ORGANIC CHEMISTRY(LL)-W/ACCESS >CUSTOM<
5th Edition
ISBN: 9781260014129
Author: SMITH
Publisher: MCG CUSTOM
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Textbook Question
Chapter 4, Problem 4.12P
Give the structure corresponding to each IUPAC name.
a.
b.
c.
d.
e.
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How do structures of these IUPAC names look like? a) 2-Methylhexan-2-olb) 4-Mercaptocyclohex-2-enolc) Ethyl methyl sulphided) 4-Mercapto-3-methylthiopentene
e) 2-Propoxy-1-(2-propoxyethoxy)propane
Draw a structure for each compound (includes old and new names).(a) 3-methylpent-1-ene (b) cis-3-methyl-3-hexene (c) 3,4-dibromobut-1-ene(d) 1,3-cyclohexadiene
Draw a structure for each compound (includes old and new names).(a) 3-methylpent-1-ene (b) cis-3-methyl-3-hexene (c) 3,4-dibromobut-1-ene(d) 1,3-cyclohexadiene (e) cycloocta-1,4-diene (f) (Z)-3-methyl-2-octene(g) vinylcyclopropane
Chapter 4 Solutions
ORGANIC CHEMISTRY(LL)-W/ACCESS >CUSTOM<
Ch. 4 - Prob. 4.1PCh. 4 - Problem 4.2 Which of the following is not another...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Draw the five constitutional isomers that have...Ch. 4 - Problem 4.7 Give the IUPAC name for each...Ch. 4 - Give the IUPAC name for each compound. a....Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.10P
Ch. 4 - Give the IUPAC name for each compound.Ch. 4 - Give the structure corresponding to each IUPAC...Ch. 4 - Arrange the following compounds in order of...Ch. 4 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4 - Prob. 4.15PCh. 4 - Prob. 4.16PCh. 4 - Problem 4.17 a. Draw the three staggered and...Ch. 4 - Problem 4.18 Rank the following conformations in...Ch. 4 - Problem 4.19 Consider rotation around the...Ch. 4 - Calculate the destabilization present in each...Ch. 4 - Problem 4.21 Classify the ring carbons as up or...Ch. 4 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4 - Draw a second chair conformation for each...Ch. 4 - Problem 4.24 Draw both conformations for and...Ch. 4 - Problem 4.25 Draw the structure for each compound...Ch. 4 - For cis-1, 3-diethylcyclobutane, draw a a...Ch. 4 - Prob. 4.27PCh. 4 - Problem 4.28 Consider .
Draw structures f or the...Ch. 4 - Problem 4.29 Draw a chair conformation of...Ch. 4 - Prob. 4.30PCh. 4 - Draw the products of each combustion reaction.Ch. 4 - Explain why beeswax is insoluble in H2O, slightly...Ch. 4 - Prob. 4.33PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - Consider the substituted cyclohexane shown in the...Ch. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - 4.38 Give the IUPAC name for each compound.
a. c....Ch. 4 - 4.39 Give the structure and IUPAC name for each of...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - Prob. 4.41PCh. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 4.43PCh. 4 - Prob. 4.44PCh. 4 - 4.45 Which conformation in each pair is higher in...Ch. 4 - 4.46 Considering rotation around the bond...Ch. 4 - Prob. 4.47PCh. 4 - 4.48 (a) Using Newman projections, draw all...Ch. 4 - 4.49 Label the sites of torsional and steric...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - 4.56 Convert each of the following structures into...Ch. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - 4.59 Classify each pair of compounds as...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 4.61PCh. 4 - 4.62 Draw the three constitutional isomers having...Ch. 4 - Prob. 4.63PCh. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 4.69PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 4.71PCh. 4 - Prob. 4.72PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- 1. a) write the product 2-methyl-3-ethyl-2-hexene -----O3------> Zn, H30+ b) Name this compound according to the IUPAC system: (CH3)2CH-CH2-C≡C-CH-CH2-CH2F | CH3arrow_forwardThese compounds are unreactive to NaNH2 EXCEPT a. 1-butene. b. 2-butyne. c. 2-butene. d. 1-butyne.arrow_forwardDraw the structure that corresponds with each name.(a) 3-ethyloctane (b) 4-isopropyldecane (c) sec-butylcycloheptane(d) 2,3-dimethyl-4-propylnonane (e) 2,2,4,4-tetramethylhexane (f) trans-1,3-diethylcyclopentane(g) cis-1-ethyl-4-methylcyclohexane (h) isobutylcyclopentane (i) tert-butylcyclohexane(j) pentylcyclohexane (k) cyclobutylcyclohexane (l) cis-1-bromo-3-chlorocyclohexanearrow_forward
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