Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 21.1, Problem 1P

Draw the structure for each of the following:

  1. a. dCDP
  2. b. dTTP
  3. c. dUMP
  4. d. UDP
  5. e. guanosine
  6. f. adenosine 5’-monophosphate
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Draw the structure for each of the following: a. dCDP b. dTTP c. dUMP d. UDP e. guanosine triphosphate f. adenosine 5’-monophosphate
47. A pentapeptide on complete hydrolysis yields 3 moles of glycine (R=H), 1 mole of alanine (R=CH3) and 1 mole of serine (R=CH2OH). On partial hydrolysis, the fragments are ala-gly, gly-ala and gly-ser. The pentapeptide is negative to the Sanger reaction. Draw a possible structure for the pentapeptide.
Arginine and lysine side chains fit into trypsin’s binding pocket (Figure 22.5). One of these side chains forms a direct hydrogen bond with serine and an indirect hydrogen bond (mediated through a water molecule) with aspartate. The other side chain forms direct hydrogen bonds with both serine and aspartate. Which is which?

Chapter 21 Solutions

Essential Organic Chemistry (3rd Edition)

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