ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Question
Chapter 27, Problem 25P
Interpretation Introduction
Interpretation:
A reasonable mechanism for the given reaction is to be suggested.
Concept Introduction:
Nitric acid reacts with primary
This diazonium ion contains a good leaving group,
Reaction of this diazonium ion with a good nucleophile will result in a substitution reaction.
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Draw the structures of the following nucleotides.(a) guanosine triphosphate (GTP)(b) deoxycytidine monophosphate (dCMP)(c) cyclic guanosine monophosphate (cGMP)
26.18 Nebularine is a toxic nucleoside isolated from a species of mushroom. Its systematic
name is 9-B-D-ribofuranosylpurine. Write a structural formula for nebularine.
There is a hexapeptide, and its primary structure is written down according to the following
experimental results, and the analysis process is briefly written down:
(1) DNP-Ala was obtained by DNFB reaction; (2) DNP-Ile was obtained by reaction with DNFB
after hydrazine hydrolysis; (3) Two tripeptides were obtained by reaction with cyanogen bromide,
then DNP-Leu and DNP-Ala were obtained by reaction with DNFB; (4) Fragments containing 1, 2
and 3 amino acids were obtained by trypsin hydrolysis, and the Sakakuchi reaction of the last two
fragments was positive.
Chapter 27 Solutions
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
Ch. 27.1 - Problem 27.1 Write a structural formula for the...Ch. 27.1 - Prob. 2PCh. 27.1 - Prob. 3PCh. 27.2 - Prob. 4PCh. 27.3 - Prob. 5PCh. 27.3 - Prob. 6PCh. 27.5 - Prob. 7PCh. 27.5 - Prob. 8PCh. 27.5 - Prob. 9PCh. 27.6 - Prob. 10P
Ch. 27.7 - Prob. 11PCh. 27.9 - Prob. 12PCh. 27.12 - 27.13 Modify Figure 27.12 so that it corresponds...Ch. 27.13 - Prob. 14PCh. 27 - Prob. 15PCh. 27 - Prob. 16PCh. 27 - Prob. 17PCh. 27 - Nebularine is a toxic nucleoside isolated from a...Ch. 27 - Prob. 19PCh. 27 - The 5-nucleotide of inosine, inosinic acid...Ch. 27 - Prob. 21PCh. 27 - (a) The two most acidic hydrogens of uracil have...Ch. 27 - The phosphorylation of -D-glucopyranose by ATP...Ch. 27 - When 6-chloropurine is heated with aqueous sodium...Ch. 27 - Prob. 25PCh. 27 - Prob. 26PCh. 27 - Prob. 27PCh. 27 - Prob. 28PCh. 27 - Oligonucleotide Synthesis In Section 27.6 we noted...Ch. 27 - Oligonucleotide Synthesis In Section 27.6 we noted...Ch. 27 - Oligonucleotide Synthesis In Section 27.6 we noted...Ch. 27 - Oligonucleotide Synthesis In Section 27.6 we noted...Ch. 27 - Oligonucleotide Synthesis In Section 27.6 we noted...Ch. 27 - Oligonucleotide Synthesis In Section 27.6 we noted...
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