BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
8th Edition
ISBN: 9781337687539
Author: Brown/Iverson/Anslyn/ Foote
Publisher: CENGAGE C
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Question
Chapter 25.3, Problem 25.4P
Interpretation Introduction
Interpretation:
To methyl α-D-mannopyranoside (methyl α-D-mannoside), Haworth projection and chair conformations has to be given and the anomeric carbon and the glycosidic bond has to be labelled.
Concept Introduction:
The
The bond formed between the anomeric carbon and the alcohol molecule is said to be glycosidic bond.
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Students have asked these similar questions
Draw the structure of:
a polysaccharide formed by joining D-mannose units in 1→4-β- glycosidic linkages;
Draw a chair conformation for the b-anomer of a disaccharide in which two units of d-glucopyranose are joined by an a-1,6-glycosidic bond.
1. Draw Haworth projections of B-D-arabinofuranose and a-L-mannopyranose.
2. Consider the structure of the disaccharide drawn at right:
НО
`CH2
В
ОН
(a) Give the names and D/L designation for the two
monosaccharides linked together.
H,C-O
OHO
„OH OH
А:
НО
НО
A
В:
ОН
(b) In the structure, circle the anomeric carbon of each saccharide.
(c) Is each saccharide present in its a or ß anomer? Specify both A and B
(d) Would this disaccharide undergo mutarotation? Why or why not?
(e) Would this disaccharide react with Tollens and/or Benedicts reagent? Why or why
not?
(f) There are two reasons this is very unlikely to be a naturally occurring disaccharide.
What about its structure suggests this is true? Give both reasons.
Chapter 25 Solutions
BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
Ch. 25.1 - Prob. 25.1PCh. 25.2 - Prob. 25.2PCh. 25.2 - Prob. 25.3PCh. 25.3 - Prob. 25.4PCh. 25.3 - Prob. 25.5PCh. 25.3 - Prob. AQCh. 25.3 - Prob. BQCh. 25.3 - Prob. CQCh. 25.3 - Prob. DQCh. 25.3 - How many stereoisomers would result from the...
Ch. 25.4 - Prob. 25.6PCh. 25 - Prob. 25.7PCh. 25 - Prob. 25.8PCh. 25 - Prob. 25.9PCh. 25 - Prob. 25.10PCh. 25 - Prob. 25.11PCh. 25 - Prob. 25.12PCh. 25 - Prob. 25.13PCh. 25 - Prob. 25.14PCh. 25 - Prob. 25.15PCh. 25 - Prob. 25.16PCh. 25 - Prob. 25.17PCh. 25 - Prob. 25.18PCh. 25 - Prob. 25.19PCh. 25 - Prob. 25.20PCh. 25 - Prob. 25.21PCh. 25 - Prob. 25.22PCh. 25 - Prob. 25.23PCh. 25 - Prob. 25.24PCh. 25 - Prob. 25.25PCh. 25 - Prob. 25.26PCh. 25 - Prob. 25.27PCh. 25 - Prob. 25.28PCh. 25 - Prob. 25.29PCh. 25 - Prob. 25.30PCh. 25 - Prob. 25.31PCh. 25 - Prob. 25.32PCh. 25 - Prob. 25.33PCh. 25 - Prob. 25.34PCh. 25 - In making candy or sugar syrups, sucrose is boiled...Ch. 25 - Prob. 25.36PCh. 25 - Prob. 25.37PCh. 25 - Prob. 25.38PCh. 25 - Prob. 25.39PCh. 25 - Prob. 25.40PCh. 25 - Prob. 25.41PCh. 25 - Prob. 25.42PCh. 25 - Prob. 25.43PCh. 25 - Digitalis is a preparation made from the dried...Ch. 25 - Prob. 25.45PCh. 25 - Prob. 25.46PCh. 25 - Prob. 25.47PCh. 25 - Prob. 25.48PCh. 25 - Prob. 25.49PCh. 25 - Prob. 25.50P
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw the structures (using chair conformations of pyranoses) of the following disaccharides. a-d-fructofuranosyl-b-d-mannopyranoside(arrow_forwardConsider the following Haworth structure of a disaccharide and identify the type of glycosidic bond in it. a-1,6-glycosidic bond a-1,4-glycosidic bond a,ß-1,2-glycosidic bond O B-1,4-glycosidic bond H HO HOCH2 H CH₂OH H OH H H OH H OH OH H H CH₂OHarrow_forwardCellobiose, a disaccharide obtained by the hydrolysis of cellulose, is composed of two glucose units joined together in a 1→4-β-glycoside bond. What is the structure of cellobiose?arrow_forward
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