Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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draw the two possible carbocations that can form when this alkene reacts with a strong acid (such as HBr or H3O+). of the two structures you drew, circle the more stable carbocation
Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction.
b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.
Consider the following reactions:
When C5H12 is reacted with Cl2(g) in the presence of ultraviolet light, four different monochlorination products form. What is the structure of C5H12 in this reaction?
When C4H8 is reacted with H2O, a tertiary alcohol is produced as the major product. What is the structure of C4H8 in this reaction?
When C7H12 is reacted with HCl, 1-chloro-1-methylcyclohexane is produced as the major product. What are the two possible structures for C7H12 in this reaction?
When a hydrocarbon is reacted with water and the major product of this reaction is then oxidized, acetone (2-propanone) is produced. What is the structure of the hydrocarbon in this reaction?
When C5H12O is oxidized, a carboxylic acid is produced. What are the possible structures for C5H12O in this reaction?
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- What are the reagents used to convert 2-butyne to C4H8? What are the products when that C4H8 is mixed with OsO4, and H2O (the formula will be C4H10O2 racemic)? What is the product when C4H8 is mixed with RCO3H, and H2O (the formula will be C4H10O2 meso)?arrow_forwardWhat is the major product of the reaction between 2-methylbut-2-ene and Br2 in H2O?arrow_forwardThe reaction of Hbr with 2-methylpropene produces 2-bromo-2-methylpropane. What is the structure of the carbocation formed during the reaction?arrow_forward
- When compound CH3-C(CH3)=CH-CH2-CH(CH3)2 is the SUBSTRATE (reactant) in a HALOGENATION reaction with Br2 (and CH2Cl2 as the solvent), a correct condensed structural formula for the MAJOR SUBSTRATE PRODUCT of this reaction is:arrow_forwardThe reaction of CH4 and O2 to form C2H6 and H2O must be carried out carefully to avoid a competing reaction. What is the most likely competing reaction?arrow_forwardPredict the products of the ethoxycyclohexane + HBrarrow_forward
- 2-chloropropane is a major product of the reaction of chlorine with propane under ultraviolet light. Write the mechanism for this reaction including the initiation step and the two propagation steps.arrow_forwardHow does the addition of NaNH2 to an alkane lead to the synthesis of a terminal alkyne? Doesn't the starting material have to be an alkene?arrow_forwardWhen HBr adds across the double bond of 1,2-dimethylcyclopentene, the product is a mixture of the cis and trans isomers. Show why this addition is not stereospecific.arrow_forward
- In the reaction of ethylene with H20 in the presence of sulfuric acid,which one adds across the double bond first? * ulfate ionarrow_forwardThe organoborane formed in step 1 is oxidized by H2O2 in the presence of OH– in the next step of the reaction. Which of the following options correctly describe this process? Choose one or more: A.–BR2 acts as a leaving group in this step. B.OH– must attack from the face of the alkene opposite the –BR2 group. C.OH replaces –BR2 in this step. D.OH replaces H in this step. E.Configuration at the carbon-bearing B is retained in the reaction.arrow_forwardWhich alcohols can be prepared as a single product by hydroboration– oxidation of an alkene? Which alcohols can be prepared as a single product by the acid-catalyzed addition of H2O to an alkene?arrow_forward
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