BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
8th Edition
ISBN: 9781337687539
Author: Brown/Iverson/Anslyn/ Foote
Publisher: CENGAGE C
expand_more
expand_more
format_list_bulleted
Question
Chapter 29, Problem 29.11P
Interpretation Introduction
Interpretation:
The structural formula for the repeating unit of neoprene has to be drawn.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
5
Isopropylbenzene (C9H12) is commercially produced by Friedel–Crafts alkylation of
compound H with 1-chloropropane in the presence of anhydrous aluminium chloride as a
catalyst. CyH12 can be oxidized with strong oxidizing agent to form compound J.
a)
Draw the structure of H.
b)
Write the chemical reaction of isopropylbenzene to form compound J.
c)
Show the mechanism for the formation of isopropylbenzene (C,H12) from
compound H.
C,H¬B1+ OH¯→ C,H¬OH + NaBr
The rate equation for the hydrolysis of C3H,Br with sodium hydroxide is:
rate = k [C3H»Br] [OH ¯]
a)
Draw the structural formula of C3H¬Br. Explain your answer.
b)
State and show the mechanism of the reaction above.
An alkyl halide E, C5H11B undergoes hydrolysis to form an alcohol F,
CSH120. Alcohol F becomes cloudy immediately when reacted with a Lucas reagent.
c)
(i)
(ii)
Deduce the structures of E and F.
State the type of reaction and propose the mechanism for the conversion of E to F.
d)
Draw the structure of the product formed…
An unknown hydrocarbon A with the formula CgH12 reacts
with 1 molar equivalent of H2 over a palladium catalyst.
Hydrocarbon A also reacts with OsO4 to give diol B. When
oxidized with KMNO4 in acidic solution, A gives two
fragments. One fragment is propanoic acid, CH3CH2CO2H,
and the other fragment is ketone C. What are the
structures of A, B, and C? Write all reactions, and show
your reasoning.
6. Dacron is the brand name for the polymer that is made from ethane-1,2-diol and benzene-1,4-dicarboxylic acid.
(a) When the two monomers combine, what type of reaction do they undergo and what molecule is
eliminated? [1] (b) What is the name for the linkages that join the monomers together? [1] (c) Draw the
monomers and the polymer of the reaction to create Dacron. [3]
Chapter 29 Solutions
BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
Ch. 29.2 - Prob. 29.1PCh. 29.5 - Prob. 29.2PCh. 29.6 - Prob. AQCh. 29.6 - Prob. BQCh. 29.6 - Prob. CQCh. 29.6 - Prob. DQCh. 29.6 - Prob. EQCh. 29.6 - Prob. FQCh. 29.6 - Prob. 29.3PCh. 29.6 - Prob. 29.4P
Ch. 29 - Prob. 29.5PCh. 29 - Prob. 29.6PCh. 29 - Prob. 29.7PCh. 29 - Prob. 29.8PCh. 29 - Prob. 29.9PCh. 29 - Prob. 29.10PCh. 29 - Prob. 29.11PCh. 29 - Prob. 29.12PCh. 29 - Prob. 29.13PCh. 29 - Prob. 29.14PCh. 29 - Prob. 29.15PCh. 29 - Prob. 29.16PCh. 29 - Polycarbonates (Section 29.5C) are also formed by...Ch. 29 - Prob. 29.18PCh. 29 - Prob. 29.19PCh. 29 - Prob. 29.20PCh. 29 - Prob. 29.21PCh. 29 - Draw a structural formula of the polymer resulting...Ch. 29 - Prob. 29.23PCh. 29 - Prob. 29.24PCh. 29 - Prob. 29.25PCh. 29 - Select the monomer in each pair that is more...Ch. 29 - Prob. 29.27PCh. 29 - Prob. 29.28PCh. 29 - Prob. 29.29PCh. 29 - Prob. 29.30PCh. 29 - Prob. 29.31PCh. 29 - Prob. 29.32PCh. 29 - Prob. 29.33PCh. 29 - Radical polymerization of styrene gives a linear...Ch. 29 - Prob. 29.35PCh. 29 - Prob. 29.36PCh. 29 - Prob. 29.37PCh. 29 - Prob. 29.38P
Knowledge Booster
Similar questions
- The 2000 Nobel Prize in Chemistry was awarded for work on polyacetylenes. Acetylene can be polymerized using a Ziegler–Natta catalyst. The cis or trans stereochemistry of the products can be controlled by careful selection and preparation of the catalyst. The resulting polyacetylene is an electrical semiconductor with a metallic appearance. cis-Polyacetylene has a copper color, and trans-polyacetylene is silver. It is possible to prepare polyacetylene films whose electrical conductivity is anisotropic. That is, the conductivity is higher in some directions than in others. Explain how this unusual behavior is possible.arrow_forwardExplain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forwardWhat is the product of the addition of I¬Cl to 1-butene?arrow_forward
- what are the physical porpeties of 1,3,5-cyclohexene thank youarrow_forward21.) Calculate the enthalpy of hydrogenation of benzene to cyclohexane from the following reactions A,H (kJ/mol) C6H6 (1) + 15/2 02 (g) → 6 CO2 (g) + 3 H20 (1) C6H12 (1) + 9 02 (g) → 6 CO2 (g) + 6 H20 (1) H2 (g) + ½ 02 (g) → H2O (1) -3268 -3920 -285.83 a.) -205 kJ/mol b.) -1507 kJ/mol c.) -938 kJ/mol d.) -366 kJ/molarrow_forward1. The polymer below resulted from 1,4-polymerization. Provide an unambiguous structural formula for the monomer. 2. What is the IUPAC name of the monomer in 1? 3. What is the common name of the monomer in 1? CH3 to -CH2-C=C-CH2" please explain each and give correct answerarrow_forward
- For small-scale and consumer welding applications, many hardware stores sell cylinders of MAAP gas, which is a mixture of propyne (methylacetylene) and 1,2-propadiene (allene), with other hydrocarbons. How would you prepare the methylacetylene/allene mixture from propene in the laboratory?arrow_forward(d) Another variation on this type of polymer is used in hair gels. In these, the polymer chains are cross-linked by a compound known as pentaerythritol. но- OH но- OH pentaerythritol ( By what type of chemicat reaction are the cross-links in this polymer formed? (i) it is important that the gel should be easily washed out of hair What is it about the structure of the polymer that allows this to happen?arrow_forwardAn unknown hydrocarbon A with the formula C6H12 reacts with 1 molar equivalent of H2 over a palladium catalyst to give hydrocarbon B. Hydrocarbon A also reacts with OsO4 to give the glycol C. When oxidized with KMnO4 in acidic solution, A gives two fragments. One fragment is propanoic acid, CH3CH2COOH, and the other fragment is ketone D (R2C=O). What are the structures of A, B, C and D? Write all reactions.arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole