Concept explainers
(a)
Interpretation:
The structures of compounds 1,2 and 3 and also the reason behind why A gives only one Simmons–Smith product should be explained.
Concept Introduction:
Grubbs catalyst: This catalyst is used to achieve alkene metathesis. It contain
Reaction of an alkene with Grubbs, the vinyl positions in given alkene is separated from each other and finally fragments are recombined. The reaction is as follows,
Simmons – Smith reaction: It involves reaction of
(b)
Interpretation:
The relationship between 2 and 3 should be identified.
Concept Introduction:
Enantiomers: They are chiral molecules that are mirror images of one another and are non-superimposable. Chiral molecules with one or more stereocenters can be enantiomers.
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