CHEMISTRY: MOLECULAR...(LL) W/ALEKS
CHEMISTRY: MOLECULAR...(LL) W/ALEKS
9th Edition
ISBN: 9781265141875
Author: SILBERBERG
Publisher: MCG CUSTOM
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Chapter 23, Problem 23.57P

(a)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Hexaaquachromium (III) sulfate

Concept introduction:

The set of rules for naming a coordination compound is:

  1. 1. When naming a complex ion, the ligands are named before the metal ion.
  2. 2. Write the names of the ligands in the following order: neutral, negative, positive.  If there are multiple ligands of the same charge type, they are named in alphabetical order.
  3. 3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa.  Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc.  Anions end in -ido.  This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).
  4. 4. Neutral ligands are given their usual name, with some exceptions: NH3 becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl;  NO becomes nitrosyl.
  5. 5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available
  6. 6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.
  7. 7. End with “cation” or “anion” as separate words.

(b)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Barium tetrabromoferrate (III)

Concept introduction;

The set of rules for naming a coordination compound is:

  1. 1. When naming a complex ion, the ligands are named before the metal ion.
  2. 2. Write the names of the ligands in the following order: neutral, negative, positive.  If there are multiple ligands of the same charge type, they are named in alphabetical order.
  3. 3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa.  Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc.  Anions end in -ido.  This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).
  4. 4. Neutral ligands are given their usual name, with some exceptions: NH3 becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.
  5. 5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available
  6. 6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.
  7. 7. End with “cation” or “anion” as separate words.

(c)

Interpretation Introduction

Interpretation:

The formulas of the given compound has to be written using its names has to be given.

Bis (ethylene diamine) platinum (II) carbonate

Concept introduction;

The set of rules for naming a coordination compound is:

  1. 1. When naming a complex ion, the ligands are named before the metal ion.
  2. 2. Write the names of the ligands in the following order: neutral, negative, positive.  If there are multiple ligands of the same charge type, they are named in alphabetical order.
  3. 3. Multiple occurring monodentate ligands receive a prefix according to the number of occurrences: di-, tri-, tetra-, penta-, or hexa.  Polydentate ligands (e.g., ethylene diamine, oxalate) receive bis-, tris-, tetrakis-, etc.  Anions end in -ido.  This replaces the final “e” when the anion ends with “-ate” (e.g, sulfate becomes sulfato) and replaces “-ide” (cyanide becomes cyanido).
  4. 4. Neutral ligands are given their usual name, with some exceptions: NH3 becomes ammine; H2O becomes aqua or aquo;CO becomes carbonyl; NO becomes nitrosyl.
  5. 5. Write the name of the central atom/ion. If the complex is an anion, the central atom’s name will end in -ate, and its Latin name will be used if available
  6. 6. If the central atom’s oxidation state needs to be specified (when it is one of several possible, or zero), write it as a Roman numeral (or 0) in parentheses.
  7. 7. End with “cation” or “anion” as separate words.

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Chapter 23 Solutions

CHEMISTRY: MOLECULAR...(LL) W/ALEKS

Ch. 23.4 - Prob. 23.6AFPCh. 23.4 - Prob. 23.6BFPCh. 23.4 - Prob. 23.7AFPCh. 23.4 - Prob. 23.7BFPCh. 23 - Prob. 23.1PCh. 23 - Write the general electron configuration of a...Ch. 23 - Prob. 23.3PCh. 23 - Prob. 23.4PCh. 23 - Prob. 23.5PCh. 23 - Prob. 23.6PCh. 23 - (a) What is the range in electronegativity across...Ch. 23 - (a) Explain the major difference between the...Ch. 23 - (a) What behavior distinguishes paramagnetic and...Ch. 23 - Prob. 23.10PCh. 23 - Using the periodic table to locate each element,...Ch. 23 - Using the periodic table to locate each element,...Ch. 23 - Using the periodic table to locate each element,...Ch. 23 - Prob. 23.14PCh. 23 - Prob. 23.15PCh. 23 - What is the highest oxidation state for (a) Ta;...Ch. 23 - What is the highest oxidation state for (a) Nb;...Ch. 23 - Prob. 23.18PCh. 23 - Prob. 23.19PCh. 23 - Prob. 23.20PCh. 23 - Prob. 23.21PCh. 23 - Prob. 23.22PCh. 23 - Prob. 23.23PCh. 23 - Prob. 23.24PCh. 23 - Prob. 23.25PCh. 23 - Prob. 23.26PCh. 23 - What atomic property of the lanthanides leads to...Ch. 23 - Prob. 23.28PCh. 23 - Prob. 23.29PCh. 23 - Give the electron configuration of (a) La; (b)...Ch. 23 - Prob. 23.31PCh. 23 - Only a few lanthanides show an oxidation state...Ch. 23 - Prob. 23.33PCh. 23 - Prob. 23.34PCh. 23 - Describe the makeup of a complex ion, including...Ch. 23 - Prob. 23.36PCh. 23 - Prob. 23.37PCh. 23 - Prob. 23.38PCh. 23 - Prob. 23.39PCh. 23 - Prob. 23.40PCh. 23 - Prob. 23.41PCh. 23 - Prob. 23.42PCh. 23 - Prob. 23.43PCh. 23 - Prob. 23.44PCh. 23 - Prob. 23.45PCh. 23 - Prob. 23.46PCh. 23 - What are the charge and coordination number of the...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - Prob. 23.49PCh. 23 - Give systematic names for the following...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - Prob. 23.53PCh. 23 - Prob. 23.54PCh. 23 - Prob. 23.55PCh. 23 - Prob. 23.56PCh. 23 - Prob. 23.57PCh. 23 - Prob. 23.58PCh. 23 - Prob. 23.59PCh. 23 - Prob. 23.60PCh. 23 - Prob. 23.61PCh. 23 - Prob. 23.62PCh. 23 - For any of the following that can exist as...Ch. 23 - Prob. 23.64PCh. 23 - Prob. 23.65PCh. 23 - Prob. 23.66PCh. 23 - Chromium(III), like cobalt(III), has a...Ch. 23 - When MCl4(NH3)2 is dissolved in water and treated...Ch. 23 - Prob. 23.69PCh. 23 - What is a coordinate covalent bond? Is such a...Ch. 23 - Prob. 23.71PCh. 23 - Prob. 23.72PCh. 23 - Prob. 23.73PCh. 23 - In terms of the theory of color absorption,...Ch. 23 - Prob. 23.75PCh. 23 - Prob. 23.76PCh. 23 - Prob. 23.77PCh. 23 - How do the relative magnitudes of Epairing and Δ...Ch. 23 - Prob. 23.79PCh. 23 - Give the number of d electrons (n of dn) for the...Ch. 23 - Give the number of d electrons (n of dn) for the...Ch. 23 - Prob. 23.82PCh. 23 - How many d electrons (n of dn) are in the central...Ch. 23 - Prob. 23.84PCh. 23 - Prob. 23.85PCh. 23 - Prob. 23.86PCh. 23 - Prob. 23.87PCh. 23 - Prob. 23.88PCh. 23 - Prob. 23.89PCh. 23 - Prob. 23.90PCh. 23 - Prob. 23.91PCh. 23 - Prob. 23.92PCh. 23 - Prob. 23.93PCh. 23 - Prob. 23.94PCh. 23 - Prob. 23.95PCh. 23 - Prob. 23.96PCh. 23 - Prob. 23.97PCh. 23 - Prob. 23.98PCh. 23 - When neptunium (Np) and plutonium (Pu) were...Ch. 23 - Prob. 23.100PCh. 23 - Prob. 23.101PCh. 23 - For the compound [Co(en)2Cl2]Cl, give: The...Ch. 23 - Prob. 23.103PCh. 23 - Prob. 23.104PCh. 23 - Prob. 23.105PCh. 23 - Prob. 23.106PCh. 23 - Prob. 23.107PCh. 23 - Prob. 23.108PCh. 23 - Prob. 23.109PCh. 23 - Prob. 23.110PCh. 23 - Prob. 23.111PCh. 23 - The actinides Pa, U, and Np form a series of...Ch. 23 - Prob. 23.113PCh. 23 - Prob. 23.114PCh. 23 - Prob. 23.115PCh. 23 - Prob. 23.116PCh. 23 - Prob. 23.117PCh. 23 - Prob. 23.118PCh. 23 - Prob. 23.119PCh. 23 - Prob. 23.120PCh. 23 - Prob. 23.121PCh. 23 - Prob. 23.122P
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