EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
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Chapter 26.2C, Problem 26.9P

Chain branching is not as common with anionic polymerization as it is with free-radical polymerization and cationic polymerization.

  1. a. Propose a mechanism for chain branching in the polymerization of acrylonitrile.
  2. b. Compare the relative stabilities of the intermediates in this mechanism with those you drew for chain branching in the cationic polymerization of styrene (Problem26-6). Explain why chain branching is less common in this anionic polymerization.
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