Determine the number of impaired electrons in each of the following atoms in the ground state and identify each as diamagnetic or paramagnetic: (a) Rb, (b) As, (c) I, (d) Cr, (e) Zn.
(a)
Interpretation:
The number of unpaired electrons in the given atoms with its diamagnetic or paramagnetic behaviour should be given by knowing their ground-state electron configurations.
Concept Introduction:
An orbital is an area of space in which electrons are orderly filled. The maximum capacity in any type of orbital is two electrons. An atomic orbital is defined as the region of space in which the probability of finding the electrons is highest. It is subdivided into four orbitals such as
There are three basic principles in which orbitals are filled by the electrons.
- 1. Aufbau principle: In German, the word 'aufbau' means 'building up'. The electrons are arranged in various orbitals in the order of increasing energies.
- 2. Pauli exclusion principle: An electron does not have all the four quantum numbers.
- 3. Hund’s rule: Each orbital is singly engaged with one electron having the maximum same spin capacity after that only pairing occurs.
The electron configuration is the allocation of electrons of an atom in atomic orbitals. Electronic configuration of a particular atom is written by following the three basic principles. If all the atomic orbitals are filled by electrons, then the atom is diamagnetic in nature. Diamagnetic atoms are repelled by the magnetic field. If one or more unpaired electrons are present in an atom, then that atom is paramagnetic in nature. Paramagnetic atoms are attracted to the magnetic field.
To find: Count the number of unpaired electrons in
Answer to Problem 3.103QP
The number of unpaired electron in
Explanation of Solution
The noble gas core for
All the electrons are placed in the atomic orbitals by following Aufbau principle, Pauli exclusion principle and Hund’s rule.
The one electron of
The unpaired electron is present in
(b)
Interpretation:
The number of unpaired electrons in the given atoms with its diamagnetic or paramagnetic behaviour should be given by knowing their ground-state electron configurations.
Concept Introduction:
An orbital is an area of space in which electrons are orderly filled. The maximum capacity in any type of orbital is two electrons. An atomic orbital is defined as the region of space in which the probability of finding the electrons is highest. It is subdivided into four orbitals such as
There are three basic principles in which orbitals are filled by the electrons.
- 1. Aufbau principle: In German, the word 'aufbau' means 'building up'. The electrons are arranged in various orbitals in the order of increasing energies.
- 2. Pauli exclusion principle: An electron does not have all the four quantum numbers.
- 3. Hund’s rule: Each orbital is singly engaged with one electron having the maximum same spin capacity after that only pairing occurs.
The electron configuration is the allocation of electrons of an atom in atomic orbitals. Electronic configuration of a particular atom is written by following the three basic principles. If all the atomic orbitals are filled by electrons, then the atom is diamagnetic in nature. Diamagnetic atoms are repelled by the magnetic field. If one or more unpaired electrons are present in an atom, then that atom is paramagnetic in nature. Paramagnetic atoms are attracted to the magnetic field.
To find: Count the number of unpaired electrons in
Answer to Problem 3.103QP
The number of unpaired electron in
Explanation of Solution
Arsenic (
The noble gas core for
Put all the 15 electrons in the atomic orbitals by following Aufbau principle, Pauli exclusion principle and Hund’s rule.
All the 15 electrons of arsenic (
The unpaired electrons are present in
(c)
Interpretation:
The number of unpaired electrons in the given atoms with its diamagnetic or paramagnetic behaviour should be given by knowing their ground-state electron configurations.
Concept Introduction:
An orbital is an area of space in which electrons are orderly filled. The maximum capacity in any type of orbital is two electrons. An atomic orbital is defined as the region of space in which the probability of finding the electrons is highest. It is subdivided into four orbitals such as
There are three basic principles in which orbitals are filled by the electrons.
- 1. Aufbau principle: In German, the word 'aufbau' means 'building up'. The electrons are arranged in various orbitals in the order of increasing energies.
- 2. Pauli exclusion principle: An electron does not have all the four quantum numbers.
- 3. Hund’s rule: Each orbital is singly engaged with one electron having the maximum same spin capacity after that only pairing occurs.
The electron configuration is the allocation of electrons of an atom in atomic orbitals. Electronic configuration of a particular atom is written by following the three basic principles. If all the atomic orbitals are filled by electrons, then the atom is diamagnetic in nature. Diamagnetic atoms are repelled by the magnetic field. If one or more unpaired electrons are present in an atom, then that atom is paramagnetic in nature. Paramagnetic atoms are attracted to the magnetic field.
To find: Count the number of unpaired electrons in
Answer to Problem 3.103QP
The number of unpaired electron in
Explanation of Solution
Iodine (
The noble gas core for
Put all the 17 electrons in the atomic orbitals by following Aufbau principle, Pauli exclusion principle and Hund’s rule.
All the 17 electrons of iodine (
The unpaired electron is present in
(d)
Interpretation:
The number of unpaired electrons in the given atoms with its diamagnetic or paramagnetic behaviour should be given by knowing their ground-state electron configurations.
Concept Introduction:
An orbital is an area of space in which electrons are orderly filled. The maximum capacity in any type of orbital is two electrons. An atomic orbital is defined as the region of space in which the probability of finding the electrons is highest. It is subdivided into four orbitals such as
There are three basic principles in which orbitals are filled by the electrons.
- 1. Aufbau principle: In German, the word 'aufbau' means 'building up'. The electrons are arranged in various orbitals in the order of increasing energies.
- 2. Pauli exclusion principle: An electron does not have all the four quantum numbers.
- 3. Hund’s rule: Each orbital is singly engaged with one electron having the maximum same spin capacity after that only pairing occurs.
The electron configuration is the allocation of electrons of an atom in atomic orbitals. Electronic configuration of a particular atom is written by following the three basic principles. If all the atomic orbitals are filled by electrons, then the atom is diamagnetic in nature. Diamagnetic atoms are repelled by the magnetic field. If one or more unpaired electrons are present in an atom, then that atom is paramagnetic in nature. Paramagnetic atoms are attracted to the magnetic field.
To find: Count the number of unpaired electrons in
Answer to Problem 3.103QP
The number of unpaired electron in
Explanation of Solution
The noble gas core for
Put all the electrons in the atomic orbitals by following Aufbau principle, Pauli exclusion principle and Hund’s rule
The six electrons of
The unpaired electrons are present in
(e)
Interpretation:
The number of unpaired electrons in the given atoms with its diamagnetic or paramagnetic behaviour should be given by knowing their ground-state electron configurations.
Concept Introduction:
An orbital is an area of space in which electrons are orderly filled. The maximum capacity in any type of orbital is two electrons. An atomic orbital is defined as the region of space in which the probability of finding the electrons is highest. It is subdivided into four orbitals such as
There are three basic principles in which orbitals are filled by the electrons.
- 1. Aufbau principle: In German, the word 'aufbau' means 'building up'. The electrons are arranged in various orbitals in the order of increasing energies.
- 2. Pauli exclusion principle: An electron does not have all the four quantum numbers.
- 3. Hund’s rule: Each orbital is singly engaged with one electron having the maximum same spin capacity after that only pairing occurs.
The electron configuration is the allocation of electrons of an atom in atomic orbitals. Electronic configuration of a particular atom is written by following the three basic principles. If all the atomic orbitals are filled by electrons, then the atom is diamagnetic in nature. Diamagnetic atoms are repelled by the magnetic field. If one or more unpaired electrons are present in an atom, then that atom is paramagnetic in nature. Paramagnetic atoms are attracted to the magnetic field.
To find: Count the number of unpaired electrons in
Answer to Problem 3.103QP
There is no unpaired electron in
Explanation of Solution
The noble gas core for
Put all the 12 electrons in the atomic orbitals by following Aufbau principle, Pauli exclusion principle and Hund’s rule.
All the 12 electrons of
There is no unpaired electron present in
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Chapter 3 Solutions
Chemistry Atoms First - Custom Edition College Of Charleston
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