ORGANIC CHEMISTRY BOOK& SG/SM
ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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Chapter 26.6, Problem 12P
Interpretation Introduction

(a)

Interpretation: The α anomer of given aldohexose by the use of Haworth projection is to be drawn.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as β anomer, otherwise α anomer.

Interpretation Introduction

(b)

Interpretation: The α anomer of given aldohexose by the use of Haworth projection is to be drawn.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as β anomer, otherwise α anomer.

Interpretation Introduction

(c)

Interpretation: The β anomer of given aldohexose by the use of Haworth projection is to be drawn.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as β anomer, otherwise α anomer.

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Answer the following questions about monosaccharide A.a. Draw the α anomer of A in a Haworth projection.b. Draw the β anomer of A in a three-dimensional representation using a chair conformation.c. What two aldoses yield A in a Wohl degradation?d. What product is formed when A undergoes a Wohl degradation?e. What product is formed when A reacts with Ag2O in NH4OH?
D-Arabinose can exist in both pyranose and furanose forms. a. Draw the α and β anomers of D-arabinofuranose. b. Draw the α and β anomers of D-arabinopyranose.
a. How many stereogenic centers are present in α-D-galactose? b. Label the hemiacetal carbon in α-D-galactose. c. Draw the structure of β-D-galactose. d. Draw the structure of the polyhydroxy aldehyde that cyclizes to α- and β-D-galactose.

Chapter 26 Solutions

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