ORGANIC CHEM LOOSE LEAF W/ FREE SOLUTI
ORGANIC CHEM LOOSE LEAF W/ FREE SOLUTI
9th Edition
ISBN: 9780134588902
Author: Wade
Publisher: PEARSON
bartleby

Concept explainers

Question
Book Icon
Chapter 23, Problem 23.46SP

(a)

Interpretation Introduction

Interpretation:

The Fisher projection of the open chain of glucose is to be drawn.

Concept introduction:

The most abundant monsaccharide is glucose. Six carbon atoms are present in the Fisher projection of the open chain of glucose. Fisher projections are used to represent the open chain form of sugars.

(a)

Expert Solution
Check Mark

Answer to Problem 23.46SP

The Fisher projection of the open chain of glucose is shown in Figure 1.

Explanation of Solution

The Fisher projection of the open chain of glucose is shown below. Glucose is an aldose because it a sugar with an aldehyde group. Fisher projections are used to draw the structure of carbohydrates.

ORGANIC CHEM LOOSE LEAF W/ FREE SOLUTI, Chapter 23, Problem 23.46SP , additional homework tip  1

Figure 1

(b)

Interpretation Introduction

Interpretation:

The most stable conformation of the most stable pyranose anomer is to be drawn.

Concept introduction:

Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are down in the cyclic structure while groups on the left side are up.

(b)

Expert Solution
Check Mark

Answer to Problem 23.46SP

The most stable conformation of the most stable pyranose anomer is shown in Figure 2.

Explanation of Solution

The most stable conformation of the most stable pyranose anomer is shown in Figure 2. In βD(+) glucopyranose, all the OH groups are present on equatorial position.

ORGANIC CHEM LOOSE LEAF W/ FREE SOLUTI, Chapter 23, Problem 23.46SP , additional homework tip  2

Figure 2

(c)

Interpretation Introduction

Interpretation:

The most stable conformation of the most stable pyranose anomer is to be drawn.

Concept introduction:

Cyclic monosaccharides are drawn with the help of Fisher projection. The groups on the right side of fisher projection are down in the cyclic structure while groups on the left side are up.

(c)

Expert Solution
Check Mark

Answer to Problem 23.46SP

The Haworth projection of the most stable pyranose anomer is shown in Figure 3.

Explanation of Solution

The Haworth projection of the most stable pyranose anomer is shown below.

ORGANIC CHEM LOOSE LEAF W/ FREE SOLUTI, Chapter 23, Problem 23.46SP , additional homework tip  3

Figure 3

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Chapter 23 Solutions

ORGANIC CHEM LOOSE LEAF W/ FREE SOLUTI

Ch. 23.4 - Prob. 23.11PCh. 23.5 - Prob. 23.12PCh. 23.5 - Prob. 23.13PCh. 23.6 - Prob. 23.14PCh. 23.6 - Prob. 23.15PCh. 23.7 - Prob. 23.16PCh. 23.7 - Prob. 23.17PCh. 23.7 - Two sugars, A and B, are known to be glucose and...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Prob. 23.20PCh. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22PCh. 23.8 - Prob. 23.23PCh. 23.8 - Prob. 23.24PCh. 23.9 - a. Show the product that results when fructose is...Ch. 23.9 - Prob. 23.26PCh. 23.9 - Prob. 23.27PCh. 23.9 - Prob. 23.28PCh. 23.10 - Prob. 23.29PCh. 23.10 - Prob. 23.30PCh. 23.10 - Prob. 23.31PCh. 23.11 - Prob. 23.32PCh. 23.11 - The Wohl degradation, an alternative to the Ruff...Ch. 23.11 - Prob. 23.34PCh. 23.11 - Prob. 23.35PCh. 23.12A - Prob. 23.36PCh. 23.12A - Give an equation to show the reduction of Tollens...Ch. 23.12A - Prob. 23.38PCh. 23.12B - Prob. 23.39PCh. 23.12C - Prob. 23.40PCh. 23.12C - Prob. 23.41PCh. 23.13A - Prob. 23.42PCh. 23.15 - Cytosine, uracil, and guanine have tautomeric...Ch. 23.15 - a. An aliphatic aminoglycoside is relatively...Ch. 23.16C - Prob. 23.45PCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - Prob. 23.49SPCh. 23 - Prob. 23.50SPCh. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw the structure of a four-residue segment of...Ch. 23 - Retroviruses like HIV, the pathogen responsible...Ch. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SP
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Text book image
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Text book image
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Text book image
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning