The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn. Concept Introduction: The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3

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Answer 5

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3

Answer 6

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3

Answer 7

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Answer 8

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

ORG.CHEM:TXT+OWLV2+MINDTAP 6MTHS >BI<, Chapter 28, Problem 28.7P , additional homework tip 3