CHEMISTRY 3
CHEMISTRY 3
13th Edition
ISBN: 9781260669268
Author: Chang
Publisher: MCG/CREATE
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Chapter 4, Problem 4.103QP

(a)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid–base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involved in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(a)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is a redox reaction

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involved in the reaction is called redox reaction.

    Cl2+2OH-Cl-+ClO-+H2O

  • The chlorine gains one electron to produce the Cl- ion and OH loses electron.  Hence, it is a redox reaction.

(b)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(b)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is precipitation reaction

Explanation of Solution

  • If precipitate is formed, when the two solutions mixed together is called precipitation reaction.

    Ca2++CO32-CaCO3

  • The solutions of Ca2+ and CO32- are mixed together to form a CaCO3 precipitate.  So it is a precipitation reaction.

(c)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(c)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is acid­base reaction

Explanation of Solution

  • The reaction between acid and base to produce a salt is called acid-base reaction.

    NH3+H+NH4+

  • The acid is reacting with Ammonia base to give an Ammonium salt.  So, it is an acid-base reaction.

(d)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(d)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is a combination reaction

Explanation of Solution

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

    2CCl4+CrO42-2COCl2+CrO2Cl2+2Cl-

  • In the above given reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants so it is a combination reaction.

(e)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(e)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is a redox reaction

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

    Ca+F2CaF2

  • The Fluorine is gained one electron to produce the F- ion and Calcium loosed two electrons to produce Ca2+ ion.  So it is a redox reaction.

(f)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(f)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is a redox reaction.

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

    2Li+H22LiH

  • The Hydrogen is gained a one electron to produce the H- ion and Lithium loosed one electron to produce Li+ ion.  So it is a redox reaction.

(g)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(g)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is a precipitation reaction.

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

    Ba(NO3)2(aq)+Na2SO4(aq)BaSO4(s)+2Na(NO3)(aq)

  • The reaction between Ba(NO3)2andNa2SO4 is produce the BaSO4 precipitate so it is a precipitation reaction.

(h)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(h)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is redox reaction

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

    CuO+H2Cu+H2O

  • The copper is gained a two electron to produce the Cu metal.  So it is a redox reaction.

(i)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(i)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is redox reaction.

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

    Zn+2HClZnCl2+H2

  • The Zinc metal is loosed a two electron to produce the ZnCl2 salt.  So, it is a redox reaction.

(j)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(j)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is redox reaction

Explanation of Solution

  • The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

    2FeCl2+Cl22FeCl3

  • The iron Fe2 is loosed a one electron to produce the FeCl3..So, it is a redox reaction.

(k)

Interpretation Introduction

Interpretation:

The given reaction should be classified as redox reaction, acid –base, precipitation reaction and combination reaction.

Concept Introduction:

Redox reaction:

  • The oxidation number of a molecule is varied by involving in a reaction is known redox reaction.  The oxidation and reduction of chemical compounds takes place while they are involving in the reaction is called redox reaction.

Acid -Base reaction:

  • The reaction between acid and base to produce a salt is called acid-base reaction.

Precipitation reaction:

  • If precipitate is formed, when the two solutions are mixed together is called precipitation reaction.

Combination reaction:

  • In the reaction, there is no change in oxidation numbers of atoms present in the reactants and products is and only the product is offered by the combination of reactants is called combination reaction.

(k)

Expert Solution
Check Mark

Answer to Problem 4.103QP

The given reaction is acid-base reaction.

Explanation of Solution

  • The oxidation numbers of lithium, oxygen, hydrogen and nitrogen does not change.

    LiOH+HNO3LiNO3+H2O

  • This reaction is acid base reaction the base LiOH and the acid is HNO3 

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Chapter 4 Solutions

CHEMISTRY 3

Ch. 4.3 - Identify the Brnsted acid and Brnsted base in the...Ch. 4.3 - Write the net ionic equation for the following...Ch. 4.4 - Assign oxidation numbers to all the elements in...Ch. 4.4 - Prob. 6PECh. 4.4 - Which of the following combination reactions is...Ch. 4.4 - Prob. 2RCFCh. 4.5 - Prob. 7PECh. 4.5 - Prob. 8PECh. 4.5 - Prob. 9PECh. 4.5 - Prob. 1RCFCh. 4.5 - Prob. 2RCFCh. 4.5 - What mass of Ca(NO3)2 in grams is needed to...Ch. 4.6 - A sample of 0.3220 g of an ionic compound...Ch. 4.6 - Prob. 1RCFCh. 4.7 - How many grams of KHP are needed to neutralize...Ch. 4.7 - Prob. 12PECh. 4.7 - Prob. 2RCFCh. 4.8 - Prob. 13PECh. 4.8 - If a solution of a reducing agent is titrated with...Ch. 4.8 - The concentration of a KMnO4 solution can be...Ch. 4 - Define solute, solvent, and solution by describing...Ch. 4 - What is the difference between a nonelectrolyte...Ch. 4 - Describe hydration. What properties of water...Ch. 4 - What is the difference between the following...Ch. 4 - Water is an extremely weak electrolyte and...Ch. 4 - Sodium sulfate (Na2SO4) is a strong electrolyte....Ch. 4 - Prob. 4.7QPCh. 4 - Prob. 4.8QPCh. 4 - Identify each of the following substances as a...Ch. 4 - Identify each of the following substances as a...Ch. 4 - The passage of electricity through an electrolyte...Ch. 4 - Predict and explain which of the following systems...Ch. 4 - You are given a water-soluble compound X. Describe...Ch. 4 - Explain why a solution of HCl in benzene does not...Ch. 4 - What is the difference between an ionic equation...Ch. 4 - What is the advantage of writing net ionic...Ch. 4 - Two aqueous solutions of AgNO3 and NaCl are mixed....Ch. 4 - Two aqueous solutions of KOH and MgCl2 are mixed....Ch. 4 - Characterize the following compounds as soluble or...Ch. 4 - Characterize the following compounds as soluble or...Ch. 4 - Write ionic and net ionic equations for the...Ch. 4 - Write ionic and net ionic equations for the...Ch. 4 - Which of the following processes will likely...Ch. 4 - Prob. 4.24QPCh. 4 - List the general properties of acids and bases.Ch. 4 - Give Arrheniuss and Brnsteds definitions of an...Ch. 4 - Give an example of a monoprotic acid, a diprotic...Ch. 4 - What are the characteristics of an acid-base...Ch. 4 - What factors qualify a compound as a salt? Specify...Ch. 4 - Prob. 4.30QPCh. 4 - Prob. 4.31QPCh. 4 - Identify each of the following species as a...Ch. 4 - Balance the following equations and write the...Ch. 4 - Balance the following equations and write the...Ch. 4 - Prob. 4.35QPCh. 4 - True or false: All combustion reactions are redox...Ch. 4 - Prob. 4.37QPCh. 4 - Prob. 4.38QPCh. 4 - How is the activity series organized? How is it...Ch. 4 - Use the following reaction to define redox...Ch. 4 - Prob. 4.41QPCh. 4 - What is the requirement for an element to undergo...Ch. 4 - For the complete redox reactions given here, (i)...Ch. 4 - Prob. 4.44QPCh. 4 - Arrange the following species in order of...Ch. 4 - Phosphorus forms many oxoacids. Indicate the...Ch. 4 - Give the oxidation number of the underlined atoms...Ch. 4 - Give the oxidation number for the following...Ch. 4 - Give oxidation number for the underlined atoms in...Ch. 4 - Give the oxidation number of the underlined atoms...Ch. 4 - Nitric acid is a strong oxidizing agent. State...Ch. 4 - Which of the following metals can react with...Ch. 4 - On the basis of oxidation number considerations,...Ch. 4 - Predict the outcome of the reactions represented...Ch. 4 - Classify the following redox reactions. (a)...Ch. 4 - Classify the following redox reactions. (a)...Ch. 4 - Which of the following are redox processes?...Ch. 4 - Of the following, which is most likely to be the...Ch. 4 - Write the equation for calculating molarity. Why...Ch. 4 - Describe the steps involved in preparing a...Ch. 4 - Describe the basic steps involved in diluting a...Ch. 4 - Write the equation that enables us to calculate...Ch. 4 - Calculate the mass of KI in grams required to...Ch. 4 - Describe how you would prepare 250 mL of a 0.707 M...Ch. 4 - Prob. 4.65QPCh. 4 - Prob. 4.66QPCh. 4 - Calculate the molarity of each of the following...Ch. 4 - Calculate the molarity of each of the following...Ch. 4 - Calculate the volume in milliliters of a solution...Ch. 4 - Prob. 4.70QPCh. 4 - What volume of 0.416 M Mg(NO3)2 should be added to...Ch. 4 - Barium hydroxide, often used to titrate weak...Ch. 4 - Describe how to prepare 1.00 L of 0.646 M HCl...Ch. 4 - Water is added to 25.0 mL of a 0.866 M KNO3...Ch. 4 - How would you prepare 60.0 mL of 0.200 M HNO3 from...Ch. 4 - You have 505 mL of a 0.125 M HCl solution and you...Ch. 4 - A 35.2-mL, 1.66 M KMnO4 solution is mixed with...Ch. 4 - A 46.2-mL, 0.568 M calcium nitrate [Ca(NO3)2]...Ch. 4 - Describe the basic steps involved in gravimetric...Ch. 4 - Distilled water must be used in the gravimetric...Ch. 4 - If 30.0 mL of 0.150 M CaCl2 is added to 15.0 mL of...Ch. 4 - A sample of 0.6760 g of an unknown compound...Ch. 4 - How many grams of NaCl are required to precipitate...Ch. 4 - The concentration of sulfate in water can be...Ch. 4 - Describe the basic steps involved in an acid-base...Ch. 4 - How does an acid-base indicator work?Ch. 4 - Prob. 4.87QPCh. 4 - Would the volume of a 0.10 M NaOH solution needed...Ch. 4 - A quantity of 18.68 mL of a KOH solution is needed...Ch. 4 - Calculate the concentration (in molarity) of a...Ch. 4 - Calculate the volume in milliliters of a 1.420 M...Ch. 4 - What volume of a 0.500 M HCl solution is needed to...Ch. 4 - What are the similarities and differences between...Ch. 4 - Explain why potassium permanganate (KMnO4) and...Ch. 4 - Iron(II) can be oxidized by an acidic K2Cr2O7...Ch. 4 - The SO2 present in air is mainly responsible for...Ch. 4 - Prob. 4.97QPCh. 4 - The concentration of a hydrogen peroxide solution...Ch. 4 - Oxalic acid (H2C2O4) is present in many plants and...Ch. 4 - Prob. 4.100QPCh. 4 - Iodate ion, IO3, oxidizes SO32 in acidic solution....Ch. 4 - Calcium oxalate (CaC2O4), the main component of...Ch. 4 - Prob. 4.103QPCh. 4 - Prob. 4.104QPCh. 4 - Prob. 4.105QPCh. 4 - A 5.00 102 mL sample of 2.00 M HCl solution is...Ch. 4 - Shown are two aqueous solutions containing various...Ch. 4 - Shown are two aqueous solutions containing various...Ch. 4 - Calculate the volume of a 0.156 M CuSO4 solution...Ch. 4 - Prob. 4.110QPCh. 4 - A 3.664-g sample of a monoprotic acid was...Ch. 4 - Prob. 4.112QPCh. 4 - A 15.00-mL solution of potassium nitrate (KNO3)...Ch. 4 - When a 2.50-g zinc strip was placed in a AgNO3...Ch. 4 - Calculate the mass of the precipitate formed when...Ch. 4 - Calculate the concentration of the acid (or base)...Ch. 4 - (a) Describe a preparation for magnesium hydroxide...Ch. 4 - A 1.00-g sample of a metal X (that is known to...Ch. 4 - Prob. 4.119QPCh. 4 - The molecular formula of malonic acid is C3H4O4....Ch. 4 - Prob. 4.121QPCh. 4 - A 60.0-mL 0.513 M glucose (C6H12O6) solution is...Ch. 4 - An ionic compound X is only slightly soluble in...Ch. 4 - Prob. 4.124QPCh. 4 - Prob. 4.125QPCh. 4 - Prob. 4.126QPCh. 4 - The molar mass of a certain metal carbonate, MCO3,...Ch. 4 - Prob. 4.128QPCh. 4 - You are given a soluble compound of unknown...Ch. 4 - Prob. 4.130QPCh. 4 - Prob. 4.131QPCh. 4 - Prob. 4.132QPCh. 4 - Prob. 4.133QPCh. 4 - Prob. 4.134QPCh. 4 - Prob. 4.135QPCh. 4 - Prob. 4.136QPCh. 4 - Describe in each case how you would separate the...Ch. 4 - Prob. 4.138QPCh. 4 - Prob. 4.139QPCh. 4 - A 0.8870-g sample of a mixture of NaCl and KCl is...Ch. 4 - Prob. 4.141QPCh. 4 - Prob. 4.142QPCh. 4 - Prob. 4.143QPCh. 4 - A useful application of oxalic acid is the removal...Ch. 4 - Prob. 4.145QPCh. 4 - A 0.9157-g mixture of CaBr2 and NaBr is dissolved...Ch. 4 - Prob. 4.147QPCh. 4 - A 325-mL sample of solution contains 25.3 g of...Ch. 4 - Prob. 4.149QPCh. 4 - Prob. 4.150QPCh. 4 - Prob. 4.151QPCh. 4 - Prob. 4.152QPCh. 4 - Prob. 4.153QPCh. 4 - Prob. 4.154QPCh. 4 - Prob. 4.155QPCh. 4 - Prob. 4.156QPCh. 4 - Prob. 4.157QPCh. 4 - Prob. 4.158QPCh. 4 - Prob. 4.159QPCh. 4 - Prob. 4.160QPCh. 4 - The following cycle of copper experiment is...Ch. 4 - A quantity of 25.0 mL of a solution containing...Ch. 4 - Prob. 4.163QPCh. 4 - Prob. 4.165QPCh. 4 - Prob. 4.166QPCh. 4 - Prob. 4.167QPCh. 4 - Many proteins contain metal ions for structural...Ch. 4 - Prob. 4.170QPCh. 4 - Prob. 4.171QPCh. 4 - Prob. 4.172QPCh. 4 - Muriatic acid, a commercial-grade hydrochloric...Ch. 4 - Because acid-base and precipitation reactions...
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