Organic Chemistry, Third Edition Binder Ready Version
Organic Chemistry, Third Edition Binder Ready Version
3rd Edition
ISBN: 9781119110453
Author: Klein
Publisher: WILEY
Question
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Chapter 25.3, Problem 13CC

(a)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  1

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  3

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  5

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

The amino acid formed when carboxylic acid is treated with bromine and phosphorous tribromide, followed by water and the resulting α -haloacid treated with excess ammonia need to be drawn for the given set of carboxylic acid.

Concept introduction:

α -bromination of carboxylic acid in presence of bromine and a catalytic amount of phosphorous tribromide to form α -bromocarboxylic acid is known as Hell-Volhard-Zelinsky reaction.  The formed α -bromocarboxylic acid when treated with ammonia gives α -aminocarboxylic acid as the product.

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  7

To identify: the amino acid formed when the given carboxylic acid is treated with bromine, phosphorous tribromide and followed by excess ammonia,

Organic Chemistry, Third Edition Binder Ready Version, Chapter 25.3, Problem 13CC , additional homework tip  8

Blurred answer

Chapter 25 Solutions

Organic Chemistry, Third Edition Binder Ready Version

Ch. 25.2 - Prob. 10CCCh. 25.3 - Prob. 11CCCh. 25.3 - Prob. 12CCCh. 25.3 - Prob. 13CCCh. 25.3 - Prob. 2LTSCh. 25.3 - Prob. 14PTSCh. 25.3 - Prob. 15ATSCh. 25.3 - Prob. 16ATSCh. 25.3 - Prob. 17CCCh. 25.3 - Prob. 18CCCh. 25.3 - Prob. 19CCCh. 25.3 - Prob. 20CCCh. 25.4 - Prob. 3LTSCh. 25.4 - Prob. 21PTSCh. 25.4 - Prob. 22ATSCh. 25.4 - Prob. 23ATSCh. 25.4 - Prob. 24ATSCh. 25.4 - Prob. 25CCCh. 25.4 - Prob. 26CCCh. 25.4 - Prob. 27CCCh. 25.4 - Prob. 28CCCh. 25.4 - Prob. 29CCCh. 25.5 - Prob. 30CCCh. 25.5 - Prob. 4LTSCh. 25.5 - Prob. 31PTSCh. 25.5 - Prob. 32ATSCh. 25.5 - Prob. 33ATSCh. 25.6 - Prob. 5LTSCh. 25.6 - Prob. 34PTSCh. 25.6 - Prob. 35ATSCh. 25.6 - Prob. 36ATSCh. 25.6 - Prob. 6LTSCh. 25.6 - Prob. 37PTSCh. 25.6 - Prob. 38ATSCh. 25.7 - Prob. 39CCCh. 25 - Prob. 40PPCh. 25 - Prob. 41PPCh. 25 - Prob. 42PPCh. 25 - Prob. 43PPCh. 25 - Prob. 44PPCh. 25 - Prob. 45PPCh. 25 - Prob. 46PPCh. 25 - Prob. 47PPCh. 25 - Prob. 48PPCh. 25 - Prob. 49PPCh. 25 - Prob. 50PPCh. 25 - Prob. 51PPCh. 25 - Prob. 52PPCh. 25 - Prob. 53PPCh. 25 - Prob. 54PPCh. 25 - Prob. 55PPCh. 25 - Prob. 56PPCh. 25 - Prob. 57PPCh. 25 - Prob. 58PPCh. 25 - Prob. 59PPCh. 25 - Prob. 60PPCh. 25 - Prob. 61PPCh. 25 - Prob. 62PPCh. 25 - Prob. 63PPCh. 25 - Prob. 64PPCh. 25 - Prob. 65PPCh. 25 - Prob. 66PPCh. 25 - Prob. 67PPCh. 25 - Prob. 68PPCh. 25 - Prob. 69PPCh. 25 - Prob. 70PPCh. 25 - Prob. 71PPCh. 25 - Prob. 72PPCh. 25 - Prob. 73PPCh. 25 - Prob. 74PPCh. 25 - Prob. 75PPCh. 25 - Prob. 76PPCh. 25 - Prob. 77PPCh. 25 - Prob. 78PPCh. 25 - Prob. 79PPCh. 25 - Prob. 80PPCh. 25 - Prob. 81PPCh. 25 - Prob. 82PPCh. 25 - Prob. 83PPCh. 25 - Prob. 84IPCh. 25 - Prob. 85IPCh. 25 - Prob. 86IPCh. 25 - Prob. 87IPCh. 25 - Prob. 88IPCh. 25 - Prob. 89IPCh. 25 - Prob. 90CPCh. 25 - We saw in Section 25.6 that DCC can be used to...Ch. 25 - Prob. 92CP
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