(a) Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated. Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

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Answer 1

Question

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

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Draw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form asubstituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that canbe used as a synthetic detergent to clean away dirt.

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What carbonyl compound and amine or alcohol are needed to prepare each product?

Answer 2

Question

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 6

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 7

Chapter 21, Problem 21.47P

Interpretation Introduction

(a)

Interpretation: The carbonyl compound and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 8

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 9

Interpretation Introduction

(b)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 10

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 11

Interpretation Introduction

(c)

Interpretation: The carbonyl compound, and alcohol formed by the hydrolysis of the given compound are to be stated.

Concept introduction: Acetals are the groups in which carbon atom is bonded to two OR groups through single bonds. They are used as protecting groups as they are stable enough in neutral to strong basic condition. However, they are unstable in acidic media, and dissociates into corresponding alcohol and carbonyl compound.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Rank the following compounds in order of...Ch. 21 - Prob. 21.2P Ch. 21 - Give the IUPAC name for each aldehyde.Ch. 21 - Prob. 21.4P Ch. 21 - Give the IUPAC name for each ketone.Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - The boiling point of is significantly higher than...Ch. 21 - Which carbonyl group in each pair absorbs at a...Ch. 21 - Problem 21.10 Draw the structure of all...

Solution Summary: The author explains that acetals are the groups in which carbon atom is bonded to two OR groups through single bonds.

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Chapter 21 Solutions