ORGANIC CHEMISTRY,VOL.1 >CUSTOM<
10th Edition
ISBN: 9781260020724
Author: Carey
Publisher: MCG CUSTOM
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 3, Problem 24P
Interpretation Introduction
Interpretation:
The class of hydrocarbons to which the reactant in the given reaction belong is to be identified and the IUPAC name of the reactant molecule is to be written, the carbon that is oxidized in the formation of each product is to be identified by IUPAC locant and the relation between the alcohols in the product is to be determined.
Concept introduction:
The bicyclic
While determining the locants for the given alakne, the direction is chosen in such a way that the lower locant is given the first point of difference. The substituents are then listed in alphabetical order, and the locants and substituents are written first in the name of the alkane.
The isomers that have the same molecular formula but differ in the way the different atoms are connected in their structure are constitutional isomers.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
a. What hydrocarbon with molecular formula C4H10 forms only two monochlorinated products? Both products are achiral.
b. What hydrocarbon with the same molecular formula as in part a forms three monochlorinated products? One is achiral and two are chiral.
Which statements are true about constitutional isomers?
(a) They have the same molecular formula.
(b) They have the same molecular weight.
(c) They have the same order of attachment of atoms.
(d) They have the same physical properties
Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other.
Chapter 3 Solutions
ORGANIC CHEMISTRY,VOL.1 >CUSTOM<
Ch. 3.1 - Identify the alkanes corresponding to each of the...Ch. 3.1 - Find the conformations in Figure 3.4 in which the...Ch. 3.2 - Sketch a potential energy diagram for rotation...Ch. 3.2 - Acetylcholine is a neurotransmitter in the central...Ch. 3.2 - Prob. 5PCh. 3.5 - The heats of combustion of ethylcyclopropane and...Ch. 3.8 - Prob. 7PCh. 3.10 - The following questions relate to a cyclohexane...Ch. 3.10 - Draw the most stable conformation of...Ch. 3.11 - Prob. 10P
Ch. 3.11 - Prob. 11PCh. 3.12 - Based on what you know about disubstituted...Ch. 3.12 - Write structural formulas for the most stable...Ch. 3.14 - Cubane (C4H8) is the common name of the polycyclic...Ch. 3.14 - Prob. 15PCh. 3.14 - Prob. 16PCh. 3.14 - Prob. 17PCh. 3.14 - Prob. 18PCh. 3.15 - Prob. 19PCh. 3 - Give the IUPAC names of each of the following: (a)...Ch. 3 - Draw Newman projections for the gauche and...Ch. 3 - Identify all atoms that are (a) anti and (b)...Ch. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Oxidation of 4-tert-butylthiane proceeds according...Ch. 3 - The following are representations of two forms of...Ch. 3 - Draw (a) a Newman projection of the most stable...Ch. 3 - Write a structural formula for the most stable...Ch. 3 - Sight down the C-2-C-3 bond, and draw Newman...Ch. 3 - Prob. 34PCh. 3 - Sketch an approximate potential energy diagram for...Ch. 3 - Prob. 36PCh. 3 - Even though the methyl group occupies an...Ch. 3 - Which do you expect to be the more stable...Ch. 3 - Arrange the trimethylcyclohexane isomers shown in...Ch. 3 - Identify the more stable stereoisomer in each of...Ch. 3 - One stereoisomer of 1,1,3,5-tetramethylcyclohexane...Ch. 3 - One of the following two stereoisomers is...Ch. 3 - In each of the following groups of compounds,...Ch. 3 - The heats of combustion of the more and less...Ch. 3 - The measured dipole moment of ClCH2CH2Cl is 1.12D....Ch. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48DSPCh. 3 - Prob. 49DSPCh. 3 - Prob. 50DSPCh. 3 - Prob. 51DSPCh. 3 - Prob. 52DSPCh. 3 - Prob. 53DSP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each attached otherarrow_forwardThere are 17 possible alkene isomers with the formula C6H12. Draw structures of the five isomers in which the longest chain has six carbon atoms, and give the name of each. Are any of these isomers chiral? (There are also eight isomers in which the longest chain has five carbon atoms, and four isomers in which the longest chain has four carbon atoms. How many can you find?)arrow_forwardClassify the following alcohols as primary, secondary, or tertiary: a. b. CH3CH2CH2CH2OH c.arrow_forward
- Based on the structures of lycopene and β-carotene, which are two chemicals found in another common vegetable, the tomato, answer the following questions: 1. Are they stereoisomers, constitutional isomers or not even isomers? 2. Do you expect them to be relatively polar or nonpolar substances? Why? 3. How many double bonds are in lycopene? How many in β -carotene? 4. As lycopene is transformed into β -carotene, how many pi electrons from the double bonds are transformed into single bonds? How many new single bonds are being formed in β -carotene? 5. The first step of a possible mechanism for the ring closure in the transformation is outlined below (only part of the structure is shown for simplicity). Draw the product that results from this arrow pushing mechanism. Be sure to include any formal charges that arise from the carbon atoms.arrow_forwardFor the following compounds identify and draw freehand structural isomers and/ or stereoisomers where possible. For each isomer, clearly explain what type of isomerism is being shown and how it arises. i) Br2C=CH2 ii) CH3CH2CH2CHOarrow_forwarda. Which of the following statements concerning a pair of geometrical isomers are correct?(1) They have different boiling points and melting points.(2) They have the same relative molecular mass.(3) Their atoms are joined in the same order.A. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)b. Which of the following statements concerning enantiomers is INCORRECT?A. If a pair of enantiomers is present in the same amount, the mixture is optically inactive.B. A pair of enantiomers has the same melting point.C. There is at least one plane of symmetry in the molecules of enantiomers.D. A pair of enantiomers has the same molecular formula.arrow_forward
- Which of the following statements about alkenes and alcohols are correct? 1.Alcohols are formed as a result of the reactions of alkenes with water in an acidic environment. This is a solid reaction reaction. 2.When alcohols are heated at high temperatures, alkenes can be obtained in basic conditions. 3.The oxidation step of an alcohol with the same carbon number and alkene is the same.arrow_forwarddraw the three different structures of C2H2Br2 Name the three molecules (IUPAC). The names should NOT be the same. Identify how your molecules are related. The relationships are not all the same.(a) How are your first and second molecules related? (choose one of the following: identical, stereoisomers, constitutional isomers, or completely unrelated)(b) How are your first and third molecules related? (choose one of the following: identical, stereoisomers, constitutional isomers, or completely unrelated)(c) How are your second and third molecules related? (choose one of the following: identical, stereoisomers, constitutional isomers, or completely unrelated)arrow_forwardDefine conformational isomers. Draw or attach a photo then arrange the following conformers of butane in order of energy, lowest to highest: eclipsed, totally eclipsed, gauche, and anti.arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning