air in a thundercloud expands as it rises. If its...Ch. 21 - Why is the following situation impossible? A new...Ch. 21 - During the power stroke in a four-stroke...Ch. 21 - Air (a diatomic ideal gas) at 27.0C and...Ch. 21 - A 4.00-L sample of a diatomic ideal gas with...Ch. 21 - Prob. 21.34PCh. 21 - Prob. 21.35PCh. 21 - Fifteen identical particles have various speeds:...Ch. 21 - Prob. 21.37PCh. 21 - Prob. 21.38PCh. 21 - Prob. 21.39PCh. 21 - Consider a container of nitrogen gas molecules at...Ch. 21 - Prob. 21.41PCh. 21 - Prob. 21.42PCh. 21 - The law of atmospheres states that the number...Ch. 21 - Prob. 21.44APCh. 21 - Prob. 21.45APCh. 21 - The dimensions of a classroom are 4.20 m 3.00 m ...Ch. 21 - The Earths atmosphere consists primarily of oxygen...Ch. 21 - Prob. 21.48APCh. 21 - An air rifle shoots a lead pellet by allowing high...Ch. 21 - Prob. 21.50APCh. 21 - A certain ideal gas has a molar specific heat of...Ch. 21 - Prob. 21.52APCh. 21 - Review. Oxygen at pressures much greater than 1...Ch. 21 - Prob. 21.54APCh. 21 - Model air as a diatomic ideal gas with M = 28.9...Ch. 21 - Review. As a sound wave passes through a gas, the...Ch. 21 - Prob. 21.57APCh. 21 - In a cylinder, a sample of an ideal gas with...Ch. 21 - As a 1.00-mol sample of a monatomic ideal gas...Ch. 21 - A sample consists of an amount n in moles of a...Ch. 21 - Prob. 21.61APCh. 21 - A vessel contains 1.00 104 oxygen molecules at...Ch. 21 - A pitcher throws a 0.142-kg baseball at 47.2 m/s....Ch. 21 - The latent heat of vaporization for water at room...Ch. 21 - A sample of a monatomic ideal gas occupies 5.00 L...Ch. 21 - Prob. 21.66APCh. 21 - Prob. 21.67APCh. 21 - Prob. 21.68APCh. 21 - Prob. 21.69APCh. 21 - On the PV diagram for an ideal gas, one isothermal...Ch. 21 - Prob. 21.71APCh. 21 - Review, (a) H it has enough kinetic energy, a...Ch. 21 - Prob. 21.73APCh. 21 - Prob. 21.74CPCh. 21 - A cylinder is closed at both ends and has...
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