The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted. Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C 1 - C 2 bond.

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Answer 1

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Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

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Treatment with sodium borohydride converts aldose A to an optically inactive alditol. Wohl degradation of A forms B, whose alditol is optically inactive. Wohl degradation of B forms d-glyceraldehyde. Identify A and B.

Which D-aldopentose is oxidized to an optically active aldaric acid and undergoes the Wohl degradation to yield a D-aldotetrose that is oxidized to an optically active aldaric acid?

An oligosaccharide isolated from an organism is found tocontain two glucose residues and one galactose residue.Exhaustive methylation followed by hydrolysis producedtwo glucoses with methoxy groups at positions 2, 3,and 6 and galactose with methoxy groups at positions2, 3, 4, and 6. What is the structure of the originaloligosaccharide?

Answer 2

Question

Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

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Answer 3

Question

Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

Expert Solution & Answer

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Answer 4

Question

Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

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Answer 5

Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

Answer 6

Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

Answer 7

Chapter 28, Problem 28.53P

Interpretation Introduction

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

Answer 8

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Answer 9

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Answer 11

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted. Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C 1 - C 2 bond.

Solution Summary: The author explains that the two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept explainers

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

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Chapter 28 Solutions

The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted. Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C 1 - C 2 bond.

Solution Summary: The author explains that the two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept explainers

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted. Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.

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Chapter 28 Solutions

Interpretation: The two aldohexoses yield D-arabinose upon Wohl degradation are to be predicted.

Concept introduction: Wohl degradation is a method which is used for the contraction of the carbon chains in aldose. In this method, the aldose chain is shortens by the cleavage of C1-C2 bond.