ORGANIC CHEMISTRY W/ALEKS
ORGANIC CHEMISTRY W/ALEKS
6th Edition
ISBN: 9781264905430
Author: SMITH
Publisher: MCG CUSTOM
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Chapter 26.6, Problem 12P
Interpretation Introduction

(a)

Interpretation: The α anomer of given aldohexose by the use of Haworth projection is to be drawn.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as β anomer, otherwise α anomer.

Interpretation Introduction

(b)

Interpretation: The α anomer of given aldohexose by the use of Haworth projection is to be drawn.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as β anomer, otherwise α anomer.

Interpretation Introduction

(c)

Interpretation: The β anomer of given aldohexose by the use of Haworth projection is to be drawn.

Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as β anomer, otherwise α anomer.

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a. How many stereogenic centers are present in α-D-galactose? b. Label the hemiacetal carbon in α-D-galactose. c. Draw the structure of β-D-galactose. d. Draw the structure of the polyhydroxy aldehyde that cyclizes to α- and β-D-galactose.
D-Arabinose can exist in both pyranose and furanose forms. a. Draw the α and β anomers of D-arabinofuranose. b. Draw the α and β anomers of D-arabinopyranose.
Draw Haworth projection formulas for the a-anomer of monosaccharides with each of the following Fischer projection formulas. a. CHO HOH H- HO- H -ОН -Η OH CH₂OH b. CHO H -OH H -ОН HO H CH₂OH

Chapter 26 Solutions

ORGANIC CHEMISTRY W/ALEKS

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