Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Organic Chemistry
Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Organic Chemistry
9th Edition
ISBN: 9780134161600
Author: Wade
Publisher: PEARSON
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Chapter 26, Problem 26.33SP
Interpretation Introduction

Interpretation: The general structure of phenol formaldehyde resin and mechanism of its formation under acidic conditions is to be shown.

Concept Introduction: Phenol reacts with formaldehyde in the presence of the catalyst to form phenol formaldehyde resin called Bakelite. This polymerization reaction proceeds through the formation of carbocation of formaldehyde.

To determine: The structure of Bakelite and mechanism of its formation under acidic conditions.

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2) One of the most common consumer plastics is PET (polyethylene terephthalate), which is used extensively in containers for food and beverage products. Coca-Cola has recently come up with a biobased source of ethylene glycol for synthesizing this polymer, however, the terephthalic acid is still derived from petroleum sources. A sustainable source of terephthalic acid is therefore highly desired. One candidate is 2,5-furandioic acid. Draw the repeat unit for the resulting sustainable polyester derived from 2,5furandioic acid and ethylene glycol.
11c. Nylon 6 and poly(ε-caprolactone) have similar polymer backbone structure with one carbonyl, 5 methylene and a heteroatom, nitrogen or oxygen, respectively. Each is able to undergo crystallization. However, their thermal transition temperature differs significantly. The glass transition temperature (Tg) for Nylon 6 is 52 °C, whereas the Tg for poly(εcaprolactone) is 112 degree lower than Nylon 6 at – 60 °C. Similarly, the melting temperature (Tm) for Nylon 6 is 223 °C, whereas the Tm for poly(εcaprolactone) is 60 °C. Briefly explain the significant differences in the thermal properties of these two polymers.
Chemicals for which the commercially important plastic resins are derived are themselves derived from natural products that are quite plentiful;These raw materials include coal,  water lime stone, sulfur, salt and petroleum.  True or false.
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