Connect Access Card For Foundations Of Materials Science And Engineering
Connect Access Card For Foundations Of Materials Science And Engineering
6th Edition
ISBN: 9781260049060
Author: William F. Smith Professor, Javad Hashemi Prof.
Publisher: McGraw-Hill Education
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Chapter 2.9, Problem 59AAP
To determine

The net potential energy for a Ba2+S2- ion pair.

Expert Solution & Answer
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Answer to Problem 59AAP

The net potential energy for a Ba2+S2- ion pair is 2.6279×1018J.

Explanation of Solution

The net force acting between two atoms is,

  Fnet=FattractionFrepulsion

Refer Equation (2.8),

Write the formula for repulsion force (Frepulsion).

  Frepulsion=nban+1        (I)

Here, the constants are n,b, and inter-ionic distance is a.

Write the formula for net potential energy (Enet).

  Enet=Fattraction+Frepulsion=z1z2e24πεoa+ban        (II)

Here, the electrons removed from Ba is z1, the electrons added to S is z2, the electron charge is e, the permittivity of space is εo and the inter-ionic distance is a.

When, the bond is formed, the net potential energy become zero.

  0=Fattraction+FrepulsionFrepulsion=Fattraction

Write the expression for inter-ionic distance.

    a=r1+r2        (III)

Here the ionic distance of Ba2+ is r1 and the ionic radius of S2- is r2.

Conclusion:

Substitute 0.143nm for r1 and 0.174nm for r2 in equation (II).

    a=0.143nm+0.174nm=(0.317nm)(109m1nm)=3.17×1010m

Refer problem 2.58. The force of attraction between Ba2+ and S2- ions is,

  Fattraction=9.1628×109N

Here,

  Frepulsion=Fattraction=(9.1628×109N)=9.1628×109N

Substitute 9.1628×109N for Frepulsion, 10.5 for n, and 3.17×1010m for a in

Equation (I).

  9.1628×109N=(10.5)b(3.17×1010m)10.5+1b=(3.17×1010m)11.5(9.1628×109N)10.5b=5.2992×1011810.5b=5.0468×10119Nm11.5

Substitute 2 for z1, 2 for z2, 1.6×1019C for e, 8.85×1012C2/Nm2 for εo, 3.17×1010m for a, 5.0468×10119Nm11.5 for b, and 10.5 for n in Equation (III).

    Enet=(2)(2)(1.6×1019C)24π(8.85×1012C2/Nm2)(3.17×1010m)+5.0468×10119Nm11.5(3.17×1010m)10.5=(2.9046×1018Nm)+(2.7663×1019Nm)=2.6279×1018Nm=2.6279×1018J

Thus, the net potential energy for a Ba2+S2- ion pair is 2.6279×1018J.

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Chapter 2 Solutions

Connect Access Card For Foundations Of Materials Science And Engineering

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