Concept explainers
(a)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and
Answer to Problem 28.50P
The product formed by the treatment of
Explanation of Solution
The conversion of hydroxyl groups of
Figure 1
The product formed by the treatment of
(b)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The two anomers are formed by the treatment of monosaccharides with methanol in the presence of hydrochloric acid. One product with methoxy group on the equatorial position and other product with methoxy group on the axial position. The corresponding chemical reaction is shown below.
Figure 2
The products formed by the treatment of
(c)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The conversion of hydroxyl groups of product
Figure 3
The product formed by the treatment of
(d)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The first step is the conversion of hydroxyl groups of gulose into the ether groups in the presence of
Figure 4
The products formed by the treatment of
(e)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide.
Answer to Problem 28.50P
The product formed by the treatment of
Explanation of Solution
In the presence of acetic anhydride and pyridine, the conversion of alcoholic groups in
Figure 5
The products formed by the treatment of
(f)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide.
Answer to Problem 28.50P
The product formed by the treatment of
Explanation of Solution
In the presence of
Figure 7
The products formed by the treatment of
(g)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars. The hydroxyl groups of monosaccharides are converted into the ether groups in presence of base and alkyl halide.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The first step is the conversion of hydroxyl groups of gulose into the ether groups in presence of base and methyl iodide as shown in Figure 2.
The product
Figure 8
The products formed by the treatment of
(h)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars The hydroxyl groups of monosaccharides are converted into the ester groups in presence of base and acetic anhydride or acetyl chloride.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The conversion of alcoholic groups of product
Figure 9
The products formed by the treatment of
(i)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars The hydroxyl groups of monosaccharides are converted into the ester groups in presence of base and acetic anhydride or acetyl chloride.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The conversion of the product
Figure 10
The products formed by the treatment of
(j)
Interpretation: The product formed by the treatment of
Concept introduction: Monosaccharides are the small units of simple sugars The hydroxyl groups of monosaccharides are converted into the ester groups in presence of base and acetic anhydride or acetyl chloride.
Answer to Problem 28.50P
The products formed by the treatment of
Explanation of Solution
The conversion of the product
Figure 11
The products formed by the treatment of
Want to see more full solutions like this?
Chapter 28 Solutions
Organic Chemistry - With Access (Custom)
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
- World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning