CHEM: STRUC & PROP (LL) VOL 2 >C PKG<
2nd Edition
ISBN: 9780137390922
Author: Tro
Publisher: PEARSON C
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Chapter 22, Problem 13E
Interpretation Introduction
To determine: Zn2+ is white and Cu2+ is green or blue
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Write the formula for diaquadibromoplatinum (II).
C [Pt(H2O)2Br2]2
C [Pt(H2O)2]Br2*1
C [Pt(H2O)2]Br2
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C (Pt(H2O)2Br2]
C PE(H,O),Bra]*1
[Cu (NH3) 4]
SO4.H2O
Discuss the
magnetic property of
the compound.
Consider the reactions
1. [Cr(H2O)6]** + [C©CI(NH3)s]* → [Co(NH3)s(H2O)]²* + [CrCl(H2O)s]**
2. [Fe(CN)6]* + [Mo(CN)s]-→ [Fe(CN)6]³¯ + [Mo(CN)8]*
Which one of the following is the correct statement?
(i) Both involve an inner sphere mechanism
(ii) Both involve an outer sphere mechanism
(iii) Reaction 1 follows inner sphere and reaction 2 follows outer sphere mechanism
(iv) Reaction 1 follows outer sphere and reaction 2 follows inner sphere mechanism
(A) i
(B) ii
(C) iv
(D) ii
Chapter 22 Solutions
CHEM: STRUC & PROP (LL) VOL 2 >C PKG<
Ch. 22 - When a transition metal atom forms an ion, which...Ch. 22 - Explain why transition metals exhibit multiple...Ch. 22 - Why is the +2 oxidation state so common for...Ch. 22 - Explain why atomic radii of elements in the third...Ch. 22 - Gold is the most electronegative transition metal....Ch. 22 - Prob. 6ECh. 22 - Prob. 7ECh. 22 - Explain the differences between each pair of...Ch. 22 - Prob. 9ECh. 22 - Prob. 10E
Ch. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Prob. 17ECh. 22 - Write the ground state electron configuration for...Ch. 22 - Determine the highest possible oxidation state for...Ch. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - Prob. 27ECh. 22 - Write the formula and the name of each complex ion...Ch. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Most of the second-row transition metals do not...Ch. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Hexacyanomanganate(III) ion is a low-spin complex....Ch. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Calculate the solubility of Zn(OH)2(s) in 2.0 M...Ch. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Have each group member choose a row of the...Ch. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Many aqueous solutions of complex ions display...Ch. 22 - What is the electron configuration of the Cu+ ion?...Ch. 22 - Prob. 2SAQCh. 22 - Prob. 3SAQCh. 22 - Prob. 4SAQCh. 22 - Prob. 5SAQCh. 22 - Prob. 6SAQCh. 22 - Prob. 7SAQCh. 22 - Estimate the crystal field splitting energy (in...Ch. 22 - Use crystal field theory to determine the number...Ch. 22 - Prob. 10SAQ
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- Explain the Jan teller distortion in [Cu(H2O)6]²+.arrow_forwardWhen orange solution containing Cr2O72–ion is treated with an alkali, a yellow solution is formed and when H+ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?arrow_forwardGive the electron configuration and the number of unpaired electrons for: (a) Cr3+; (b) Ti4+; (c) Co3+; (d) Ta2+.arrow_forward
- [CrCl3(NMe3)2] What is the name of the compound?arrow_forward2) a) Write the chemical equation for the dissociation of [Cu(NH3)4]2+ d) Calculate the concentration of free, uncomplexed Cu2+ ions in a solution that originally contains a total of 1.0 × 10-3 M copper (II) ions and an equilibrium concentration of 0.10 M NH3.arrow_forwardProvide systematic names for each of the following compoundsA. (NH4)2[CuCl4]B. [Co(NH3)5(OH2)]Br3C. K3[Cr(CO)4]D. K2[NiF6]E. [Cu(NH3)4](ClO4)2arrow_forward
- explain how can you practically detect the presence of copper ions in Cu2(02C204)4.2H2O?arrow_forward3. Consider the blue-colored compound, [Cr(H₂O)]3³ and the yellow-colored compound, [Cr(CN)6]³. Calculate their magnetic moments and discuss their magnetic properties and their color.arrow_forwardPyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a monodentate or bidentate ligand? (b) For the equilibrium reaction [Ru(py),(bipy)]²+ + 2 py = [Ru(py),J* + bipy would you predict the equilibrium constant to be larger or smaller than one?arrow_forward
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