ORGANIC CHEMISTRY 345 WSU >IP<
ORGANIC CHEMISTRY 345 WSU >IP<
15th Edition
ISBN: 9781269916264
Author: Pearson
Publisher: PEARSON C
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Chapter 3.10, Problem 38P

(a)

Interpretation Introduction

Interpretation:

Given organic molecules has to be convert from Newman projection to skeletal structure and thus molecule should be named.

Concept introduction:

IUPAC systematic method:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).  IUPAC name consists of three parts in major namely Prefix suffix and root word.

Skeletal formula:

It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond are called conformational isomers.

Newman projection:

Its assume that the viewer is looking along the longitudinal axis of a particular carbon-carbon (C-C) bond.  The carbon in front is represented by a point and the back is represented by a circle.

(b)

Interpretation Introduction

Interpretation:

Given organic molecules has to be convert from Newman projection to skeletal structure and thus molecule should be named.

Concept introduction:

IUPAC systematic method:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).  IUPAC name consists of three parts in major namely prefix suffix and root word.

Skeletal formula:

It’s indicated as the line-angle formula or shorted formula of an organic compound is a type of molecular structural formula the indicated of molecular bonding and information its molecular geometry.

Conformers:

The different spatial arrangements of the atoms the result from rotation about a single bond are called conformational isomers.

Newman projection:

Its assume that the viewer is looking along the longitudinal axis of a particular carbon-carbon (C-C) bond.  The carbon in front is represented by a point and the back is represented by a circle.

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Convert the following Newman projections to skeletal structures and name them.
Convert the following condensed structures into skeletal structures: a. CH3CH2CH2CH2CH2CH2OH b. CH3CH2CH2CH2CH2CH3 c. CH3CH2CHCH2CHCH2CH3 d. CH3CH2CH2CH2OCH3 e. CH3CH2NHCH2CH2CH3  f. CH3CHCH2CH2CHCH3
Provide the correct IUPAC name for the skeletal (line-bond) structure shown here.

Chapter 3 Solutions

ORGANIC CHEMISTRY 345 WSU >IP<

Ch. 3.3 - Prob. 15PCh. 3.3 - Prob. 16PCh. 3.3 - What is each compounds systematic name?Ch. 3.4 - Give two names for each of the following alkyl...Ch. 3.4 - Prob. 19PCh. 3.5 - a. What is each ethers systematic name? 1....Ch. 3.6 - Draw the structures of a homologous series of...Ch. 3.6 - Give each of the following a systematic name and...Ch. 3.6 - Prob. 23PCh. 3.6 - Prob. 24PCh. 3.7 - Are the following compounds primary, secondary, or...Ch. 3.7 - Prob. 26PCh. 3.7 - Prob. 27PCh. 3.7 - For each of the following, give the systematic...Ch. 3.8 - Predict the approximate size of the following bond...Ch. 3.9 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - Prob. 32PCh. 3.9 - Rank the following compounds from highest boiling...Ch. 3.9 - Rank the compounds in each set from highest...Ch. 3.9 - Prob. 35PCh. 3.9 - In which solvent would cyclohexane have the lowest...Ch. 3.10 - a. Draw all the staggered and eclipsed conformers...Ch. 3.10 - Prob. 38PCh. 3.10 - Using Newman projections, draw the most stable...Ch. 3.11 - The bond angles in a regular polygon with n sides...Ch. 3.11 - Prob. 41PCh. 3.11 - Prob. 42PCh. 3.12 - Draw 1,2,3,4,5,6-hexachlorocydohexane with a. all...Ch. 3.13 - The chair conformer of fluorocyclohexane is 0.25...Ch. 3.13 - Using the data in Table 3.9, calculate the...Ch. 3.14 - Prob. 46PCh. 3.14 - Which has a higher percentage of the...Ch. 3.14 - For each of the following disubstituted...Ch. 3.14 - a. Calculate the energy difference between the two...Ch. 3 - a. How many hydrogen does an alkene with 17...Ch. 3 - Draw the structure of octane and isooctaneCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 53PCh. 3 - a. What is each compounds systematic name? b. Draw...Ch. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - Draw a skeletal structure for an alkane that has...Ch. 3 - What is each compounds systematic name? a....Ch. 3 - Which bus a. the higher boiling point:...Ch. 3 - a. Draw Newman projections of the two conformers...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - Prob. 63PCh. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 66PCh. 3 - Prob. 67PCh. 3 - For rotation about the C-3C-4 bond of...Ch. 3 - Prob. 69PCh. 3 - What is each compounds systematic name? a. b. c....Ch. 3 - Prob. 71PCh. 3 - Why are lower molecular weight alcohols more...Ch. 3 - a. Draw a potential energy diagram for rotation...Ch. 3 - For each of the following compound, determine...Ch. 3 - How many ethers have molecular formula C5H12O?...Ch. 3 - Draw the most stable conformer of the following...Ch. 3 - What is each compounds systematic name?Ch. 3 - Calculate the energy difference between the two...Ch. 3 - The most stable from of glucose (blood sugar) is a...Ch. 3 - Prob. 80PCh. 3 - Explain the following: a. 1-Hexanol has a higher...Ch. 3 - One of the chair conformers of cis-...Ch. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Name the following compounds:Ch. 3 - Prob. 85PCh. 3 - Using the data obtained in Problem 85, calculate...
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