a)
Interpretation:
To prepare the esters for the given corresponding acids.
Concept introduction:
We introspect the two parts of the given ester.
b)
Interpretation:
To prepare the esters for the given corresponding acids.
Concept introduction:
We begin by observing the two parts of the tanget ester given. The acyl part comes from the carboxylic acid while the OR’ part viz –OCH3 comes from the alcohol. In this example, the tanget ester given is methyl butanoate .so it can be prepared by treating butanoic acid with methanol.
c)
Interpretation:
To prepare the esters for the given corresponding acids.
Concept introduction:
We observe the two parts of the tanget ester molecule given. Its acyl part comes from the carboxylic acid while the OR’ part viz –O-CH(CH3)2 comes from the alcohol.
In this example, the tanget ester given is isopropyl cyclopentane carboxylate. So it can be prepared by treating cyclopentone carboxylic acid with isopropyl alcohol.
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Chapter 21 Solutions
Bundle: Organic Chemistry, Loose-leaf Version, 9th + LMS Integrated for OWLv2, 4 terms (24 months) Printed Access Card
- Predict the products obtained from the reaction of triolein with the following reagents.(a) NaOH in waterarrow_forwardPredict the products obtained from the reaction of triolein with the following reagents. ozone, then dimethyl sulfidearrow_forwardHow would you prepare the following ketones using an acetoacetic ester synthesis?arrow_forward
- show how to make the following from acetoacetic ester and show stepsarrow_forwardPropose a reaction for the formation of the following products involving esterformation.arrow_forwardPredict the products obtained from the reaction of triolein with the following reagents.(a) NaOH in water (b) H2 and a nickel catalyst (c) Br2 in CCl4(d) ozone, then dimethyl sulfide (e) warm KMnO4 in water (f) CH2I2>Zn(Cu)arrow_forward
- Show the products you would expect to obtain from reaction of glyceryl Trioleate with the following reagents: (a) Excess Br2 in CH2Cl2 (b) H2/Pd (c) NaOH/H2O (d) O3, then Zn/CH3CO2H (e) LiAlH4, then H3O1 (f) CH3MgBr, then H3O1arrow_forwardShow how you would synthesize the following esters from appropriate acyl chloridesand alcohols. (c) benzyl benzoate (d) cyclopropyl cyclohexanecarboxylatearrow_forwardShow how you would synthesize the following esters from appropriate acyl chloridesand alcohols.(a) ethyl propionate (b) phenyl 3-methylhexanoatearrow_forward
- Show how the malonic ester synthesis is used to prepare 2-benzylbutanoic acid.Sarrow_forwardCarboxylic acids can be prepared from alkyl halides by two different routes, with the use of cyanide ion and Grignard reagent. How would you prepare phenylacetic acid (PhCH2CO2H) from benzyl bromide (PhCH2Br) using the mentioned routesarrow_forwardShow how you would synthesize the following esters from appropriate acyl chloridesand alcohols. e) tert-butyl acetate (f) diallyl succinatearrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT