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Concept explainers
(a)
Interpretation: The structures for the products of the given oxidation reactions of alcohols are to be drawn.
Concept introduction: Alcohols are oxidized to either
To determine: The structure for the product of the given oxidation reaction of alcohol.
(b)
Interpretation: The structures for the products of the given oxidation reactions of alcohols are to be drawn.
Concept introduction: Alcohols are oxidized to either aldehyde or carboxylic acids depending upon the reaction condition. When the formation of carboxylic acids is required, primary alcohol is first oxidizing to aldehyde which is then further oxidizes to give carboxylic acids. Secondary alcohols can be oxidized into ketones and tertiary alcohols do not undergo this type of oxidation.
To determine: The structure for the product of the given oxidation reaction of alcohol.
(c)
Interpretation: The structures for the products of the given oxidation reactions of alcohols are to be drawn.
Concept introduction: Alcohols are oxidized to either aldehyde or carboxylic acids depending upon the reaction condition. When the formation of carboxylic acids is required, primary alcohol is first oxidizing to aldehyde which is then further oxidizes to give carboxylic acids. Secondary alcohols can be oxidized into ketones and tertiary alcohols do not undergo this type of oxidation.
To determine: The structure for the product of the given oxidation reaction of alcohol.
(d)
Interpretation: The structures for the products of the given oxidation reactions of alcohols are to be drawn.
Concept introduction: Alcohols are oxidized to either aldehyde or carboxylic acids depending upon the reaction condition. When the formation of carboxylic acids is required, primary alcohol is first oxidizing to aldehyde which is then further oxidizes to give carboxylic acids. Secondary alcohols can be oxidized into ketones and tertiary alcohols do not undergo this type of oxidation.
To determine: The structure for the product of the given oxidation reaction of alcohol.
(e)
Interpretation: The structures for the products of the given oxidation reactions of alcohols are to be drawn.
Concept introduction: Alcohols are oxidized to either aldehyde or carboxylic acids depending upon the reaction condition. When the formation of carboxylic acids is required, primary alcohol is first oxidizing to aldehyde which is then further oxidizes to give carboxylic acids. Secondary alcohols can be oxidized into ketones and tertiary alcohols do not undergo this type of oxidation.
To determine: The structure for the product of the given oxidation reaction of alcohol.
(f)
Interpretation: The structures for the products of the given oxidation reactions of alcohols are to be drawn.
Concept introduction: Alcohols are oxidized to either aldehyde or carboxylic acids depending upon the reaction condition. When the formation of carboxylic acids is required, primary alcohol is first oxidizing to aldehyde which is then further oxidizes to give carboxylic acids. Secondary alcohols can be oxidized into ketones and tertiary alcohols do not undergo this type of oxidation.
To determine: The structure for the product of the given oxidation reaction of alcohol.
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Chapter 22 Solutions
Study Guide for Zumdahl/Zumdahl/DeCoste’s Chemistry, 10th Edition
- Consider the following reactions: When C5H12 is reacted with Cl2(g) in the presence of ultraviolet light, four different monochlorination products form. What is the structure of C5H12 in this reaction? When C4H8 is reacted with H2O, a tertiary alcohol is produced as the major product. What is the structure of C4H8 in this reaction? When C7H12 is reacted with HCl, 1-chloro-1-methylcyclohexane is produced as the major product. What are the two possible structures for C7H12 in this reaction? When a hydrocarbon is reacted with water and the major product of this reaction is then oxidized, acetone (2-propanone) is produced. What is the structure of the hydrocarbon in this reaction? When C5H12O is oxidized, a carboxylic acid is produced. What are the possible structures for C5H12O in this reaction?arrow_forwardamong the compounds shown in the linked image, identify the primary and secondary alcohols and then draw the chemical structure of the aldehyde or ketone produced when these alcohols are oxidized. write like this: primary alcohol product of oxidizing primary alcohol secondary alcohol product of oxidizing secondary alcoholarrow_forwardWhat is the structural difference between primary, secondary, and tertiary alcohols?arrow_forward
- Secondary alcohols can be oxidized to give aldehyde and tertiary alcohols oxidized to give ketones. O True O Falsearrow_forwardExplain what is meant by oxidation in organic moleculesand provide an example of an oxidation reaction involving an aldehydearrow_forwardIn an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.arrow_forward
- Please provide the reagents, reactants, and/or the products for the following reactions.arrow_forwardWhen benzene enters the body, it is oxidized to phenol (C 6H 5OH). What is the purpose of this oxidation reaction?arrow_forwardIn organic chemistry, oxidation reactions A transform aldehydes into ketones B decrease the oxidation number of the elements involved C increase the number of carbon-oxygen bonds D) convert ketones into carboxylic acids E produce aldehydes from secondary alcoholsarrow_forward
- Briefly describe the preparation of alcohols from ketones, and the preparation of alcohols from esters, each using the same Grignard reagent CH3CH2MgCl. Show an example reaction equation involving your own chosen ketone and ester molecules,respectively, to illustrate your descriptionarrow_forward1,3-Propanediol, HOCH₂CH₂CH₂OH, is a diol used as a building block in the production of polymers for use in adhesives and coatings. Draw the condensed structure of the most oxidized product formed after the oxidation of 1,3-propanediol.arrow_forward2. An unknown organic compound has the molecular formula C4H&O. It resists oxidation and it can be reduced with H2 to form an alcohol. Draw the structure for the compound and write equations for the reactions described. Name the reactant and product. 3. Draw the structures for 2,3-dimethylhexanal undergoing the following reactions: Oxidation Reduction with H2 Draw the structures for 2-methyl-3-hexanol undergoing the following reactions: Intramolecular dehydration Oxidation Rank the following from lowest to highest boiling point. Explain your ranking. Butanal, 1-butanol, butane Both ethane and ethanol contain 2 carbon atoms. Ethane is a gas at room temperature and is insoluble in water, whereas ethanol is a liquid at room temperature and is very soluble. Explain the reasons for the differences in the properties of these compounds.arrow_forward
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