QUANTITATIVE CHEM ANALYSIS CUSTOM 9TH
QUANTITATIVE CHEM ANALYSIS CUSTOM 9TH
9th Edition
ISBN: 9781319067861
Author: Harris
Publisher: MAC HIGHER
Question
Book Icon
Chapter 3, Problem 3.BE

(a)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(a)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 2.1±0.2  and 2.1±0.8% respectively.

Explanation of Solution

Given data:

[12.41(±0.09)÷4.16(±0.01)]×7.0682(±0.0004)=?

Calculation of absolute and percent relative uncertainty:

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 12.41(±0.09) , percent relative uncertainty is (±0.09/12.4)×100=±0.725%

For 4.16(±0.01) , percent relative uncertainty is (±0.01/4.16)×100=±0.240%

For 7.0682(±0.0004) , percent relative uncertainty is (±0.0004/7.0682)×100=±0.0057%

The uncertainty (e) is calculated as follows,

uncertainty =0.7252+0.00572+0.2402      =0.764% =0.8% (rounded to correct significant figure)

Substitute all the values in the given problem.

[12.41(±0.09)÷4.16(±0.01)]×7.0682(±0.0004)=12.41(±0.725%)×7.0682(±0.0057%)4.16(±0.240%)=21.086(±0.764%)Since 0.7252+0.00572+0.2402=0.764%

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.00764×21.086 =0.16 =0.2(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 2.1±0.2

The percent relative uncertainty is 2.1±0.8%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 2.1±0.2 and 2.1±0.8% respectively.

(b)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(b)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 27.4(±0.9) and 27.4(±3.2%) respectively.

Explanation of Solution

Given data:

[3.26(±0.10)×8.47(±0.05)]0.18(±0.06)=?

Calculation of absolute and percent relative uncertainty:

First solve the terms in bracket.

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 3.26(±0.10) , percent relative uncertainty is (±0.10/3.26)×100=±3.07%

For 8.47(±0.05) , percent relative uncertainty is (±0.05/8.47)×100=±0.59%

The uncertainty (e) is calculated as follows,

uncertainty =3.072+0.592      =±3.12%

Substitute all the values in the given problem.

[3.26(±0.10)×8.47(±0.05)]0.18(±0.06)=[3.26(±3.07%)×8.47(±0.59%)]0.18(±0.06)=[27.612(±3.12%)]0.18(±0.06) (Since 3.072+0.592=3.12%)=[27.612(±0.863)]0.18(±0.06) [Since (3.12/100)×27.612=0.863]=27.4(±0.86)=27.4(±0.9)(rounded to correct significant figures)

Therefore, the absolute uncertainty is 27.4(±0.9)

The percent relative uncertainty is calculated as follows,

Percent Relative uncertainty  =0.86327.43×100 =3.2%

Therefore,

The absolute uncertainty is given as 27.4(±0.9)

The percent relative uncertainty is 27.4(±3.2%)

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 27.4(±0.9) and 27.4(±3.2%) respectively.

(c)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(c)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.49(±0.1)×105 and 1.49(±9.0%)×105 respectively.

Explanation of Solution

Given data:

6.843(±0.008)×104÷[2.09(±0.04)1.63(±0.01)]=?

Calculation of absolute and percent relative uncertainty:

First solve the terms in bracket.

[2.09(±0.04)1.63(±0.01)]=0.46(±0.0412) (Since (0.04)2+(0.01)2=0.0412)

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

Substitute the above value and rewrite the given equation.

6.843(±0.008)×104÷[0.46(±0.0412)]=?

For 6.843(±0.008) , percent relative uncertainty is (±0.008/6.843)×100=±0.117%

For 0.46(±0.0412) , percent relative uncertainty is (±0.0412/0.46)×100=±8.96%

Substitute all the values in the given problem.

6.843(±0.008)×104÷[0.46(±0.0412)]=6.843(±0.117%)×104÷[0.46(±8.96%)]=1.49(±8.96%)×105 (Since 0.1172+8.962=8.96%)=1.49(±9%)×105(rounded to correct significant figure)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.0896×1.49 =0.1335 =0.1(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.49(±0.1)×105

The percent relative uncertainty is 1.49(±9.0%)×105

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 1.49(±0.1)×105 and 1.49(±9.0%)×105 respectively.

(d)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty for powers and roots:

For the function y=xa , the relative uncertainty in y (%ey) is a times the relative uncertainty in x (%ex)

y=xa  %ey = a(%ex)

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(d)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.80±0.02 and 1.80±1% respectively.

Explanation of Solution

Given data:

3.24±0.08=?

Calculation of absolute and percent relative uncertainty:

Use y=xa  %ey = a(%ex)

%ey =12%ex =12(0.083.24×100) =1.235%

Now,

(3.24±0.08)12 =1.80±1.235% (Since3.24=1.80) =1.80±1.2%(rounded to correct significant figure) 

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.01235×1.80 =0.02223 =0.02(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.80±0.02

The percent relative uncertainty is 1.80±1%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written 1.80±0.02 and 1.80±1% respectively.

(e)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty for powers and roots:

For the function y=xa , the relative uncertainty in y (%ey) is a times the relative uncertainty in x (%ex)

y=xa  %ey = a(%ex)

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(e)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.1(±0.1)×102 and 1.1(±9.9%)×102 respectively.

Explanation of Solution

Given data:

(3.24±0.08)4=?

Calculation of absolute and percent relative uncertainty:

Use y=xa  %ey = a(%ex)

%ey =4%ex =4(0.083.24×100) =9.877%

Now,

(3.24±0.08)4 =110.20±9.877% (Since (3.24)4=110.20) =110.20±9.9% =1.1×102±9.9% (rounded to correct significant figure)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.099×1.1 =0.1089 =0.11 =0.1  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.1(±0.1)×102

The percent relative uncertainty is 1.1(±9.9%)×102

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 1.1(±0.1)×102 and 1.1(±9.9%)×102 respectively.

(f)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Exponents and logarithm:

Consider, y=logx .

Here, the absolute uncertainty in y(ey) is proportional to the relative uncertainty in x, which is ex/x

Uncertainty for logarithm:        y =1ogxey =1ln 10 xexx 0.43429 exx

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(f)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 0.51(±0.01) and 0.51±2% respectively.

Explanation of Solution

Given data:

log(3.24±0.08)=?

Calculation of absolute and percent relative uncertainty:

Use y=logxey =0.43429exx

ey =0.43429exx =0.43429(0.083.24) =0.0107

Now,

log(3.24±0.08)=0.5105±0.0107 (Since log 3.24=0.5101)  =0.51±0.01(rounded to correct significant figure)

Calculate percent relative uncertainty as follows,

Percent Relative uncertainty =(0.0107/0.5105)×100 =2.095% =2.1% =2%  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 0.51(±0.01)

The percent relative uncertainty is 0.51±2%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 0.51(±0.01) and 0.51±2% respectively.

(g)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Exponents and logarithm:

Consider, y=antilog xy=10x .

Here, the relative uncertainty in y is proportional to the absolute uncertainty in x.

Uncertainty for 10x:        y =10xeyy =(ln 10)ex 2.3026ex

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(g)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.7(±0.3)×103 and 1.7(±18%)×103 respectively.

Explanation of Solution

Given data:

103.24±0.08=?

Calculation of absolute and percent relative uncertainty:

Use y=antilog xy=10x

eyy =2.3026ex =2.3026(0.08) =0.184 =18.4%

Now,

103.24±0.08 =1.74×103±18.4% (Since 103.24=1734.81.74×103) =1.7×103±18%(rounded to correct significant figure)

Convert percent relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.184×1.74 =0.320 =0.32% =0.3%  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.7(±0.3)×103

The percent relative uncertainty is 1.7(±18%)×103

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 1.7(±0.3)×103 and 1.7(±18%)×103 respectively.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Knowledge Booster
Background pattern image
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY