Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 21, Problem 60E
Explain why the ether with formula
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Why can't ethers hydrogen bond? Can't an ether and an alcohol engage in hydrogen bonding?
Why are lower molecular weight alcohols more soluble in water than higher molecular weight alcohols?
3. Dimethyl ether, H3C-O-CH3, is a gas at room temperature and insoluble in water. Draw a structural isomer of dimethyl ether that is much more soluble in water and explain the basis of its increased water solubility.
Chapter 21 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 21 - Prob. 1ECh. 21 - Prob. 2ECh. 21 - Prob. 3ECh. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - Prob. 8ECh. 21 - Prob. 9ECh. 21 - Prob. 10E
Ch. 21 - Prob. 11ECh. 21 - Prob. 12ECh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Is the general formula of a cycloalkanes the same...Ch. 21 - Prob. 24ECh. 21 - Draw the skeleton diagram of cyclopentane.Ch. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - What is the difference in bonding and in the...Ch. 21 - Prob. 38ECh. 21 - Draw the structural formula of trichloroethene, a...Ch. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Give the IUPAC name of the following molecule:Ch. 21 - Give the IUPAC name of the following molecule:Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - Write an equation for the hydrogenation of...Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Explain why the ether with formula C2H6O is very...Ch. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Distinguish precisely, and in scientific terms,...Ch. 21 - Prob. 96ECh. 21 - What is the difference in bonding and in general...Ch. 21 - Draw all isomers of C4H8.Ch. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 21.1TCCh. 21 - Prob. 21.2TCCh. 21 - Prob. 21.3TCCh. 21 - Prob. 21.4TCCh. 21 - Prob. 21.5TCCh. 21 - Prob. 21.6TCCh. 21 - Prob. 21.7TCCh. 21 - Prob. 21.8TCCh. 21 - Prob. 21.9TCCh. 21 - Prob. 21.10TCCh. 21 - Prob. 21.11TCCh. 21 - Prob. 21.12TCCh. 21 - Prob. 1CLECh. 21 - Prob. 2CLECh. 21 - Prob. 3CLECh. 21 - Prob. 4CLECh. 21 - Prob. 5CLECh. 21 - Prob. 6CLECh. 21 - Prob. 7CLECh. 21 - Prob. 8CLECh. 21 - Prob. 9CLECh. 21 - Prob. 10CLE
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- Which of the following statements concerning the boiling points of isomeric alcohols is true? a. The relative boiling points of isomeric alcohols are determined primarily by the different shapes of the molecules b. Both statements are incorrect c. The relative boiling points of isomeric alcohols are determined by the different number of hydrogen bonds that they can form d. Both statements are correctarrow_forwardWhy do alcohols have boiling points much higher than hydrocarbons of similar molecular weight? a. Alcohols have greater van der Waals attraction forces.b. Alcohol molecules have greater molecular symmetry.c. Hydrogen bonds must be broken in the process of volatilization.d. Alcohols must overcome greater ionic forces in the process of volatilization.arrow_forwardExplain the following: a. 1-Hexanol has a higher boiling point than 3-hexanol. b. Diethyl ether has very limited solubility in water, but tetrahydrofuran is completely soluble.arrow_forward
- 1. Which of the following compounds is most soluble in water: (a) dimethyl ether, (b) diethyl ether or (c) hexane? 2. Give the IUPAC names for the following cyclic ethers. Refer to the image.arrow_forwardWhat is the importance of making sure that the correct process is done in the process of fermentation in making alcohols?arrow_forwardSuppose the hydrogens on the OH groups in glucose were replaced with methyl groups, CH3. Would you expect the water solubility of the resulting molecule to be higher than, lower than, or about the same as glucose?arrow_forward
- Classify each statement as a property of ethers, alcohols, or both ethers and alcohols. 1. These compounds cannot form hydrogen bonds between themselves, but they can form hydrogen bonds with other compounds containing an O−HO−H , N−HN−H , or F−HF−H bond, such as water.2. These compounds are water soluble if they have fewer than four carbon atoms.3. When comparing ethers and alcohols of similar molecular weights, these compounds have the higher boiling point. alcohols both ethers and alcohols ethersarrow_forwardwhat is the trend in the oxidizability of alcohols?arrow_forwardALCOHOLS 1. WHY IS ETHANOL MORE SOLUBLE IN WATER THAN 1-HEXANOL? 2. WHAT IS DENATURED ALCOHOL? AND WHY IS ALCOHOL DENATURED?  ETHER 1. WHY DOES DIETHYL ETHER HAVE MUCH LOWER BOILING POINT THAN 1-BUTANOL?arrow_forward
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