MASTERING CHEMISTY NVCC ACCESS CODE
1st Edition
ISBN: 9780136444459
Author: Tro
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Videos
Question
Chapter 22, Problem 84E
Interpretation Introduction
Interpretation:
The electronic configuration with orbital diagram including high spin and low spin possibility from d1 to d10.
Concept introduction:
The effect of strong field and weak field ligand on the electronic configuration depend upon the number of ligand present or the geometry of the complex i.e. tetrahedral or octahedral. For tetrahedral complexes the effect of ligand field to generate high spin or low spin complex is seen from d3 to d6 and for octahedral complex it is seen from d4 to d7 system. For octahedral complexes in presence of the ligand field the five (5) degenerate orbitals of d-orbital divided in t2g and eg whereas for tetrahedral complexes it divides into e and t2 orbitals.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Divide the electron configurations d1 through d10 among the groupmembers such that every configuration is assigned to at least twogroup members. Working individually, draw the orbital diagram forthe configurations assigned to you, including both high-spin andlow-spin diagrams where possible. Present your diagrams to yourgroup. Combine all diagrams into one set for the group.
True or False:
Elements exists in various oxidation states in the second and third transition series due to the availability of various electrons in the 3d and 6s subshells.
D-block elements could react with the orbitals of the neighboring ligands because of the existence of vacant and low energy orbitals
All halogens have very pungent odors and can cause inflammation of the mucous membranes.
What do you mean by ligands?
Chapter 22 Solutions
MASTERING CHEMISTY NVCC ACCESS CODE
Ch. 22 - When a transition metal atom forms an ion, which...Ch. 22 - Explain why transition metals exhibit multiple...Ch. 22 - Why is the +2 oxidation state so common for...Ch. 22 - Explain why atomic radii of elements in the third...Ch. 22 - Gold is the most electronegative transition metal....Ch. 22 - Prob. 6ECh. 22 - Prob. 7ECh. 22 - Explain the differences between each pair of...Ch. 22 - Prob. 9ECh. 22 - Prob. 10E
Ch. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Prob. 17ECh. 22 - Write the ground state electron configuration for...Ch. 22 - Determine the highest possible oxidation state for...Ch. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - Prob. 27ECh. 22 - Write the formula and the name of each complex ion...Ch. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Most of the second-row transition metals do not...Ch. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Hexacyanomanganate(III) ion is a low-spin complex....Ch. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Calculate the solubility of Zn(OH)2(s) in 2.0 M...Ch. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Have each group member choose a row of the...Ch. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Many aqueous solutions of complex ions display...Ch. 22 - What is the electron configuration of the Cu+ ion?...Ch. 22 - Prob. 2SAQCh. 22 - Prob. 3SAQCh. 22 - Prob. 4SAQCh. 22 - Prob. 5SAQCh. 22 - Prob. 6SAQCh. 22 - Prob. 7SAQCh. 22 - Estimate the crystal field splitting energy (in...Ch. 22 - Use crystal field theory to determine the number...Ch. 22 - Prob. 10SAQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw an octahedral and tetrahedral crystal field splitting diagram for Co3+ (paramagnetic) and label the d- orbitals.arrow_forwardexplain why heavier lanthanides form more stable complexes than lighter onesarrow_forward4. For each of the following transition metal complex ions : see image (i) Draw the structure of the transition metal complex ion. Show the charge on the complex in your structure.(ii) Give the oxidation state of the metal.(iii) State whether the complex is high spin or low spin or not applicable. Providereasons for your answer.(iv) Draw the arrangement of d-electrons in the ground state. Label the orbital sets.(v) Calculate the LFSE (in units of ∆o or ∆T) for each complexarrow_forward
- Predict the number of unpaired electrons for each of the following: a) a high-spin octahedral d6 complex b) a low-spin tetrahedral d4 complex c) [Co(CN)6]3- d) [Cr(Cl)6]4-arrow_forwardwhy d³ and d⁸ high spin complexes are more stable than other configurations?arrow_forwardWhat is a Chelate ligand? Give one example.arrow_forward
- How many bonds could each of the following chelating ligands form with a metal ion? acetylacetone (acacH), a common ligand in organometallic catalysts:________ bonds diethylenetriamine, used in a variety of industrial processes: ________ bonds salen, a common ligand for chiral organometallic catalysts: ________ bonds porphine, often used in supermolecular chemistry as well as catalysis; biologically, porphine is the basis for many different types of porphyrin-containing proteins, including heme proteins: _________bondsarrow_forwardExplain the effect of the presence of a ring structure on the stability of complex compoundsarrow_forwardWhat is the most crucial feature that a molecule should have so that it can be considered a ligand? Presence of at least one pair of unshared electrons Presence of a hydrogen atom Presence of an unfilled d orbital Presence of an acidic grouparrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Lanthanoids and its Position in Periodic Table - D and F Block Elements - Chemistry Class 12; Author: Ekeeda;https://www.youtube.com/watch?v=ZM04kRxm6tY;License: Standard YouTube License, CC-BY