Loose Leaf for Organic Chemistry
5th Edition
ISBN: 9781259637025
Author: Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 3, Problem 3.40P
(a) Draw four compounds with molecular formula
one different functional group. (b) Predict which compound has the highest boiling point, and explain your reasoning.
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5. a) Draw two different structures with the molecular formula C2H6O.
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Draw molecules for the formula C5H10O with functional group alcohol and an ether with an R chiral center.
Chapter 3 Solutions
Loose Leaf for Organic Chemistry
Ch. 3 - Prob. 3.1PCh. 3 - (a) Classify the carbon atoms in each compound as...Ch. 3 - Problem 3.3 Classify a carbon atom by the number...Ch. 3 - Classify each alkyl halide and alcohol as , or...Ch. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Draw the structure of a compound of molecular...Ch. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Draw the structure of a compound fitting each...
Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- Maleic acid and fumaric acid are the cis- and trans- isomers, respectively, of C2H2(COOH)2, a dicarboxylic acid. Draw and label their structures.arrow_forwardGlucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.arrow_forwardHow GC-MS separates and identify organic compounds?arrow_forward
- which functional groups are in C6H12O2 with it having 1 degree of saturation, and is the molecule hexanoic acid?arrow_forward1-Propylamine, propan-1-ol, acetic acid, and butane have about the same molar masses. Which would you expect to have the (a) highest boiling point, (b) lowest boiling point, (c) least solubility in water, and (d) least chemical reactivity? Have each member of your group chose a part to answer, andthen discuss with each other why those answers were chosen.arrow_forwardAssume for the purposes of this problem that to be an alcohol (-ol) or an amine (-amine), the hydroxyl or amino group must be bonded to a tetrahedral (sp3 hybridized) carbon atom. Write the structural formula of a compound with an unbranched chain of four carbon atoms that is an: Q. Alkanolarrow_forward
- Write a condensed structural formula for a cyclic ketone with the formula C5H8Oarrow_forwardOf the alcohols with the molecular formula C4H9OH, which has the highest boiling point?arrow_forwardWrite structural formulas for all ketones with the molecular formula C6H12O and give each its IUPAC name. Which of these ketones are chiral?arrow_forward
- Draw structures that fit each description and name the functional group in each molecule: (a) two constitutional isomers with molecular formula C5H10O that contain different functional groups; (b) two constitutional isomers with molecular formula C6H10O that contain the same functional group.arrow_forwardDraw the seven constitutional isomers having molecular formula C4H10O. Identify the functional group in each isomer.arrow_forwardDraw a chiral alkene with the formula C6H12.arrow_forward
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