Concept explainers
(a)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 1
Explanation of Solution
The name of the given molecule suggests that a nitrogen atom is bonded to cyclopentane and isobutyl group. Cyclopentane consists of five carbon atoms. Therefore, the structure of the given compound is,
Figure 1
The structure that corresponds to the given name is shown in Figure 1.
(b)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 2
Explanation of Solution
The name of the given compound is tri-tert-butylamine. Prefix ‘tri’ shows that a nitrogen atom is bonded to three tert-butyl groups. Therefore, the structure of the given compound is,
Figure 2
The structure that corresponds to the given name is shown in Figure 2.
(c)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 3
Explanation of Solution
The name of the given compound is N, N-diisopropylaniline. Prefix ‘di’ shows that a nitrogen atom is bonded to two isopropyl groups and it is bonded to six membered
Figure 3
The structure that corresponds to the given name is shown in Figure 3.
(d)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 4
Explanation of Solution
The name of the given compound is N-methylpyrrole. Pyrrole is the parent chain of the given compound. It is an aromatic five membered ring which contains nitrogen atom and two double bonds. The nitrogen atom is bonded to methyl group. Therefore, the structure of the given compound is,
Figure 4
The structure that corresponds to the given name is shown in Figure 4.
(e)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 5
Explanation of Solution
The name of the given compound is N-methylcyclopentanamine. The name suggests that nitrogen atom is bonded to cyclopentane and methyl group. Therefore, the structure of the given compound is,
Figure 5
The structure that corresponds to the given name is shown in Figure 5.
(f)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 6
Explanation of Solution
The name of the given compound is
Figure 6
The structure that corresponds to the given name is shown in Figure 6.
(g)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 7
Explanation of Solution
The name of the given compound is
Figure 7
The structure that corresponds to the given name is shown in Figure 7.
(h)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 8
Explanation of Solution
The name of the given compound is (S)-heptan-
Figure 8
The structure that corresponds to the given name is shown in Figure 8.
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Chapter 25 Solutions
ORGANIC CHEM CONNECT ACCESS CARD
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning