Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 23, Problem 45PP

 (a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  1, Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  2 and Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  3groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound.  First one is the method of giving general name in which name of the alkyl group followed by amine name is given.  Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain.  Other chains are considered as substituents to the main chain.  Position of the substituents should be included in the name.  If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes.  If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups.  If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name.  If the compound contains heavier groups on the same side, it gets (Z)-configuration.  If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature.  If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer.  If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Assign the name for a given compound (a)

Categorize the number of alkyl groups attached to nitrogen atom

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  4, Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  5 and Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  6groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound.  First one is the method of giving general name in which name of the alkyl group followed by amine name is given.  Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain.  Other chains are considered as substituents to the main chain.  Position of the substituents should be included in the name.  If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes.  If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups.  If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name.  If the compound contains heavier groups on the same side, it gets (Z)-configuration.  If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature.  If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer.  If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Assign the name for a given compound (b)

Categorize the number of alkyl groups attached to nitrogen atom

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  7, Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  8 and Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  9groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound.  First one is the method of giving general name in which name of the alkyl group followed by amine name is given.  Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain.  Other chains are considered as substituents to the main chain.  Position of the substituents should be included in the name.  If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes.  If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups.  If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name.  If the compound contains heavier groups on the same side, it gets (Z)-configuration.  If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature.  If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer.  If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Assign the name for a given compound (c)

Categorize the number of alkyl groups attached to nitrogen atom

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  10, Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  11 and Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  12groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound.  First one is the method of giving general name in which name of the alkyl group followed by amine name is given.  Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain.  Other chains are considered as substituents to the main chain.  Position of the substituents should be included in the name.  If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes.  If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups.  If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name.  If the compound contains heavier groups on the same side, it gets (Z)-configuration.  If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature.  If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer.  If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Assign the name for a given compound (d)

Categorize the number of alkyl groups attached to nitrogen atom

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  13, Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  14 and Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  15groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound.  First one is the method of giving general name in which name of the alkyl group followed by amine name is given.  Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain.  Other chains are considered as substituents to the main chain.  Position of the substituents should be included in the name.  If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes.  If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups.  If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name.  If the compound contains heavier groups on the same side, it gets (Z)-configuration.  If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature.  If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer.  If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Assign the name for a given compound (e)

Categorize the number of alkyl groups attached to nitrogen atom

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  16, Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  17 and Organic Chemistry, Binder Ready Version, Chapter 23, Problem 45PP , additional homework tip  18groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound.  First one is the method of giving general name in which name of the alkyl group followed by amine name is given.  Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain.  Other chains are considered as substituents to the main chain.  Position of the substituents should be included in the name.  If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes.  If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups.  If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name.  If the compound contains heavier groups on the same side, it gets (Z)-configuration.  If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature.  If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer.  If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Assign the name for a given compound (f)

Categorize the number of alkyl groups attached to nitrogen atom

Blurred answer

Chapter 23 Solutions

Organic Chemistry, Binder Ready Version

Ch. 23.4 - Prob. 10CCCh. 23.4 - Prob. 11CCCh. 23.5 - Prob. 2LTSCh. 23.5 - Prob. 12PTSCh. 23.5 - Prob. 13PTSCh. 23.6 - Prob. 3LTSCh. 23.6 - Prob. 14PTSCh. 23.6 - Prob. 15ATSCh. 23.6 - Prob. 16ATSCh. 23.6 - Prob. 17ATSCh. 23.7 - Prob. 18PTSCh. 23.7 - Prob. 19PTSCh. 23.7 - Prob. 20PTSCh. 23.7 - Prob. 21ATSCh. 23.8 - Prob. 22CCCh. 23.8 - Prob. 23CCCh. 23.8 - Prob. 24CCCh. 23.9 - Prob. 5LTSCh. 23.9 - Prob. 25PTSCh. 23.9 - Prob. 26ATSCh. 23.9 - Prob. 27ATSCh. 23.9 - Prob. 28ATSCh. 23.10 - Prob. 29CCCh. 23.11 - Prob. 30CCCh. 23.11 - Prob. 6LTSCh. 23.11 - Prob. 31PTSCh. 23.11 - Prob. 32ATSCh. 23.11 - Prob. 33ATSCh. 23.12 - Prob. 34CCCh. 23.12 - Prob. 35CCCh. 23.13 - Prob. 36CCCh. 23.13 - Prob. 37CCCh. 23 - Prob. 38PPCh. 23 - Prob. 39PPCh. 23 - Prob. 40PPCh. 23 - Prob. 41PPCh. 23 - Prob. 42PPCh. 23 - Prob. 43PPCh. 23 - Prob. 44PPCh. 23 - Prob. 45PPCh. 23 - Prob. 46PPCh. 23 - Prob. 47PPCh. 23 - Prob. 48PPCh. 23 - Prob. 49PPCh. 23 - Prob. 50PPCh. 23 - Prob. 51PPCh. 23 - Prob. 52PPCh. 23 - Prob. 53PPCh. 23 - Prob. 54PPCh. 23 - Prob. 55PPCh. 23 - Prob. 56PPCh. 23 - Prob. 57PPCh. 23 - Prob. 58PPCh. 23 - Prob. 59PPCh. 23 - Prob. 60PPCh. 23 - Prob. 61PPCh. 23 - Prob. 62PPCh. 23 - Prob. 63PPCh. 23 - Prob. 64PPCh. 23 - Prob. 65PPCh. 23 - Prob. 66PPCh. 23 - Prob. 67PPCh. 23 - Prob. 68PPCh. 23 - Prob. 69PPCh. 23 - Prob. 70PPCh. 23 - Prob. 71PPCh. 23 - Prob. 72PPCh. 23 - Prob. 73PPCh. 23 - Prob. 74PPCh. 23 - Prob. 75PPCh. 23 - Prob. 76PPCh. 23 - Prob. 77IPCh. 23 - Prob. 78IPCh. 23 - Prob. 79IPCh. 23 - Prob. 80IPCh. 23 - Prob. 81IPCh. 23 - Prob. 82IPCh. 23 - Prob. 83IPCh. 23 - Prob. 84IPCh. 23 - Prob. 85IPCh. 23 - Prob. 86IPCh. 23 - Prob. 87IPCh. 23 - Prob. 88IPCh. 23 - Prob. 89IPCh. 23 - Prob. 90IPCh. 23 - Prob. 91CPCh. 23 - Prob. 92CPCh. 23 - Prob. 93CPCh. 23 - Prob. 94CPCh. 23 - Prob. 95CPCh. 23 - Prob. 96CPCh. 23 - Prob. 97CPCh. 23 - Prob. 98CP
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