Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.22NP
Interpretation Introduction

Interpretation:The expression (U/V)T for an ideal gas needs to be determined using the following relation:

  (U/V)T(βT- κP)

Concept Introduction: Thermodynamics is the branch of chemistry that deals with heat exchange between system and surroundings. The thermodynamic process can be classified in two types: isothermal and adiabatic process.

Different thermodynamic properties like enthalpy, entropy, free energy etc. are used to define different properties like volume, pressure and heat capacity.

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A) For nitrogen gas the values of Cv and Cp at 25°C are 20.8 J K−1 mol−1 and 29.1 J K−1 mol−1, respectively. When a sample of nitrogen is heated at constant pressure, what fraction of the energy is used to increase the internal energy of the gas?  B) How much energy (in KJ) is required to raise the temperature of 136.4 g N2 from 25.0°C to 87.0°C in a vessel having a constant volume?
Investigate the dependence of pV on V for real gases.
What is Isothermal Expansion of a van der Waals Gas?

Chapter 3 Solutions

Thermodynamics, Statistical Thermodynamics, & Kinetics

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