EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780133897340
Author: Petrucci
Publisher: PEARSON CO
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 23, Problem 66E
Interpretation Introduction
Interpretation:
The reason should be explained for the stability of AgF2 and AgO compound and instability of AgCl2, AgBr2, and AgS.
Concept introduction:
Stability of an oxidation state of a transition metal depends on other atoms which it is bonded, whether the compound is in solid or aqueous form, pH of the solution.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Draw the structures and label the type for all the isomers of
each ion.
a. (Cr(CO),(NH,),+
b. (Pd(CO),(H;0)cij+
Why is [Fe(OH2)6]³+ prepared in an acidic solution?
A. It is a Bronsted acid in aqueous solution
B. It is stabilized against reduction in acid
C. It is not soluble in water at pH = 7.0
%3D
O D. All of the choices
The photographs below (a) show what occurs when a solution of iron(III) nitrate istreated with a few drops of aqueous potassium thiocyanate. The nearly colorlessiron(III) ion is converted to a red [Fe(H2O)5SCN)2+ion. (This is a classic test for thepresence of iron(III) ions in solution.)[Fe(H2O)6]3+(aq) + SCN−(aq) ⇄ [Fe(H2O)5SCN]2+(aq) + H2O(ℓ)(a) As more KSCN is added to the solution, the color becomes even more red.Explain this observation.(b) Silver ions form a white precipitate with SCN−ions. What would you observeon adding a few drops of aqueous silver nitrate to a red solution of [Fe(H2O)5 Explain your observations?
Chapter 23 Solutions
EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 23 - By means of orbital diagrams, write electron...Ch. 23 - Arrange the following species according to the...Ch. 23 - Describe how the transition elements compare with...Ch. 23 - With only minor irregularities, the melting points...Ch. 23 - Why do the atomic radii vary so much for two...Ch. 23 - Prob. 6ECh. 23 - Which of me first transition series elements...Ch. 23 - Why is the number of common oxidation states for...Ch. 23 - As a group, the lanthanides are more reactive...Ch. 23 - The maximum difference in standard reduction...
Ch. 23 - Complete and balance the following equations. If...Ch. 23 - By means of e chemical equation, give an example...Ch. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Prob. 16ECh. 23 - Prob. 17ECh. 23 - According to Figure 23-8, G decreases with...Ch. 23 - Prob. 19ECh. 23 - Prob. 20ECh. 23 - Write plausible half-equations to represent each...Ch. 23 - Prob. 22ECh. 23 - Use electrode potential data from this chapter or...Ch. 23 - You are given these three reducing agents: Zn(s);...Ch. 23 - Prob. 25ECh. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Use data from the text to construct a standard...Ch. 23 - When a soluble lead compound is added to a...Ch. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - If CO2(g) under pressure is passed into...Ch. 23 - Use equation (23.19) to determine [Cr2O72] in a...Ch. 23 - If a solution is prepared by dissolving 1.505 g...Ch. 23 - Prob. 35ECh. 23 - Prob. 36ECh. 23 - Prob. 37ECh. 23 - Prob. 38ECh. 23 - Will reaction (23.25) still be spontaneous in the...Ch. 23 - Prob. 40ECh. 23 - Prob. 41ECh. 23 - Prob. 42ECh. 23 - Prob. 43ECh. 23 - Prob. 44ECh. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - At 400C , 2Hg(I)+O2(g)2HgO(s) for the reaction...Ch. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - The text notes that in small quantities, zinc is...Ch. 23 - Prob. 56ECh. 23 - What formulas would you expect for the metal...Ch. 23 - For the straight-line graphs in Figure 23-8...Ch. 23 - Prob. 59ECh. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65ECh. 23 - Prob. 66ECh. 23 - Prob. 67ECh. 23 - Prob. 68ECh. 23 - Prob. 69ECh. 23 - Prob. 70ECh. 23 - Prob. 71ECh. 23 - For a coordination number of four, the radius of...Ch. 23 - Prob. 73ECh. 23 - Prob. 74FPCh. 23 - Several transition metal ions are found in cation...Ch. 23 - Prob. 76SAECh. 23 - Briefly describe each of the following ideas. phe...Ch. 23 - Prob. 78SAECh. 23 - Prob. 79SAECh. 23 - Prob. 80SAECh. 23 - Prob. 81SAECh. 23 - Prob. 82SAECh. 23 - Prob. 83SAECh. 23 - Prob. 84SAECh. 23 - Prob. 85SAECh. 23 - Provide the missing name or formula for the...Ch. 23 - Prob. 87SAECh. 23 - Prob. 88SAECh. 23 - Prob. 89SAECh. 23 - Prob. 90SAE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The transition metals form a class of compounds called metal carbonyls, an example of which is the tetrahedral complex Ni(CO)4. Given the following thermodynamic data (at 298 K): (a) Calculate the equilibrium constant for the formation of Ni(CO)4(g) from nickel metal and CO gas. (b) Is the reaction of Ni(s) and CO(g) product- or reactant-favored at equilibrium? (c) Is the reaction more or less product-favored at higher temperatures? How could this reaction be used in the purification of nickel metal?arrow_forwardThe ferrate ion, FeO42, is such a powerful oxidizing agent that in acidic solution, aqueous ammonia is reduced to elemental nitrogen along with the formation of the iron(III) ion. a. What is the oxidation state of iron in FeO42, and what is the electron configuration of iron in this polyatornic ion? b. lf 25.0 mL of a 0.243 M FeO42 solution is allowed to react with 55.0 mL of 1.45 M aqueous ammonia, what volume of nitrogen gas can form at 25C and 1.50 atm?arrow_forwardIs it more difficult to oxidize Cr or Mo? Explain.arrow_forward
- I need help on this?arrow_forward4. Which of the first transition series elements exhibits the greatest number of different oxidation states in its compounds? Explain.arrow_forwardWhat are the oxidation states of the transition metals inthe following series of compounds? Nb2O5, MoS2, RuCl3,RhO2, PdF2, and Ag2O.arrow_forward
- Explain reaction chemistry of CO with transition metals based on its Molecular orbital diagram?arrow_forwardCo3+ ions can form complex ions with ligands F, NH3, H2O, and CN. Of the complex ions that have the highest crystal field stabilization energy is ....a. [Co(CN)6]3-b. [CoF6]3-c. [Co(H2O)6]3+d. [Co(NH3)6]3+ Ti3+ ions can form complex ions with H2O, NH3, CN, and F ligands. Of these complex ions, the largest value of 10Dq is in the ….a. [Ti(NH3)6]3+b. [Ti(H2O)6]3+c. [Ti(CN)6]3-d. [TiF6]3- Complex compound [Ru(NH3)5(NO2)]Cl will produce … ions in water..a. 3b. 6c. 7d. 2arrow_forward[Fe(H2O)6]3+ (aq) + SCN1- ↔ Fe(H2O)5SCN]2+(aq) + heat yellow red For the above reaction, describe using Le Chatelier’s Principle what changes (color changes and shifts) would occur when each stress is applied to this equilibrium. Explain your answers. a) Add KSCN(aq) b) Decrease temperature c) Add AgNO3, which causes AgSCN to precipitate out.arrow_forward
- The addition of S2- ion to Fe(OH)2(s) results in the formation of FeS(s). Explain why the addition of S2- ion to Cr(OH)3(s) does not result in the formation of Cr2S3(s).arrow_forward21. Name the following compounds. a. Ni(CO), b. Naz[Co(H;O)2(OH),] c. [Ag(NH3)2]Br d. [Co(NH,),CI]SO, g. [Ni(NH3).(H2O)2](NO3)2arrow_forwardThe equilibrium-constant expression for the reaction Ti (s) + 2CI 2 (g) TICI 4 (1) is given by O [Ti (s)] [Cl2 (g)F [TIC14(1}] [TIC14 (1)] [Ti (s)] [Cl2( g))? [TIC14 (1)] [Ti (s)] [Cl2 (g)] O [TIC14 (1)] [Cl2 (g))? O [Cl2 (g)]2arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningLiving By Chemistry: First Edition TextbookChemistryISBN:9781559539418Author:Angelica StacyPublisher:MAC HIGHER
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Living By Chemistry: First Edition Textbook
Chemistry
ISBN:9781559539418
Author:Angelica Stacy
Publisher:MAC HIGHER
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning