Pearson eText Organic Chemistry -- Instant Access (Pearson+)
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
8th Edition
ISBN: 9780135213711
Author: Paula Bruice
Publisher: PEARSON+
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Chapter 27, Problem 33P
Interpretation Introduction

Interpretation:

The products formed in the two flasks should be explained after the given experiment.

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What is the fraction of monomers (p) that have been used in a stepwise polymerisation reaction if the reaction solution started with a monomer concentration of 1.58 mol L-1 and now has a concentration of 0.231 mol L-1?
In a free - radical polymerization of styrene in solution at 600C, carbon tetrabromide was used as a chain transfer agent. The initial concentrations of styrene and CBr4 were 1 mol/L and 0.01 mol/L, respectively. In 1 h, these concentrations dropped to 0.85 mol/L and 0.007 mol/L, respectively. What is the chain transfer constant CS for styrene/CBr4? (Neglect chain transfer to monomer, initiator, and solvent.)
Macromolecules can also be formed from cyclic monomers such as cyclic hydrocarbons, ethers, esters, amides, siloxanes, and sulfur (eight-membered ring). Thus, ring-opening polymerization is of particular interest, since macromolecules of almost any chemical structure can be prepared. Choose two of the above type polymers to explain the mechanism and chemical reaction of polymerization process.

Chapter 27 Solutions

Pearson eText Organic Chemistry -- Instant Access (Pearson+)

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