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Concept explainers
(a)
Interpretation:
The chemical equation of nitric oxide with ozone and its reverse reaction has to be written.
(a)
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Explanation of Solution
In the stratosphere, nitric oxide destroys ozone by forming nitrogen dioxide and oxygen. The chemical equation is given by
(b)
Interpretation:
The general rate law for given reaction has to be written.
(b)
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Explanation of Solution
The
(c)
Interpretation:
The standard free energy of given reaction has to be written.
Concept Introduction:
Free energy,
(c)
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Explanation of Solution
The standard Gibb’s free energy is calculated by substituting change in enthalpy and change in entropy of the reaction.
(d)
Interpretation:
The ratio of rate constants is consistent with equilibrium constant at given temperature has to be calculated.
Concept Introduction:
Free energy,
(d)
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Explanation of Solution
At equilibrium, the forward rate equals the reverse rate and their ratio equals the equilibrium constant:
Therefore, the ratio of rate constants is
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Chapter 22 Solutions
CHEMISTRY >CUSTOM<
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