CAREY: ORGANIC CHEMISTRY
10th Edition
ISBN: 9781260364002
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 25.2, Problem 1P
What fatty acids are produced on hydrolysis of
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How would you expect the melting point of eicosapentaenoic acid[CH3CH2(CH=CHCH2)5(CH2)2COOH] to compare with the melting points of the fatty acids listed in attached file
Each molecule of fatty acid ester provides how many equivalents of carboxylate acid salts?
How would you expect the melting point of eicosapentaenoic acid [CH3CH2(CH = CHCH2)5(CH2)2COOH] to compare with the melting points of the fatty acids listed in Table 31.2?
Table 31.2: The Most Common Fatty Acids in Triacylglycerols
Chapter 25 Solutions
CAREY: ORGANIC CHEMISTRY
Ch. 25.2 - What fatty acids are produced on hydrolysis of...Ch. 25.3 - Give the structure of the keto acyl-ACP formed...Ch. 25.4 - Prob. 3PCh. 25.4 - Prob. 4PCh. 25.5 - Prob. 5PCh. 25.6 - Write the structural formula and give the IUPAC...Ch. 25.6 - Prob. 7PCh. 25.7 - Locate the isoprene units in each of the...Ch. 25.7 - Prob. 9PCh. 25.9 - Prob. 10P
Ch. 25.9 - Prob. 11PCh. 25.10 - Prob. 12PCh. 25.11 - Prob. 13PCh. 25.11 - Prob. 14PCh. 25.12 - Prob. 15PCh. 25.16 - Prob. 16PCh. 25 - Prob. 17PCh. 25 - Prob. 18PCh. 25 - Prob. 19PCh. 25 - Pyrethrins are a group of naturally occurring...Ch. 25 - Prob. 21PCh. 25 - Prob. 22PCh. 25 - Prob. 23PCh. 25 - Prob. 24PCh. 25 - Prob. 25PCh. 25 - Prob. 26PCh. 25 - Prob. 27PCh. 25 - Prob. 28PCh. 25 - A synthesis of triacylglycerols has been described...Ch. 25 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - Prob. 32PCh. 25 - Prob. 33DSPCh. 25 - Prob. 34DSPCh. 25 - Prob. 35DSPCh. 25 - Prob. 36DSPCh. 25 - Prob. 37DSPCh. 25 - Prob. 38DSP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A simple triacylglycerol is one that: a) Upon hydrolysis produces glycerol and three different fatty acids. b) Upon hydrolysis produces glycerol and at least two different fatty acids. c) Upon saponification gives glycerol and three fatty acid salts. d) Upon saponification gives three esters. e) Upon hydrolysis produces glycerol and three mol of a fatty acid.arrow_forwardWhat is the structure of an optically inactive triacylglycerol that yields two moles of oleic acid and one mole of palmitic acid when hydrolyzed in aqueous acid?arrow_forwardLinoleic acid is shown below. What makes this fatty acid particularly susceptible to autoxidation? 1. The red CH bond has a low bond dissociation energy because it is doubly allylic. 2. The red CH bond has a high bond dissociation energy because it is doubly allylic. 3. The red CH bond is the most accessible to reaction with O2 because it is the least sterically crowded CH bond. 4. Both 2 and 3.arrow_forward
- In step 7 of fatty-acid biosynthesis (Figure 29-5), dehydration of a -hydroxy thioester occurs to give trans-crotonyl ACP. Is the dehydration a syn elimination or an anti elimination?arrow_forwardDraw structures of glyceryl tripalmitate and glyceryl trioleate. Which would you expect to have a higher melting point?arrow_forwardDraw the products formed when triacylglycerol A is treated with each reagent. Rank compounds A, B, and C in order of increasing melting point.a. H2O, H+b. H2 (excess), Pd-C → Bc. H2(1 equiv), Pd-C → Carrow_forward
- Show how you would convert oleic acid to the following fatty acid derivatives.(a) octadecan-1-ol (b) stearic acid (c) octadecyl stearate(d) nonanal (e) nonanedioic acid (f) 2,9,10-tribromostearic acidarrow_forwardShow how you would convert oleic acid to the following fatty acid derivatives.(a) octadecan-1-olarrow_forward1. Some marine plankton contain triacylglycerols formed from the polyunsaturated fatty acid (PUFA) such as: CH3CH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2COOH a) Draw the skeletal structure of the given PUFA showing the preffered stereogenic arrangement for a naturally-occuring lipid at each double bond. b) Write the systematic name of the fatty acid. c) What type of omega-n acid is this fatty acid? d) Would you expect this fatty acid to be a soild or liquid at room temperature?arrow_forward
- What is the composition of the soap prepared by hydrolysis of the attachedtriacylglycerol?arrow_forwardCopy the reaction scheme and draw the structural formulae of the two triglycerides (1) and (2) that could produce the triglyceride product 4. Indicate which two fatty acids have swapped between the starting triglycerides by labelling them as a and b in the starting materials and product. What other reagent (3) is needed to carry out the inter-esterification reaction above?arrow_forwardHow HCl converts the hemiacetal to an acetal called a glycoside ?arrow_forward
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