CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 21, Problem 21.84SP
Interpretation Introduction
(a)
Interpretation:
The formula and the name of the given structures needs to be determined.
Concept introduction:
The set of the
Interpretation Introduction
(b)
Interpretation:
The linkage isomer structures needs to be determined.
Concept introduction:
The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.
Interpretation Introduction
(c)
Interpretation:
The ionization isomer structures needs to be determined.
Concept introduction:
The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.
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(b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.
A complex ion is formed from one Fe*, two CN and four NO, ions.
(a)
What is the structural formula and name of the complex ion?
(b)
Identify the type of isomerism and draw the isomer structures exhibited by the
complex ion.
(c)
Draw the molecular orbital diagram and calculate the CFSE for the complex ion.
A coordination compound has the following composition (by mass %): 23.53% Co; 42.47% Cl, and
34.00% NH3. When 4.91 g of the compound is dissolved in 75.0 mL of deionized water, and the solution
is reacted with an excess of AGNO; solution, it yields 5.60 g of AgCl precipitate.
(a) Determine the empirical formula of the compound and write in the form of Co(NH;),Cl, (where x and
24.
y
are simple integers), and calculate its molar mass. (Assume the compound contains only one Co atom).
(b) Deduce the number of chloride (Cl) as counter ions and as ligand, respectively. (c) Write the Werner's
formula of the compound and give its systematic name.
(Answers: (a) Co(NH3);C13; molar mass = 250.43 g/mol; (b) 2 Cl are counter ions and one is ligand;
(c) [Co(NH3);CI]Cl2 = pentaammonechlorocobalt(III) chloride)
Chapter 21 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 21 - Prob. 21.1PCh. 21 - Prob. 21.2ACh. 21 - Prob. 21.3PCh. 21 - Prob. 21.4ACh. 21 - Prob. 21.5PCh. 21 - Prob. 21.6ACh. 21 - Prob. 21.7PCh. 21 - Prob. 21.8ACh. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A
Ch. 21 - Prob. 21.11PCh. 21 - How many diastereoisomer are possible for the...Ch. 21 - Prob. 21.13PCh. 21 - Consider the following ethylenediamine complexes...Ch. 21 - Prob. 21.15PCh. 21 - Prob. 21.16ACh. 21 - Draw a crystal field energy-level diagram and...Ch. 21 - Prob. 21.18ACh. 21 - Prob. 21.19PCh. 21 - Prob. 21.20ACh. 21 - Prob. 21.21PCh. 21 - Prob. 21.22PCh. 21 - Prob. 21.23PCh. 21 - Prob. 21.24PCh. 21 - Prob. 21.25PCh. 21 - Prob. 21.26CPCh. 21 - Prob. 21.27CPCh. 21 - Prob. 21.28CPCh. 21 - Prob. 21.29CPCh. 21 - CH2 Classify the following ligands as monodentate,...Ch. 21 - Prob. 21.31CPCh. 21 - Prob. 21.32CPCh. 21 - Prob. 21.33CPCh. 21 - Consider the following ethylenediamine complexes....Ch. 21 - Prob. 21.35CPCh. 21 - Prob. 21.36SPCh. 21 - Prob. 21.37SPCh. 21 - Prob. 21.38SPCh. 21 - Prob. 21.39SPCh. 21 - Prob. 21.40SPCh. 21 - Prob. 21.41SPCh. 21 - Prob. 21.42SPCh. 21 - Prob. 21.43SPCh. 21 - Prob. 21.44SPCh. 21 - Prob. 21.45SPCh. 21 - Prob. 21.46SPCh. 21 - Prob. 21.47SPCh. 21 - Prob. 21.48SPCh. 21 - Prob. 21.49SPCh. 21 - Prob. 21.50SPCh. 21 - Prob. 21.51SPCh. 21 - Prob. 21.52SPCh. 21 - Prob. 21.53SPCh. 21 - Prob. 21.54SPCh. 21 - Prob. 21.55SPCh. 21 - Prob. 21.56SPCh. 21 - Prob. 21.57SPCh. 21 - Prob. 21.58SPCh. 21 - Prob. 21.59SPCh. 21 - Prob. 21.60SPCh. 21 - Prob. 21.61SPCh. 21 - What is the coordination number of the metal in...Ch. 21 - Prob. 21.63SPCh. 21 - Prob. 21.64SPCh. 21 - Prob. 21.65SPCh. 21 - Prob. 21.66SPCh. 21 - Prob. 21.67SPCh. 21 - Prob. 21.68SPCh. 21 - Prob. 21.69SPCh. 21 - Draw the structure of the iron oxalate complex...Ch. 21 - Prob. 21.71SPCh. 21 - Prob. 21.72SPCh. 21 - Prob. 21.73SPCh. 21 - Prob. 21.74SPCh. 21 - Prob. 21.75SPCh. 21 - Prob. 21.76SPCh. 21 - Prob. 21.77SPCh. 21 - What is the systematic name for each of the...Ch. 21 - Prob. 21.79SPCh. 21 - Prob. 21.80SPCh. 21 - Prob. 21.81SPCh. 21 - Prob. 21.82SPCh. 21 - Prob. 21.83SPCh. 21 - Prob. 21.84SPCh. 21 - Prob. 21.85SPCh. 21 - Prob. 21.86SPCh. 21 - Prob. 21.87SPCh. 21 - Prob. 21.88SPCh. 21 - Prob. 21.89SPCh. 21 - Prob. 21.90SPCh. 21 - Prob. 21.91SPCh. 21 - Prob. 21.92SPCh. 21 - Prob. 21.93SPCh. 21 - Prob. 21.94SPCh. 21 - Prob. 21.95SPCh. 21 - Prob. 21.96SPCh. 21 - Prob. 21.97SPCh. 21 - Prob. 21.98SPCh. 21 - Prob. 21.99SPCh. 21 - Prob. 21.100SPCh. 21 - Prob. 21.101SPCh. 21 - Prob. 21.102SPCh. 21 - Prob. 21.103SPCh. 21 - Prob. 21.104SPCh. 21 - Prob. 21.105SPCh. 21 - Prob. 21.106SPCh. 21 - Prob. 21.107SPCh. 21 - Prob. 21.108SPCh. 21 - Prob. 21.109SPCh. 21 - Prob. 21.110SPCh. 21 - Prob. 21.111SPCh. 21 - Prob. 21.112SPCh. 21 - Prob. 21.113SPCh. 21 - Prob. 21.114SPCh. 21 - Prob. 21.115SPCh. 21 - Prob. 21.116SPCh. 21 - Prob. 21.117SPCh. 21 - Prob. 21.118SPCh. 21 - Prob. 21.119SPCh. 21 - Prob. 21.120SPCh. 21 - Prob. 21.121SPCh. 21 - Prob. 21.122SPCh. 21 - Prob. 21.123SPCh. 21 - Prob. 21.124SPCh. 21 - Prob. 21.125SPCh. 21 - Prob. 21.126SPCh. 21 - Prob. 21.127SPCh. 21 - Prob. 21.128SPCh. 21 - Prob. 21.129SPCh. 21 - Prob. 21.130MPCh. 21 - Nickel(II) complexes with the formula NiX2L2 ,...Ch. 21 - Prob. 21.132MPCh. 21 - The amount of paramagnetism for a first-series...Ch. 21 - Prob. 21.134MPCh. 21 - Prob. 21.135MPCh. 21 - Prob. 21.136MPCh. 21 - Prob. 21.137MPCh. 21 - Prob. 21.138MPCh. 21 - Chromium forms three isomeric compounds A, B, and...Ch. 21 - Prob. 21.140MPCh. 21 - Prob. 21.141MPCh. 21 - Prob. 21.142MP
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