Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781319117313
Author: Harris
Publisher: MAC HIGHER
Question
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Chapter 3, Problem 3.16P

(a)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(a)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 10.18±0.07  and 10.18±0.7% respectively.

Explanation of Solution

Given data:

9.23(±0.03)+4.12(±0.02)3.26(±0.06)=?

Calculation of absolute and percent relative uncertainty:

+9.23(±0.03)+4.21(±0.02)3.26(±0.06)10.18(±0.07)

The uncertainty (e) is calculated as follows,

uncertainty =0.032+0.022+0.062      =0.07%

The percent relative uncertainty is calculated as follows,

Percent relative uncertainty  = 100 × relative uncertainty =100×0.0710.18 =0.687 =0.7% (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 10.18±0.07

The percent relative uncertainty is 10.18±0.7%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 10.18±0.07 and 10.18±0.7% respectively.

(b)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(b)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 174±3 and 174±2% respectively.

Explanation of Solution

Given data:

91.3(±1.0)×40.3(±0.2)/21.1(±0.2)=?

Calculation of absolute and percent relative uncertainty:

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 91.3(±1.0) , percent relative uncertainty is (±1.0/91.3)×100=±1.10%

For 40.3(±0.2) , percent relative uncertainty is (±0.2/40.3)×100=±0.50%

For 21.1(±0.2) , percent relative uncertainty is (±0.2/21.1)×100=±0.95%

The percentage uncertainty (e) is calculated as follows,

%uncertainty =1.102+0.502+0.952      =1.54% =2% (rounded to correct significant figure)

Substitute all the values in the given problem.

91.3(±1.0)×40.3(±0.2)/21.1(±0.2)=91.3(±1.10%)×40.3(±0.50%)21.1(±0.95%)=174.37(±1.54%)=174(±2%) (rounded to correct significant figures)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =±0.0154×174.37 =±2.685 =±3(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 174±3

The percent relative uncertainty is 174±2%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 174±3 and 174±2% respectively.

(c)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(c)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 0.147±0.003 and 0.147±2% respectively.

Explanation of Solution

Given data:

[4.97(±0.05)1.86(±0.01)]/21.1(±0.2)=?

Calculation of absolute and percent relative uncertainty:

Solve the bracket first.

+4.97(±0.05)1.86(±0.01)3.11(±0.0510)

The uncertainty (e) is calculated as follows,

uncertainty =0.052+0.12      =±0.0510

Substitute the obtained value in the given problem and solve further.

[4.97(±0.05)1.86(±0.01)]/21.1(±0.2)[3.11(±0.0510)]/21.1(±0.2)

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 3.11(±0.0510) , percent relative uncertainty is (±0.0510/3.11)×100=±1.64%

For 21.1(±0.2) , percent relative uncertainty is (±0.2/21.1)×100=±0.95%

Thus,

3.11(±0.0510)]/21.1(±0.2)=3.11(±1.64%)/21.1(±0.95%)=0.147(±1.90%) (since (1.64)2+(0.95)2=1.90%=0.147(±2%) (rounded to correct significant figure)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =±0.02×0.147 =±0.00294 =±0.003(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 10.18±0.07

The percent relative uncertainty is 10.18±0.7%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found as 0.147±0.003 and 0.147±2% respectively.

(d)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(d)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 7.86±0.01 and 7.86±0.1% respectively.

Explanation of Solution

Given data:

2.0164(±0.0008)+1.233(±0.002)+4.61(±0.01)=?

Calculation of absolute and percent relative uncertainty:

+2.0164(±0.0008)+1.233(±0.002)+4.61(±0.01)7.86(±0.01)

The uncertainty (e) is calculated as follows,

uncertainty =0.00082+0.0022+0.012      =0.01

The percent relative uncertainty is calculated as follows,

Percent relative uncertainty  = 100 × relative uncertainty =100×0.017.86 =0.127 =0.1% (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 7.86±0.01

The percent relative uncertainty is 7.86±0.1%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found as 7.86±0.01 and 7.86±0.1% respectively.

(e)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(e)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 2185.8±0.8 and 2185.8±0.04% respectively.

Explanation of Solution

Given data:

2.0164(±0.0008)×103+1.233(±0.002)×102+4.61(±0.01)×101=?

Calculation of absolute and percent relative uncertainty:

+2016.4(±0.8)+123.3(±0.2)+46.1(±0.1)2185.8(±0.8)

The uncertainty (e) is calculated as follows,

uncertainty =0.82+0.22+0.12      =0.8

The percent relative uncertainty is calculated as follows,

Percent relative uncertainty  = 100 × relative uncertainty =100×0.82185.8 =0.0365 =0.04% (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 7.86±0.01

The percent relative uncertainty is 7.86±0.1%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found as 2185.8±0.8 and 2185.8±0.04% respectively.

(f)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty for powers and roots:

For the function y=xa , the relative uncertainty in y (%ey) is a times the relative uncertainty in x (%ex)

y=xa  %ey = a(%ex)

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(f)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.464±0.007 and 1.464±0.5% respectively.

Explanation of Solution

Given data:

[3.14(±0.05)]1/3=?

Calculation of absolute and percent relative uncertainty:

Use y=xa  %ey = a(%ex)

x=3.14±0.05%ex=(0.05/3.14)×100=1.592%

%ey =13%ex =13(1.592%) =0.531%

Now,

(3.24±0.08)12 =1.4643±0.531% (Since3.14=1.4643) =1.464±0.5%(rounded to correct significant figure) 

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.00531×1.464 =0.007773 =0.0078 =0.007(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.464±0.007

The percent relative uncertainty is 1.464±0.5%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 1.464±0.007 and 1.464±0.5% respectively.

(g)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Exponents and logarithm:

Consider, y=logx .

Here, the absolute uncertainty in y(ey) is proportional to the relative uncertainty in x, which is ex/x

Uncertainty for logarithm:        y =1ogxey =1ln 10 xexx 0.43429 exx

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(g)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 0.496(±0.006) and 0.496(±1.3%) respectively.

Explanation of Solution

Given data:

log[3.14±0.05]=?

Calculation of absolute and percent relative uncertainty:

Use y=logxey =0.43429exx

ey =0.43429exx =0.43429(0.053.14) =0.006915 =0.006 (round to correct significant figure)

Now,

log(3.14±0.05)=0.4969±0.006915 (Since log 3.14=0.5101)  =0.496±0.006(rounded to correct significant figure)

Calculate percent relative uncertainty as follows,

Percent Relative uncertainty =(0.000069/0.496)×100 =0.0139% =1.39% =1.3%  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 0.496(±0.006)

The percent relative uncertainty is 0.496(±1.3%)

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 0.496(±0.006) and 0.496(±1.3%) respectively.

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