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Organic Chemistry

8th Edition
William H. Brown + 3 others
Publisher: Cengage Learning
ISBN: 9781305580350

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BuyFindarrow_forward

Organic Chemistry

8th Edition
William H. Brown + 3 others
Publisher: Cengage Learning
ISBN: 9781305580350
Chapter 25, Problem 25.34P
Textbook Problem
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Draw structural formulas for the products formed by hydrolysis at pH 7.4 (the pH of blood plasma) of all ester, thioester, amide, anhydride, and glycoside groups in acetyl coenzyme A. Name as many of the products as you can.

Chapter 25, Problem 25.34P, Draw structural formulas for the products formed by hydrolysis at pH 7.4 (the pH of blood plasma) of

Interpretation Introduction

Interpretation:

The structural formula for the product formed by the hydrolysis at pH 7.4 of all ester, thioester, amide, anhydride and glycosidic groups in acetyl coenzyme A has to be drawn.

Concept Introduction:

The acetyl coenzyme A contains ester, thioester, amide, anhydride and glycosidic groups.  They all are linked together to form the acetyl coenzyme A molecule.  The groups in the acetyl coenzyme A molecule are

Organic Chemistry, Chapter 25, Problem 25.34P

Explanation of Solution

On hydrolysis, the acetyl coenzyme A is cleaved into smaller molecules of amide, ester, anhydride, and glycosidic groups.  The products formed by hydrolysis are acetic acid, 3-aminopropanoic acid, 2-amino ethane thiol, 2,4-dihydroxy-3,3-dimethyl butanoic acid, β-D-ribofuranose, adenine and phosphate molecules...

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Chapter 25 Solutions

Organic Chemistry
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Ch. 25.4 - Draw a chair conformation for the form of a...Ch. 25 - Explain the meaning of the designations D and L...Ch. 25 - How many chiral centers are present in D-glucose?...Ch. 25 - Which carbon of an aldopentose determines whether...Ch. 25 - How many aldooctoses are possible? How many...Ch. 25 - Which compounds are D-monosaccharides? Which are...Ch. 25 - Write Fischer projections for L-ribose and...Ch. 25 - What is the meaning of the prefix deoxy- as it is...Ch. 25 - Give L-fucose (Chemical Connections: A, B, AB, and...Ch. 25 - 2,6-Dideoxy-D-altrose, known alternatively as...Ch. 25 - Define the term anomeric carbon. In glucose, which...Ch. 25 - Define the terms (a) pyranose and (b) furanose.Ch. 25 - What is the anomeric carbon in a 2-ketohexose?Ch. 25 - Are -D-glucose and -D-glucose enantiomers?...Ch. 25 - Convert each Haworth projection to an open-chain...Ch. 25 - Convert each chair conformation to an open-chain...Ch. 25 - Explain the phenomenon of mutarotation with...Ch. 25 - The specific rotation of -D-glucose is +112.2. (a)...Ch. 25 - Draw Fischer projections for the product(s) formed...Ch. 25 - Repeat Problem 25.24 using D-ribose. 25.24 Draw...Ch. 25 - An important technique for establishing relative...Ch. 25 - There are four D-aldopentoses (Table 25.1). If...Ch. 25 - Name the two alditols formed by NaBH4 reduction of...Ch. 25 - One pathway for the metabolism of D-glucose...Ch. 25 - What is the difference in meaning between the...Ch. 25 - Treatment of methyl -D-glucopyranoside with...Ch. 25 - Vanillin (4-hydroxy-3-methoxybenzaldehyde), the...Ch. 25 - Hot water extracts of ground willow and poplar...Ch. 25 - Draw structural formulas for the products formed...Ch. 25 - In making candy or sugar syrups, sucrose is boiled...Ch. 25 - Trehalose is found in young mushrooms and is the...Ch. 25 - The trisaccharide raffinose occurs principally in...Ch. 25 - Amygdalin is a toxic component in the pits of...Ch. 25 - Following is a structural formula for stachyose, a...Ch. 25 - What is the difference in structure between oligo-...Ch. 25 - Why is cellulose insoluble in water?Ch. 25 - Consider N-acetyl-D-glucosamine (Section 25.1D)....Ch. 25 - Propose structural formulas for the following...Ch. 25 - Digitalis is a preparation made from the dried...Ch. 25 - Following is the structural formula of ganglioside...Ch. 25 - Hyaluronic acid acts as a lubricant in the...Ch. 25 - The anticlotting property of heparin is partly the...Ch. 25 - Keratin sulfate is an important component of the...Ch. 25 - Following is a chair conformation for the...Ch. 25 - Following is a structural formula for the...

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